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Machine learning–assisted CO2 utilization in the catalytic dry reforming of hydrocarbons: Reaction pathways and multicriteria optimization analyses (2021)
Journal Article
Lim, J. Y., Loy, A. C. M., Alhazmi, H., Fui, B. C. L., Cheah, K. W., Taylor, M. J., …Yoo, C. K. (in press). Machine learning–assisted CO2 utilization in the catalytic dry reforming of hydrocarbons: Reaction pathways and multicriteria optimization analyses. International journal of energy research, https://doi.org/10.1002/er.7565

The catalytic dry reforming (DR) process is a clean approach to transform CO2 into H2 and CO-rich synthetic gas that can be used for various energy applications such as Fischer–Tropsch fuels production. A novel framework is proposed to determine the... Read More about Machine learning–assisted CO2 utilization in the catalytic dry reforming of hydrocarbons: Reaction pathways and multicriteria optimization analyses.

Support induced effects on the ir nanoparticles activity, selectivity and stability performance under CO<inf>2</inf> reforming of methane (2021)
Journal Article
Nikolaraki, E., Goula, G., Panagiotopoulo, P., Taylor, M. J., Kousi, K., Kyriakou, G., …Yentekakis, I. V. (2021). Support induced effects on the ir nanoparticles activity, selectivity and stability performance under CO2 reforming of methane. Nanomaterials, 11(11), Article 2880. https://doi.org/10.3390/nano11112880

The production of syngas (H2 and CO)—a key building block for the manufacture of liquid energy carriers, ammonia and hydrogen—through the dry (CO2 −) reforming of methane (DRM) continues to gain attention in heterogeneous catalysis, renewable energy... Read More about Support induced effects on the ir nanoparticles activity, selectivity and stability performance under CO<inf>2</inf> reforming of methane.

PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural (2021)
Journal Article
Islam, M. J., Granollers Mesa, M., Osatiashtiani, A., Manayil, J. C., Isaacs, M. A., Taylor, M. J., …Kyriakou, G. (2021). PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural. Applied catalysis. B, Environmental, 299, Article 120652. https://doi.org/10.1016/j.apcatb.2021.120652

Single-atom catalysts serve as a skilful control of precious metals on heterogenous catalysts where all active sites are accessible for catalytic reactions. Here we report the adoption of PdCu single-atom alloys supported on alumina for the selective... Read More about PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural.

Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics (2021)
Journal Article
Cheah, K. W., Yusup, S., Loy, A. C. M., How, B. S., Skoulou, V., & Taylor, M. J. (2021). Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics. Molecular Catalysis, Article 111469. https://doi.org/10.1016/j.mcat.2021.111469

With the inevitable human innate aspirations for better urban mobility and sustainable economic development, bio-based transportation fuels are projected to play an essential role in the foreseeable automotive transportation sector. Agricultural-base... Read More about Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics.

Atom efficient PtCu bimetallic catalysts and ultra dilute alloys for the selective hydrogenation of furfural (2020)
Journal Article
Taylor, M. J., Beaumont, S. K., Islam, M. J., Tsatsos, S., Parlett, C. A., Issacs, M. A., & Kyriakou, G. (2021). Atom efficient PtCu bimetallic catalysts and ultra dilute alloys for the selective hydrogenation of furfural. Applied catalysis. B, Environmental, 284, Article 119737. https://doi.org/10.1016/j.apcatb.2020.119737

A range of Pt:Cu bimetallic nanoparticles were investigated for the liquid-phase selective hydrogenation of furfural, an important platform biomass feedstock. Alloying of the two metals had a profound effect on the overall catalytic activity, providi... Read More about Atom efficient PtCu bimetallic catalysts and ultra dilute alloys for the selective hydrogenation of furfural.

Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step (2020)
Journal Article
Cheah, K. W., Yusup, S., Taylor, M. J., How, B. S., Osatiashtiani, A., Nowakowski, D. J., …Uemura, Y. (2020). Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step. Reaction Chemistry and Engineering, 5(9), 1682-1693. https://doi.org/10.1039/d0re00214c

Herein, for the first time, we demonstrate a novel continuous flow process involving the application of tetralin as a hydrogen donor solvent for the catalytic conversion of oleic acid to diesel-like hydrocarbons, using an efficient and stable carbon... Read More about Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step.

Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation (2020)
Journal Article
Aladbrabalameer, H., Taylor, M. J., Kauppinen, J., Soini, T., Pikkarainen, T., & Skoulou, V. (2020). Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation. Sustainable Energy & Fuels, 4(7), 3764-3772. https://doi.org/10.1039/d0se00155d

Defluidisation as a result of reactor bed agglomeration is a global challenge associated with the gasification of lignocellulosic biomass waste, specifically its high inorganic content. The use of conventional water leaching has been scrutanised for... Read More about Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation.

Probing synergies between lignin-rich and cellulose compounds for gasification (2020)
Journal Article
Taylor, M. J., Michopoulos, A. K., Zabaniotou, A. A., & Skoulou, V. (2020). Probing synergies between lignin-rich and cellulose compounds for gasification. Energies, 13(10), Article 2590. https://doi.org/10.3390/en13102590

The fixed bed gasification of lignin rich and deficient mixtures was carried out to probe the synergistic effects between two model compounds, Lignin Pink (LP) rich in Na and Cellulose Microcrystalline (CM). Reaction conditions utilized the most comm... Read More about Probing synergies between lignin-rich and cellulose compounds for gasification.

The effect of metal precursor on copper phase dispersion and nanoparticle formation for the catalytic transformations of furfural (2020)
Journal Article
Islam, M. J., Granollers Mesa, M., Osatiashtiani, A., Taylor, M. J., Manayil, J. C., Parlett, C. M., …Kyriakou, G. (2020). The effect of metal precursor on copper phase dispersion and nanoparticle formation for the catalytic transformations of furfural. Applied catalysis. B, Environmental, 273, Article 119062. https://doi.org/10.1016/j.apcatb.2020.119062

The formation of copper-based catalysts ranging from nanoparticles to isolated and dimeric Cu species supported on nanophased alumina is reported and utilised for the catalytic liquid-phase hydrogenation of furfural. The materials were synthesised vi... Read More about The effect of metal precursor on copper phase dispersion and nanoparticle formation for the catalytic transformations of furfural.

Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network (2020)
Journal Article
Taylor, M. J., Alabdrabalameer, H. A., Michopoulos, A. K., Volpe, R., & Skoulou, V. (2020). Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network. ACS Sustainable Chemistry and Engineering, 8(14), 5674-5682. https://doi.org/10.1021/acssuschemeng.0c00351

© 2020 American Chemical Society. By augmenting conventional leaching technologies for the removal of ash constituents from lignocellulosic waste residues, a cleaner and energy efficient solution can be provided for critical industrial problems such... Read More about Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network.

Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels (2019)
Journal Article
Taylor, M. J., Alabdrabalameer, H. A., & Skoulou, V. (2019). Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels. Sustainability, 11(13), Article 3604. https://doi.org/10.3390/su11133604

Various methods of physical, chemical and combined physicochemical pre-treatments for biomass waste valorization to value added feedstock for downstream processes in Chemical Industries have been reviewed. Where relevant literature was scrutinized fo... Read More about Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels.

A comprehensive experimental and theoretical study of the CO + NO reaction catalyzed by Au/Ni nanoparticles (2019)
Journal Article
Holgado, J. P., Wheatley, A. E., Kyriakou, G., Márquez, A. M., Holgado, J. P., Taylor, M. J., …Lambert, R. M. (2019). A comprehensive experimental and theoretical study of the CO + NO reaction catalyzed by Au/Ni nanoparticles. ACS Catalysis, 9(6), 4919-4929. https://doi.org/10.1021/acscatal.8b05154

The catalytic and structural properties of five different nanoparticle catalysts with varying Au/Ni composition were studied by six different methods, including in situ X-ray absorption spectroscopy and density functional theory (DFT) calculations. T... Read More about A comprehensive experimental and theoretical study of the CO + NO reaction catalyzed by Au/Ni nanoparticles.

