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Empowering clean water whilst safeguarding water distribution pipeline integrity: Towards manganese- and iron-free lime hydrate for water treatment (2023)
Journal Article
Wadhawan, J. D., Kocsis, D., Meyer, C., Ward, R., Thompson, M., Prior, T. J., …Lawrence, N. (2023). Empowering clean water whilst safeguarding water distribution pipeline integrity: Towards manganese- and iron-free lime hydrate for water treatment. Environmental Science: Water Research & Technology, https://doi.org/10.1039/d2ew00109h

Hydrated limes are amongst the most economically valuable alkalis used by the water industry for the treatment of potable water. They are typically manufactured from the thermal decomposition of high purity limestones. However, the latter contain bot... Read More about Empowering clean water whilst safeguarding water distribution pipeline integrity: Towards manganese- and iron-free lime hydrate for water treatment.

Electrochemically Induced Mesomorphism Switching in a Chlorpromazine Hydrochloride Lyotropic Liquid Crystal (2021)
Journal Article
Crapnell, R. D., Alhasan, H. S., Partington, L. I., Zhou, Y., Ahmed, Z., Altalhi, A. A., …Wadhawan, J. D. (2021). Electrochemically Induced Mesomorphism Switching in a Chlorpromazine Hydrochloride Lyotropic Liquid Crystal. ACS Omega, 6(7), 4630-4640. https://doi.org/10.1021/acsomega.0c05284

The discovery of electrochemical switching of the Lα phase of chlorpromazine hydrochloride in water is reported. The phase is characterized using polarizing microscopy, X-ray scattering, rheological measurements, and microelectrode voltammetry. Fast,... Read More about Electrochemically Induced Mesomorphism Switching in a Chlorpromazine Hydrochloride Lyotropic Liquid Crystal.

Lyotropic 'hairy' TiO2 nanorods (2018)
Journal Article
Cheng, F., Verrelli, E., Alharthi, F. A., Kelly, S. M., O'Neill, M., Kemp, N. T., …Anthopoulos, T. (2019). Lyotropic 'hairy' TiO2 nanorods. Nanoscale advances, 1(1), 254-264. https://doi.org/10.1039/c8na00054a

We report the synthesis of the first stable, solution-processable and photocrosslinkable hybrid organic/inorganic titanium dioxide nanorods as ‘hairy rods’ coated with phosphonate ligands with photoreactive coumarin groups located in a terminal posit... Read More about Lyotropic 'hairy' TiO2 nanorods.

Synthesis and antimicrobial effects of highly dispersed, cellulose-stabilized silver/cellulose nanocomposites (2018)
Journal Article
Alahmadi, N. S., Kelly, S. M., Betts, J. W., Heinze, T., Wadhawan, J. D., & Koschella, A. (2018). Synthesis and antimicrobial effects of highly dispersed, cellulose-stabilized silver/cellulose nanocomposites. RSC advances, 8(7), 3646-3656. https://doi.org/10.1039/c7ra12280b

Small, spherical silver nanoclusters were synthesised on the surface of paper as a model cellulosic fibre substrate by a standard chemical reduction method. The concentration of the silver nanoclusters on the substrate surface is roughly proportional... Read More about Synthesis and antimicrobial effects of highly dispersed, cellulose-stabilized silver/cellulose nanocomposites.

Lipase immobilised on silica monoliths as continuous-flow microreactors for triglyceride transesterification (2017)
Journal Article
Alotaibi, M., Manayil, J. C., Greenway, G. M., Haswell, S. J., Kelly, S. M., Lee, A. F., …Kyriakou, G. (2017). Lipase immobilised on silica monoliths as continuous-flow microreactors for triglyceride transesterification. Reaction Chemistry and Engineering, 3(1), 68-74. https://doi.org/10.1039/c7re00162b

Lipase immobilised on silica monoliths has been prepared and applied as biocatalytic continuous-flow microreactors for the transesterification of tributyrin as a model bio-oil component. Candida antarctica lipase was trapped within the pores of silic... Read More about Lipase immobilised on silica monoliths as continuous-flow microreactors for triglyceride transesterification.

