Wenxue Yang
Manganese coordination chemistry of bis(imino)phenoxide derived [2 + 2] Schiff-base macrocyclic ligands
Yang, Wenxue; Zhao, Ke-Qing; Wang, Bi-Qin; Redshaw, Carl; Elsegood, Mark R.J.; Zhao, Jiang-Lin; Yamato, Takehiko
Authors
Ke-Qing Zhao
Bi-Qin Wang
Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry
Mark R.J. Elsegood
Jiang-Lin Zhao
Takehiko Yamato
Abstract
The [2 + 2] Schiff base macrocycles [2,2'-(CH₂CH₂)(C₆H₄N)₂-2,6-(4-RC₆H₃OH)]₂ (IʳH₂), upon reaction with MnCl₂ (two equivalents) afforded the bimetallic complex [Cl₃Mn(NCMe)][MnCl(IᵗᵇᵘH₂)] (2). Under similar conditions, use of the related [2 + 2] oxy-bridged macrocycle [2,2'-O(C₆H₄N=CH)₂4-RC₆H₃OH] (IIʳH₂), afforded the bimetallic complexes [(MnCl)₂IIʳ] (R = Me 3, tBu 4), whilst the macrocycle derived from 1,2-diaminobenzene and 5,5'-di-tert-butyl-2,2'-dihydroxy-3,3'-methylenedibenzaldehyde (IIIH₄) afforded the complex [(MnCl)₂(III)]·2MeCN (5·2MeCN). For comparative studies, the salt complexes [2,6-(ArNHCH)₂-4-MeC₆H₂O][MnCl₃(NCMe)] (Ar = 2,4-Me₂C₆H₃, 6) and {[2,6-(ArNHCH)₂-4-MeC₆H₂O][MnCl}₂[MnCl₄]·8CH₂Cl₂ (Ar = 4-MeC₆H₄, 7·8CH₂Cl₂) were prepared. The crystal structures of 1 - 7 are reported (synchrotron radiation was necessary for complexes 1, 3 and 5). Complexes 1 - 7 (not 5) were screened for their potential to act as pre-catalysts for the ring opening polymerization (ROP) of ε-caprolactone; 3, 4 and 6, 7 were inactive, whilst 1 and 2 exhibited only poor activity low conversion (<15 %) at temperatures above 60 °C.
Citation
Yang, W., Zhao, K., Wang, B., Redshaw, C., Elsegood, M. R., Zhao, J., & Yamato, T. (in press). Manganese coordination chemistry of bis(imino)phenoxide derived [2 + 2] Schiff-base macrocyclic ligands. Dalton Transactions : an international journal of inorganic chemistry, 45(1), 226-236. https://doi.org/10.1039/c5dt03453a
Acceptance Date | Nov 10, 2015 |
---|---|
Online Publication Date | Nov 10, 2015 |
Deposit Date | Dec 11, 2015 |
Publicly Available Date | Mar 29, 2024 |
Journal | Dalton transactions |
Print ISSN | 1477-9226 |
Electronic ISSN | 1477-9234 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 45 |
Issue | 1 |
Pages | 226-236 |
DOI | https://doi.org/10.1039/c5dt03453a |
Keywords | Schiff base |
Public URL | https://hull-repository.worktribe.com/output/382445 |
Publisher URL | http://pubs.rsc.org/en/Content/ArticleLanding/2016/DT/c5dt03453a#!divAbstract |
Additional Information | Authors' accepted manuscript of article published in: Dalton transactions, 2016, v.45, issue 1. |
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