Monometallic and bimetallic catalysts based on Pd, Cu and Ni for hydrogen transfer deoxygenation of a prototypical fatty acid to diesel range hydrocarbons (2019)
Journal Article
Cheah, K. W., Taylor, M. J., Osatiashtiani, A., Beaumont, S. K., Nowakowski, D. J., Yusup, S., …Kyriakou, G. (in press). Monometallic and bimetallic catalysts based on Pd, Cu and Ni for hydrogen transfer deoxygenation of a prototypical fatty acid to diesel range hydrocarbons. Catalysis Today, https://doi.org/10.1016/j.cattod.2019.03.017

Bimetallic PdxNi(100-x) and PdxCu(100-x) structures of a wide compositional range supported on activated carbon were synthesised via a simple, cheap and commercially relevant method. The surface and bulk properties of both the bimetallic structures a... Read More about Monometallic and bimetallic catalysts based on Pd, Cu and Ni for hydrogen transfer deoxygenation of a prototypical fatty acid to diesel range hydrocarbons.

Effect of support oxygen storage capacity on the catalytic performance of Rh nanoparticles for CO2 reforming of methane (2018)
Journal Article
Yentekakis, I. V., Goula, G., Hatzisymeon, M., Betsi-Argyropoulou, I., Botzolaki, G., Kousi, K., …Lambert, R. M. (2019). Effect of support oxygen storage capacity on the catalytic performance of Rh nanoparticles for CO2 reforming of methane. Applied catalysis. B, Environmental, 243, 490-501. https://doi.org/10.1016/j.apcatb.2018.10.048

The effects of the metal oxide support on the activity, selectivity, resistance to carbon deposition and high temperature oxidative aging on the Rh-catalyzed dry reforming of methane (DRM) were investigated. Three Rh catalysts supported on oxides cha... Read More about Effect of support oxygen storage capacity on the catalytic performance of Rh nanoparticles for CO2 reforming of methane.

In-situ hydrogen generation from 1,2,3,4-tetrahydronaphthalene for catalytic conversion of oleic acid to diesel fuel hydrocarbons: Parametric studies using Response Surface Methodology approach (2018)
Journal Article
Cheah, K. W., Yusup, S., Kyriakou, G., Ameen, M., Taylor, M. J., Nowakowski, D. J., …Uemura, Y. (2019). In-situ hydrogen generation from 1,2,3,4-tetrahydronaphthalene for catalytic conversion of oleic acid to diesel fuel hydrocarbons: Parametric studies using Response Surface Methodology approach. International Journal of Hydrogen Energy, 44(37), 20678-20689. https://doi.org/10.1016/j.ijhydene.2018.05.112

This work reported a new strategy in producing synthetic diesel hydrocarbons from a mono-unsaturated fatty acid model compound, oleic acid and replacing high pressure molecular hydrogen with a hydrogen-rich donor solvent, 1,2,3,4–tetrahydronaphthalen... Read More about In-situ hydrogen generation from 1,2,3,4-tetrahydronaphthalene for catalytic conversion of oleic acid to diesel fuel hydrocarbons: Parametric studies using Response Surface Methodology approach.

Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions (2017)
Journal Article
Yentekakis, I., Goula, G., Kampouri, S., Betsi-argyropoulou, I., Panagiotopoulou, P., Taylor, M., …Lambert, R. (2018). Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions. Catalysis Letters, 148(1), 341-347. https://doi.org/10.1007/s10562-017-2233-z

The effect of the morphology of Ir particles supported on γ-Al2O3, 8 mol%Y2O3-stabilized ZrO2 (YSZ), 10 mol%Gd2O3-doped CeO2 (GDC) and 80 wt%Al2O3–10 wt%CeO2–10 wt%ZrO2 (ACZ) on their stability on oxidative conditions, the associated metal–support in... Read More about Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions.

