@article { , title = {Electrochemistry and charge transport in sporopollenin particle arrays}, abstract = {Electrochemical oxidation of hollow sporopollenin particles immobilised on an electrode surface is investigated in aqueous acidic solution. Redox activity is demonstrated to occur via a mixture of 2e(-)-2H(+) and 2e(-)-1H(+) processes, likely due to the oxidation of conjugated phenolics embedded within the surface-shell of the polymer particles. Charge transport over the surface is suggested to be fast based on comparison with an approximate physicochemical model. (C) 2010 Elsevier B.V. All rights reserved.}, doi = {10.1016/j.elecom.2010.07.038}, issn = {1388-2481}, issue = {10}, journal = {ELECTROCHEMISTRY COMMUNICATIONS}, note = {Batch 003. Output ID 26558.}, pages = {1428-1431}, publicationstatus = {Published}, publisher = {Elsevier}, url = {https://hull-repository.worktribe.com/output/396336}, volume = {12}, keyword = {Specialist Research - Other, Conducting polymer, Electron hopping, Sporopollenin, Antioxidant}, year = {2010}, author = {Thomasson, Matthew J. and Baldwin, David J. and Diego-Taboada, Alberto and Atkin, Stephen L. and Mackenzie, Grahame and Wadhawan, Jay D.} }