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Long-term ambient air-stable cubic CsPbBr3 perovskite quantum dots using molecular bromine (2019)
Journal Article
Thapa, S., Bhardwaj, K., Basel, S., Pradhan, S., Eling, C. J., Adawi, A. M., …Tamang, S. (in press). Long-term ambient air-stable cubic CsPbBr3 perovskite quantum dots using molecular bromine. Nanoscale advances, https://doi.org/10.1039/c9na00486f

We report unprecedented phase stability of cubic CsPbBr3 quantum dots in ambient air obtained by using Br2 as halide precursor. Mechanistic investigation reveals the decisive role of temperature-controlled in situ generated, oleylammonium halide spec... Read More

Dynamic electric field alignment of metal-organic framework micro- rods (2019)
Journal Article
Cheng, F., Young, A. J., Bouillard, J. G., Kemp, N. T., Guillet-Nicolas, R., Hall, C. H., …Chin, J. M. (2019). Dynamic electric field alignment of metal-organic framework micro- rods. Journal of the American Chemical Society, 141(33), 12989-12993. https://doi.org/10.1021/jacs.9b06320

Alignment of Metal Organic Framework (MOF) crystals has previously been performed via careful control of oriented MOF growth on substrates, as well as by dynamic magnetic alignment. We show here that microrod crystals of the MOF NU-1000 can also be d... Read More

Probing the molecular orientation of a single conjugated polymer via nano-gap SERS (2019)
Journal Article
Marshall, A. R. L., Roberts, M., Gierschner, J., Bouillard, J. G., & Adawi, A. M. (2019). Probing the molecular orientation of a single conjugated polymer via nano-gap SERS. ACS applied polymer materials, 1(5), 1175-1180. https://doi.org/10.1021/acsapm.9b00180

Determining the molecular orientation at the single molecule level is of key importance for a wide range of applica-tions ranging from molecular electronic devices to biomedical applications. In this work Surface-Enhanced Raman Scattering (SERS) was... Read More

Synthesis of super bright indium phosphide colloidal quantum dots through thermal diffusion (2019)
Journal Article
Clarke, M. T., Viscomi, F. N., Chamberlain, T. W., Hondow, N., Adawi, A. M., Sturge, J., …Stasiuk, G. J. (2019). Synthesis of super bright indium phosphide colloidal quantum dots through thermal diffusion. Communications Chemistry, 2(1), https://doi.org/10.1038/s42004-019-0138-z

Indium phosphide based quantum dots have emerged in recent years as alternatives to traditional heavy metal (cadmium, lead) based materials suitable for biomedical application due to their non-toxic nature. The major barrier to this application, is t... Read More