Critical role of oxygen in silver-catalyzed Glaser-Hay coupling on Ag(100) under vacuum and in solution on Ag particles (2017)
Journal Article
Orozco, N., Kyriakou, G., Beaumont, S. K., Fernandez Sanz, J., Holgado, J. P., Taylor, M. J., …Lambert, R. M. (2017). Critical role of oxygen in silver-catalyzed Glaser-Hay coupling on Ag(100) under vacuum and in solution on Ag particles. ACS Catalysis, 7(5), 3113-3120. https://doi.org/10.1021/acscatal.7b00431

The essential role of oxygen in enabling heterogeneously catalyzed Glaser-Hay coupling of phenylacetylene on Ag(100) was elucidated by STM, laboratory and synchrotron photoemission, and DFT calculations. In the absence of coadsorbed oxygen, phenylace... Read More about Critical role of oxygen in silver-catalyzed Glaser-Hay coupling on Ag(100) under vacuum and in solution on Ag particles.

Catalytic hydrogenation and hydrodeoxygenation of Furfural over Pt(111): A model system for the rational design and operation of practical biomass conversion catalysts (2017)
Journal Article
Taylor, M. J., Jiang, L., Reichert, J., Papageorgiou, A. C., Beaumont, S. K., Wilson, K., …Kyriakou, G. (2017). Catalytic hydrogenation and hydrodeoxygenation of Furfural over Pt(111): A model system for the rational design and operation of practical biomass conversion catalysts. Journal of physical chemistry. C, 121(15), 8490-8497. https://doi.org/10.1021/acs.jpcc.7b01744

Furfural is a key bioderived platform chemical whose reactivity under hydrogen atmospheres affords diverse chemical intermediates. Here, temperature-programmed reaction spectrometry and complementary scanning tunneling microscopy (STM) are employed t... Read More about Catalytic hydrogenation and hydrodeoxygenation of Furfural over Pt(111): A model system for the rational design and operation of practical biomass conversion catalysts.

Stabilization of catalyst particles against sintering on oxide supports with high oxygen ion lability exemplified by Ir-catalyzed decomposition of N2O (2016)
Journal Article
Yentekakis, I. V., Goula, G., Panagiotopoulou, P., Kampouri, S., Taylor, M. J., Kyriakou, G., & Lambert, R. M. (2016). Stabilization of catalyst particles against sintering on oxide supports with high oxygen ion lability exemplified by Ir-catalyzed decomposition of N2O. Applied catalysis. B, Environmental, 192, 357-364. https://doi.org/10.1016/j.apcatb.2016.04.011

© 2016 Elsevier B.V.. Iridium nanoparticles deposited on a variety of surfaces exhibited thermal sintering characteristics that were very strongly correlated with the lability of lattice oxygen in the supporting oxide materials. Specifically, the hig... Read More about Stabilization of catalyst particles against sintering on oxide supports with high oxygen ion lability exemplified by Ir-catalyzed decomposition of N2O.

Selective oxidation of cyclohexene through gold functionalized silica monolith microreactors (2015)
Journal Article
Alotaibi, M. T., Taylor, M. J., Liu, D., Beaumont, S. K., & Kyriakou, G. (2016). Selective oxidation of cyclohexene through gold functionalized silica monolith microreactors. Surface science, 646, 179-185. https://doi.org/10.1016/j.susc.2015.10.039

Two simple, reproducible methods of preparing evenly distributed Au nanoparticle containing mesoporous silica monoliths are investigated. These Au nanoparticle containing monoliths are subsequently investigated as flow reactors for the selective oxid... Read More about Selective oxidation of cyclohexene through gold functionalized silica monolith microreactors.