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Vanadium(v) phenolate complexes for ring opening homo- and co-polymerisation of ε-caprolactone, L-lactide and rac-lactide (2015)
Journal Article
Ge, F., Dan, Y., Al-Khafaji, Y., Prior, T. J., Jiang, L., Elsegood, M. R. J., & Redshaw, C. (2016). Vanadium(v) phenolate complexes for ring opening homo- and co-polymerisation of ε-caprolactone, L-lactide and rac-lactide. RSC advances, 6(6), 4792-4802. https://doi.org/10.1039/c5ra24816g

The vanadyl complexes [VO(OtBu)L¹ ] (1) and {[VO(OiPr)]₂ (μ-p-L²ᵖ)} (2) {[VO(OR)]₂ (μ-p-L²ᵐ )} (R = iPr 3, tBu 4) have been prepared from [VO(OR)₃ ] (R = nPr, iPr or tBu) and the respective phenol, namely 2,2′-ethylidenebis(4,6-di-tert-butylphenol) (... Read More about Vanadium(v) phenolate complexes for ring opening homo- and co-polymerisation of ε-caprolactone, L-lactide and rac-lactide.

Molybdenum (VI) imido complexes derived from chelating phenols : Synthesis, characterization and ɛ-Caprolactone ROP capability (2015)
Journal Article
Al-Khafaji, Y., Prior, T., Redshaw, C., & Elsegood, M. (2015). Molybdenum (VI) imido complexes derived from chelating phenols : Synthesis, characterization and ɛ-Caprolactone ROP capability. Catalysts open access journal, 5(4), 1928-1947. https://doi.org/10.3390/catal5041928

Reaction of the bulky bi-phenols 2,2′-RCH[4,6-(t-Bu)₂C₆H₂OH]₂ (R = Me L¹ᵐᵉH₂, Ph L¹ᵖʰH₂) with the bis(imido) molybdenum(VI) tert-butoxides [Mo(NR¹)(NR²)(Ot-Bu)₂] (R¹ = R² = 2,6-C₆H₃-i-Pr₂; R¹ = t-Bu, R² = C₆F₅) afforded, following the successive remo... Read More about Molybdenum (VI) imido complexes derived from chelating phenols : Synthesis, characterization and ɛ-Caprolactone ROP capability.

Influence of secondary ligand on structures and topologies of lanthanide coordination polymers with 1,3,5-triazine-2,4,6-triamine hexaacetic acid (2015)
Journal Article
Bunlawee, Y., Meundaeng, N., Mookda, P., Watcharee, F., Prior, T. J., & Apinpus, R. (2015). Influence of secondary ligand on structures and topologies of lanthanide coordination polymers with 1,3,5-triazine-2,4,6-triamine hexaacetic acid. Journal of coordination chemistry, 68(23), 4184-4202. https://doi.org/10.1080/00958972.2015.1100721

© 2015 Taylor and Francis. A series of new lanthanide coordination polymers has been synthesized and structurally characterized; [Ln 4 (TTHA) 2 (pzac)(H 3 O) 2 (H 2 O)]·5H 2 O (Ln = Pr (1a) and Nd (1b)), [Sm 8 (TTHA) 4 (pzac) 0.5 (H 3 O)(H 2 O) 7.5 ]... Read More about Influence of secondary ligand on structures and topologies of lanthanide coordination polymers with 1,3,5-triazine-2,4,6-triamine hexaacetic acid.

Crystal structure of dichlorido(4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane)iron(III) hexafluoridophosphate (2015)
Journal Article
Funwie, N. L., Cain, A. N., Fanning, B. Z., Hageman, S. A., Mullens, M., Roberts, T. K., …Prior, T. J. (2015). Crystal structure of dichlorido(4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane)iron(III) hexafluoridophosphate. Acta Crystallographica Section E: Crystallographic Communications, 71(9), 1073-1076. https://doi.org/10.1107/S2056989015015340

The title compound, [FeCl₂(C₁₄H₃₀N₄)]PF₆, contains Fe³⁺ coordinated by the four nitro­gen atoms of an ethyl­ene cross-bridged cyclam macrocycle and two cis chloride ligands in a distorted octa­hedral environment. In contrast to other similar compound... Read More about Crystal structure of dichlorido(4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane)iron(III) hexafluoridophosphate.

Co-crystallisation of cytosine with 1,10-phenanthroline: computational screening and experimental realisation (2015)
Journal Article
Hoxha, K., Case, D. H., Day, G. M., & Prior, T. J. (2015). Co-crystallisation of cytosine with 1,10-phenanthroline: computational screening and experimental realisation. CrystEngComm RSC, 17(37), 7130-7141. https://doi.org/10.1039/c5ce01286d

Attempts to co-crystallise the nucleobases adenine, thymine, guanine, and cytosine with 1,10-phenanthroline by ball milling and solvent evaporation methods are described. A 1:1 co-crystal of cytosine and 1,10-phenanthroline can be obtained by grindin... Read More about Co-crystallisation of cytosine with 1,10-phenanthroline: computational screening and experimental realisation.

Thermal Behavior of Benzoic Acid/Isonicotinamide Binary Cocrystals (2015)
Journal Article
Buanz, A., Prior, T. J., Burley, J. C., Raimi-Abraham, B. T., Telford, R., Hart, M., …Williams, G. R. (2015). Thermal Behavior of Benzoic Acid/Isonicotinamide Binary Cocrystals. Crystal growth & design, 15(7), 3249-3256. https://doi.org/10.1021/acs.cgd.5b00351

© 2015 American Chemical Society. A comprehensive study of the thermal behavior of the 1:1 and 2:1 benzoic acid/isonicotinamide cocrystals is reported. The 1:1 material shows a simple unit cell expansion followed by melting upon heating. The 2:1 crys... Read More about Thermal Behavior of Benzoic Acid/Isonicotinamide Binary Cocrystals.