Silicon diimide gel as an efficient stationary phase in thin layer chromatography for acid-sensitive organic compounds (2017)
Journal Article
Kitney, S. P., Sajedin, S. M., Rocher, V., Cheng, F., & Kelly, S. M. (2017). Silicon diimide gel as an efficient stationary phase in thin layer chromatography for acid-sensitive organic compounds. Chemical communications : Chem comm / the Royal Society of Chemistry, 53(80), 11080-11082. https://doi.org/10.1039/c7cc04952h

We report the use of mesoporous silicon diimide gel as a basic stationary phase in thin layer chromatography for the characterisation and purification of acid-sensitive compounds. The gel is prepared by a simple sol-gel process and exhibits a large s... Read More about Silicon diimide gel as an efficient stationary phase in thin layer chromatography for acid-sensitive organic compounds.

Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites (2017)
Journal Article
Kelly, S., Kornherr, A., Alahmadi, N. S., Betts, J. W., Francesconi, M. G., Prior, T. J., …Kornherr, A. (2017). Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites. RSC advances, 7(32), 20020-20026. https://doi.org/10.1039/c7ra00920h

© The Royal Society of Chemistry. Green synthesis is employed to prepare cobalt/cellulose nanocomposites with cubic (α-cobalt) cobalt as a main component with antibacterial and magnetic properties. An in situ reduction of aqueous solutions of cobalt... Read More about Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites.

Novel liquid crystalline organic semiconducting oligomers incorporating N-heterocyclic carbazole moieties for fluorescent OLEDs (2017)
Journal Article
Hu, G., Kitney, S. P., Kelly, S. M., Harrison, W., & O’Neill, M. (2017). Novel liquid crystalline organic semiconducting oligomers incorporating N-heterocyclic carbazole moieties for fluorescent OLEDs. Liquid crystals, 44(11), 1632-1645. https://doi.org/10.1080/02678292.2017.1306633

A novel class of nematic liquid crystalline organic semiconducting oligomers incorporating N-heterocyclic carbazole moieties has been synthesised using simple and highly efficient reaction pathways. The electroluminescent colour of these novel oligom... Read More about Novel liquid crystalline organic semiconducting oligomers incorporating N-heterocyclic carbazole moieties for fluorescent OLEDs.

Studies on the sulfation of cellulose α-lipoate and ability of the sulfated product to stabilize colloidal suspensions of gold nanoparticles (2015)
Journal Article
Sarbova, V., Koschella, A., Cheng, F., Kelly, S. M., & Heinze, T. (2015). Studies on the sulfation of cellulose α-lipoate and ability of the sulfated product to stabilize colloidal suspensions of gold nanoparticles. Carbohydrate Polymers, 124, 117-123. https://doi.org/10.1016/j.carbpol.2015.01.080

© 2015 Elsevier Ltd. A versatile method for the synthesis of cellulose α-lipoate with a low degree of substitution (DS) has been developed using N,N-dimethylacetamide (DMA)/LiCl as a solvent and N,N′-carbonyldiimidazole (CDI) as an esterification rea... Read More about Studies on the sulfation of cellulose α-lipoate and ability of the sulfated product to stabilize colloidal suspensions of gold nanoparticles.

Green synthesis of highly concentrated aqueous colloidal solutions of large starch-stabilised silver nanoplatelets (2014)
Journal Article
Cheng, F., Betts, J. W., Kelly, S. M., & Hector, A. L. (2015). Green synthesis of highly concentrated aqueous colloidal solutions of large starch-stabilised silver nanoplatelets. Materials Science and Engineering: C, 46, 530-537. https://doi.org/10.1016/j.msec.2014.10.041

© 2014 Elsevier B.V. All rights reserved. A simple, environmentally friendly and cost-effective method has been developed to prepare a range of aqueous silver colloidal solutions, using ascorbic acid as a reducing agent,water-soluble starch as a comb... Read More about Green synthesis of highly concentrated aqueous colloidal solutions of large starch-stabilised silver nanoplatelets.

