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In Situ Characterization of Elusive Salt Hydrates-The Crystal Structures of the Heptahydrate and Octahydrate of Sodium Sulfate (2008)
Journal Article
Oswald, I. D. H., Hamilton, A., Hall, C., Marshall, W. G., Prior, T. J., & Pulham, C. R. (2008). In Situ Characterization of Elusive Salt Hydrates-The Crystal Structures of the Heptahydrate and Octahydrate of Sodium Sulfate. Journal of the American Chemical Society, 130(52), 17795-17800. https://doi.org/10.1021/ja805429m

An important intermediate phase in the crystallization of aqueous solutions of sodium sulfate is the highly metastable sodium sulfate heptahydrate (Na2SO4 center dot 7H(2)O). This has been structurally characterized for the first time by in situ sing... Read More

Synthesis and crystal structures of new lanthanide hydroxyhalide anion exchange materials, Ln2(OH)5X·1.5H2O (X = Cl, Br; Ln = Y, Dy, Er, Yb) (2008)
Journal Article
Poudret, L., Prior, T. J., McIntyre, L. J., & Fogg, A. M. (2008). Synthesis and crystal structures of new lanthanide hydroxyhalide anion exchange materials, Ln2(OH)5X·1.5H2O (X = Cl, Br; Ln = Y, Dy, Er, Yb). Chemistry of materials : a publication of the American Chemical Society, 20(24), 7447-7453. https://doi.org/10.1021/cm802301a

A family of layered lanthanide hydroxyhalide intercalation hosts, Ln 2 (OH) 5 X·1.5H 2 0 (X = Cl, Br; Ln = Y, Dy, Er, Yb), has been synthesized under hydrothermal conditions and their crystal structure determined. These are the first structures for t... Read More

Putting pressure on elusive polymorphs and solvates (2008)
Journal Article
Oswald, I. D. H., Chataigner, I., Elphick, S., Fabbiani, F. P. A., Lennie, A. R., Maddaluno, J., …Smith, R. I. (2009). Putting pressure on elusive polymorphs and solvates. CrystEngComm RSC, 11(2), 359-366. https://doi.org/10.1039/b814471k

The reproducible crystallisation of elusive polymorphs and solvates of molecular compounds at high pressure has been demonstrated through studies on maleic acid, malonamide, and paracetamol. These high-pressure methods can be scaled-up to produce 'bu... Read More

Reactivity of the N-heterocyclic carbene complexes [Ru(IMes)(2)(CO)HX] (X = OH, Cl) with alkynes (2008)
Journal Article
Chatwin, S. L., Mahon, M. F., Prior, T. J., & Whittlesey, M. K. (2010). Reactivity of the N-heterocyclic carbene complexes [Ru(IMes)(2)(CO)HX] (X = OH, Cl) with alkynes. Inorganica Chimica Acta, 363(3), 625-632. https://doi.org/10.1016/j.ica.2008.11.013

Treatment of the 16-electron hydroxy hydride complex [Ru(IMes)(2)(CO)H(OH)] (1, IMes = 1,3-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene) with HC CR affords the alkynyl species [Ru(IMes)(2)(CO) H(C CR)] (R = Ph 3, SiMe3, 4) and [Ru(IMes)(2)(CO)(C... Read More

The dimeric "hand-shake" motif in complexes and metallo-supramolecular assemblies of cyclotriveratrylene-based ligands (2008)
Journal Article
Carruthers, C., Ronson, T. K., Sumby, C. J., Westcott, A., Harding, L. P., Prior, T. J., …Hardie, M. J. (2008). The dimeric "hand-shake" motif in complexes and metallo-supramolecular assemblies of cyclotriveratrylene-based ligands. Chemistry : a European journal, 14(33), 10286-10296. https://doi.org/10.1002/chem.200801264

A series of clathrate and metal complexes with cyclotriveratrylene-like molecular host ligands show a similar dimeric homomeric inclusion motif in which a ligand arm of one host is the intra-cavity guest of another and vice versa. This "hand-shake" m... Read More

Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer (2008)
Journal Article
Lauchan, S., Prior, T. J., Meansiri, S., & Rujiwatra, A. (2008). Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer. Journal of inorganic and organometallic polymers and materials, 18(3), 352-357. https://doi.org/10.1007/s10904-008-9208-x

A pillared-layered coordination polymer of formula Co(H2NCH2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is compo... Read More

Synthesis and characterization of two metallic spin-glass phases of Fe Mo4 Ge3 (2008)
Journal Article
Baker, P. J., Battle, P. D., Blundell, S. J., Grandjean, F., Lancaster, T., Long, G. J., …Prior, T. J. (2008). Synthesis and characterization of two metallic spin-glass phases of Fe Mo4 Ge3. Physical review B: Condensed matter and materials physics, 77(13), 134405-1 - 134405-13. https://doi.org/10.1103/physrevb.77.134405

Polycrystalline samples of Fe Mo4 Ge3 have been synthesized by the reduction of an oxide mixture at 1248 K and characterized by a combination of diffraction, muon spin relaxation (μ+ SR), Mössbauer spectroscopy, magnetometry, transport, and heat-capa... Read More

New network structures from Cu(II) complexes of chelating ligands with appended hydrogen bonding sites (2008)
Journal Article
Stephenson, M. D., Prior, T. J., & Hardie, M. J. (2008). New network structures from Cu(II) complexes of chelating ligands with appended hydrogen bonding sites. Crystal growth & design, 8(2), 643-653. https://doi.org/10.1021/cg700820d

Complexes [Cu(phenpyzda)Cl-2(H2O)]center dot H2O (1) and [Cu(phenpyzda)Br-2(H2O)]center dot 2H(2)O (2), where phenpyzda = pyrazino[2,3-f][1,10]phenanthroline-2,3-diamide, show similar molecular structures with square planar Cu(II). Each complex has a... Read More

Concomitant hydrate polymorphism in the precipitation of sparfloxacin from aqueous solution (2008)
Journal Article
Llinàs, A., Burley, J. C., Prior, T. J., Glen, R. C., & Goodman, J. M. (2008). Concomitant hydrate polymorphism in the precipitation of sparfloxacin from aqueous solution. Crystal growth & design, 8(1), 114-118. https://doi.org/10.1021/cg700908m

The Potentiometric Cycling for Polymorph Creation [PC](2) has been applied to sparfloxacin, a third-generation fluoroquinolone antibiotic. Two different trihydrate phases precipitate from aqueous solution. X-ray data indicate that one of these is a p... Read More