@article { , title = {An ethylene cross-bridged pentaazamacrocycle and its Cu2+ complex: constrained ligand topology and excellent kinetic stability}, abstract = {Rigid and topologically constrained ethylene cross-bridged tetraazamacrocycles have been increasingly utilised for thirty years as they form remarkably stable transition metal complexes for catalysis, biomedical imaging, and inorganic drug molecule applications. Extending these benefits to pentaazamacrocycles has been achieved and a first transition metal complex prepared and structurally characterized. This journal is}, doi = {10.1039/d0cc00919a}, eissn = {1364-548X}, issn = {1359-7345}, issue = {54}, journal = {Chemical Communications}, pages = {7519-7522}, publicationstatus = {Published}, publisher = {Royal Society of Chemistry}, url = {https://hull-repository.worktribe.com/output/3520880}, volume = {56}, keyword = {Hull Molecular Imaging Centre, Health and Health Inequalities, Materials Chemistry, Electronic, Optical and Magnetic Materials, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Catalysis}, year = {2020}, author = {Shircliff, Anthony D. and Burke, Benjamin P. and Davilla, Dustin J. and Burgess, Gwendolyn E. and Okorocha, Faith A. and Shrestha, Alina and Allbritton, Elisabeth M. A. and Nguyen, Phillip T. and Lamar, Rachael L. and Jones, Donald G. and Gorbet, Michael Joseph and Allen, Michael B. and Eze, John I. and Fernandez, Andrea T. and Ramirez, Daniel and Archibald, Stephen J. and Prior, Timothy J. and Krause, Jeanette A. and Oliver, Allen G. and Hubin, Timothy J.} }