UV-stable paper coated with APTES-modified P25 TiO₂ nanoparticles (2014)
Journal Article
Cheng, F., Sajedin, S. M., Kelly, S. M., Lee, A. F., & Kornherr, A. (2014). UV-stable paper coated with APTES-modified P25 TiO₂ nanoparticles. Carbohydrate Polymers, 114, 246-252. https://doi.org/10.1016/j.carbpol.2014.07.076

In order to inhibit the photocatalytic degradation of organic material supports induced by small titania (TiO₂) nanoparticles, highly photocatalytically active, commercially available P25-TiO₂ nanoparticles were first modified with a thin layer of (3... Read More about UV-stable paper coated with APTES-modified P25 TiO₂ nanoparticles.

Whiter, brighter, and more stable cellulose paper coated with antibacterial carboxymethyl starch stabilized ZnO nanoparticles (2014)
Journal Article
Cheng, F., Betts, J. W., Kelly, S. M., Wareham, D. W., Kornherr, A., Dumestre, F., …Heinze, T. (2014). Whiter, brighter, and more stable cellulose paper coated with antibacterial carboxymethyl starch stabilized ZnO nanoparticles. Journal of Materials Chemistry B, 2(20), 3057-3064. https://doi.org/10.1039/c3tb21734e

Small, carboxymethyl-starch-stabilised zinc oxide nanoparticles with a defined shape, size and morphology were prepared in situ in water at relatively low reaction temperatures using soluble carboxymethyl starch (CMS) as a combined crystallising, sta... Read More about Whiter, brighter, and more stable cellulose paper coated with antibacterial carboxymethyl starch stabilized ZnO nanoparticles.

Whiter, brighter, and more stable cellulose paper coated with TiO 2/SiO2 core/shell nanoparticles using a layer-by-layer approach (2013)
Journal Article
Cheng, F., Lorch, M., Sajedin, S. M., Kelly, S. M., & Kornherr, A. (2013). Whiter, brighter, and more stable cellulose paper coated with TiO 2/SiO2 core/shell nanoparticles using a layer-by-layer approach. ChemSusChem, 6(8), 1392-1399. https://doi.org/10.1002/cssc.201300305

To inhibit the photocatalytic degradation of organic material supports induced by small titania (TiO2) nanoparticles, four kinds of TiO2 nanoparticles, that is, commercial P25-TiO2, commercial rutile phase TiO2, rutile TiO2 nanorods and rutile TiO2 s... Read More about Whiter, brighter, and more stable cellulose paper coated with TiO 2/SiO2 core/shell nanoparticles using a layer-by-layer approach.

Synthesis and antibacterial effects of aqueous colloidal solutions of silver nanoparticles using aminocellulose as a combined reducing and capping reagent (2013)
Journal Article
Cheng, F., Betts, J. W., Kelly, S. M., Schaller, J., & Heinze, T. (2013). Synthesis and antibacterial effects of aqueous colloidal solutions of silver nanoparticles using aminocellulose as a combined reducing and capping reagent. Green chemistry : an international journal and green chemistry resource : GC, 15(4), 989-998. https://doi.org/10.1039/c3gc36831a

A simple, environmentally friendly and cost-effective synthetic method has been developed to prepare highly stable aqueous colloidal solutions of small (2-14 nm) silver nanoparticles using aminocellulose (AMC) as a combined reducing and capping reage... Read More about Synthesis and antibacterial effects of aqueous colloidal solutions of silver nanoparticles using aminocellulose as a combined reducing and capping reagent.

Empowering the smart grid: Can redox batteries be matched to renewable energy systems for energy storage? (2013)
Journal Article
Halls, J. E., Hawthornthwaite, A., Hepworth, R. J., Roberts, N. A., Wright, K. J., Zhou, Y., …Wadhawan, J. D. (2013). Empowering the smart grid: Can redox batteries be matched to renewable energy systems for energy storage?. Energy & environmental science, 6(3), 1026-1041. https://doi.org/10.1039/c3ee23708g

The charging of an undivided cerium-zinc redox battery by various current waveforms some of which mimic the output of renewable energy (solar, wind, tidal, biofuel burning) to electricity transducers is considered in this work, where the battery oper... Read More about Empowering the smart grid: Can redox batteries be matched to renewable energy systems for energy storage?.