Vanadium(V) tetra-phenolate complexes: synthesis, structural studies and ethylene homo-(co-)polymerization capability (2015)
Journal Article
Redshaw, C., Walton, M. J., Elsegood, M. R. J., Prior, T. J., & Michiue, K. (2015). Vanadium(V) tetra-phenolate complexes: synthesis, structural studies and ethylene homo-(co-)polymerization capability. RSC advances, 5(109), 89783-89796. https://doi.org/10.1039/c5ra20177b

Reaction of α,α,α′,α′-tetrakis(3,5-di-tert-butyl-2-hydroxyphenyl)-p-xylene (p-L¹H₄) with two equivalents of [VO(OR)₃] (R = nPr, tBu) in refluxing toluene afforded, after work-up, the complexes {[VO(OnPr)(THF)]₂ (μ-p-L¹)}·2(THF) (1·2(THF)) or {[VO(OtB... Read More about Vanadium(V) tetra-phenolate complexes: synthesis, structural studies and ethylene homo-(co-)polymerization capability.

Synthesis, structural studies, kinetic stability, and oxidation catalysis of the late first row transition metal complexes of 4,10-dimethyl-1,4,7,10-tetraazabicyclo[6.5.2]pentadecane (2015)
Journal Article
Matz, D. L., Jones, D. G., Roewe, K. D., Gorbet, M., Zhang, Z., Chen, Z., …Hubin, T. J. (2015). Synthesis, structural studies, kinetic stability, and oxidation catalysis of the late first row transition metal complexes of 4,10-dimethyl-1,4,7,10-tetraazabicyclo[6.5.2]pentadecane. Dalton transactions : an international journal of inorganic chemistry / RSoC, 44(27), 12210-12224. https://doi.org/10.1039/c5dt00742a

© The Royal Society of Chemistry 2015. Synthetic details for 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.5.2]pentadecane, the dimethyl ethylene cross-bridged homocyclen ligand are presented for the first time. Its novel Mn 2+ , Fe 2+ , Mn 3+ , and Fe 3+... Read More about Synthesis, structural studies, kinetic stability, and oxidation catalysis of the late first row transition metal complexes of 4,10-dimethyl-1,4,7,10-tetraazabicyclo[6.5.2]pentadecane.

Tetraphenolate niobium and tantalum complexes for the ring opening polymerization of ε-caprolactone (2015)
Journal Article
Al-Khafaji, Y., Sun, X., Prior, T. J., Elsegood, M. R. J., & Redshaw, C. (2015). Tetraphenolate niobium and tantalum complexes for the ring opening polymerization of ε-caprolactone. Dalton transactions : an international journal of inorganic chemistry / RSoC, 44(27), 12349-12356. https://doi.org/10.1039/c5dt00272a

Reaction of the pro-ligand α,α,α′,α′-tetra(3,5-di-tert-butyl-2-hydroxyphenyl-p-)xylene-para-tetraphenol (p-L¹H₄) with two equivalents of [NbCl₅] in refluxing toluene afforded, after work-up, the complex {[NbCl₃(NCMe)]₂(μ-p-L¹)}·6MeCN (1·6MeCN). When... Read More about Tetraphenolate niobium and tantalum complexes for the ring opening polymerization of ε-caprolactone.

Synthesis, structural studies, and oxidation catalysis of the late-first-row-transition-metal complexes of a 2-pyridylmethyl pendant-armed ethylene cross-bridged cyclam (2015)
Journal Article
Jones, D. G., Wilson, K. R., Cannon-Smith, D. J., Shircliff, A. D., Zhang, Z., Chen, Z., …Hubin, T. J. (2015). Synthesis, structural studies, and oxidation catalysis of the late-first-row-transition-metal complexes of a 2-pyridylmethyl pendant-armed ethylene cross-bridged cyclam. Inorganic chemistry, 54(5), 2221-2234. https://doi.org/10.1021/ic502699m

The first 2-pyridylmethyl pendant-armed ethylene cross-bridged cyclam ligand has been synthesized and successfully complexed to Mn²⁺, Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺ cations. X-ray crystal structures were obtained for all six complexes and demonstra... Read More about Synthesis, structural studies, and oxidation catalysis of the late-first-row-transition-metal complexes of a 2-pyridylmethyl pendant-armed ethylene cross-bridged cyclam.

Mono- and tetra-nuclear copper complexes bearing bis(imino)phenoxide derived ligands: catalytic evaluation for benzene oxidation and ROP of ε-caprolactone (2015)
Journal Article
Wang, X., Zhao, K., Elsegood, M. R. J., Prior, T. J., Liu, X., Wu, L., …Redshaw, C. (2015). Mono- and tetra-nuclear copper complexes bearing bis(imino)phenoxide derived ligands: catalytic evaluation for benzene oxidation and ROP of ε-caprolactone. RSC advances, 5(71), 57414-57424. https://doi.org/10.1039/c5ra08696e

Complexes of the type [Cu(L)₂] (1) and [Cu₄L₂(μ₄-O)(OAc)₄] (2) have been obtained from the reaction of the phenoxydiimine 1,3-(2,6-R²₂C₆H₃N=CH)₂-5-R¹ C₆H₂OH-2 (LH) (where R¹ = Me, tBu, Cl; R² = Me, iPr) with copper(II) acetate [Cu(OAc)₂]; changing th... Read More about Mono- and tetra-nuclear copper complexes bearing bis(imino)phenoxide derived ligands: catalytic evaluation for benzene oxidation and ROP of ε-caprolactone.


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