Voltammetry within structured liquid nanosystems: towards the design of a flexible, three-dimensional framework for artificial photosystems (2012)
Journal Article
Halls, J. E., Wright, K. J., Pickersgill, J. E., Smith, J. P., Altalhi, A. A., Bourne, R. W., …Wadhawan, J. (2012). Voltammetry within structured liquid nanosystems: towards the design of a flexible, three-dimensional framework for artificial photosystems. Electrochimica acta, 70, 215-227. https://doi.org/10.1016/j.electacta.2012.03.052

Normal lyotropic liquid crystals (in the lamellar or hexagonal phases) are investigated as a route to afford a structured, three-dimensional, quasi-biphasic framework within which electron transfer cascades may be initiated voltammetrically. For mode... Read More about Voltammetry within structured liquid nanosystems: towards the design of a flexible, three-dimensional framework for artificial photosystems.

Electrochemistry of organometallic lyotropic chromonic liquid crystals (2012)
Journal Article
Halls, J. E., Bourne, R. W., Wright, K. J., Partington, L. I., Tamba, M. G., Zhou, Y., …Wadhawan, J. D. (2012). Electrochemistry of organometallic lyotropic chromonic liquid crystals. Electrochemistry communications, 19(1), 50-54. https://doi.org/10.1016/j.elecom.2012.02.032

Two aqueous lyotropic chromonic liquid crystals made from nickel(II) or copper(II) phthalocyananine tetrasulfonic acid tetrasodium salt are prepared with characterisation through optical polarising microscopy, X-ray diffraction and conductivity. Thes... Read More about Electrochemistry of organometallic lyotropic chromonic liquid crystals.

Silicon imidonitride aerogel exhibiting macro- and meso-dual porosity (2012)
Journal Article
Rocher, V., Kelly, S. M., & Hector, A. L. (2012). Silicon imidonitride aerogel exhibiting macro- and meso-dual porosity. Microporous and Mesoporous Materials, 156, 196-201. https://doi.org/10.1016/j.micromeso.2012.02.041

Porous silicon imidonitride aerogels have been produced by combining a sol-gel process based on [Si(NH2)(NMe2)3] and ammonia that is known for producing xerogels with controlled mesoporosity, with a supercritical drying process using diethylamine to... Read More about Silicon imidonitride aerogel exhibiting macro- and meso-dual porosity.

Scaling up of continuous-flow, microwave-assisted, organic reactions by varying the size of Pd-functionalized catalytic monoliths (2011)
Journal Article
He, P., Haswell, S. J., Fletcher, P. D., Kelly, S. M., & Mansfield, A. (2011). Scaling up of continuous-flow, microwave-assisted, organic reactions by varying the size of Pd-functionalized catalytic monoliths. Beilstein Journal of Organic Chemistry, 7, 1150-1157. https://doi.org/10.3762/bjoc.7.133

A product-scalable, catalytically mediated flow system has been developed to perform Suzuki-Miyaura reactions under a microwave heating regime, in which the volumetric throughput of a Pd-supported silica monolith can be used to increase the quantity... Read More about Scaling up of continuous-flow, microwave-assisted, organic reactions by varying the size of Pd-functionalized catalytic monoliths.

Preparation, structural characterization, and thermal ammonolysis of two novel dimeric transition silylamide complexes (2011)
Journal Article
Cheng, F., Hope, C. N., Archibald, S. J., Bradley, J. S., Clark, S., Francesconi, M. G., …Lefebvre, F. (2011). Preparation, structural characterization, and thermal ammonolysis of two novel dimeric transition silylamide complexes. International Journal of Applied Ceramic Technology, 8(2), 467-481. https://doi.org/10.1111/j.1744-7402.2009.02452.x

The preparation and molecular structures of two novel dimeric transition metal silylamide complexes {Li0.5Zr[NHSi(NMe2)3]1.5[NSi(NMe2)3]0.5[μ -NSi(NMe2)3]}2 and {Li0.5Hf[NHSi(NMe2)3]1.5[NSi(NMe2)3]0.5[μ-NSi(NMe2)3]}2 with a tetrahedral coordination e... Read More about Preparation, structural characterization, and thermal ammonolysis of two novel dimeric transition silylamide complexes.