All Outputs (17)

Ikaite formation in streams affected by steel waste leachate: First report and potential impact on contaminant dynamics (2023)
Journal Article
Bastianini, L., Rogerson, M., Brasier, A., Prior, T. J., Hardman, K., Dempsey, E., …Mayes, W. M. (2024). Ikaite formation in streams affected by steel waste leachate: First report and potential impact on contaminant dynamics. Chemical Geology, 644, Article 121842. https://doi.org/10.1016/j.chemgeo.2023.121842

Highly alkaline (pH 9–12) waters can arise from a range of globally significant and environmentally impactful industrial processes such as lime, steel and cement production, alumina refining and energy generation (e.g. combustion ashes). Such residue... Read More about Ikaite formation in streams affected by steel waste leachate: First report and potential impact on contaminant dynamics.

What are the different styles of calcite precipitation within a hyperalkaline leachate? A sedimentological Anthropocene case study (2021)
Journal Article
Bastianini, L., Rogerson, M., Mercedes-Martín, R., Prior, T. J., & Mayes, W. M. (in press). What are the different styles of calcite precipitation within a hyperalkaline leachate? A sedimentological Anthropocene case study. The Depositional Record, https://doi.org/10.1002/dep2.168

This study aims to compare the fabrics of anthropogenic carbonates downstream of lime and steel disposal sites with models of carbonate precipitation from natural systems to elucidate potential drivers, precipitation mechanisms, morphological similar... Read More about What are the different styles of calcite precipitation within a hyperalkaline leachate? A sedimentological Anthropocene case study.

Integrating Remediation and Resource Recovery of Industrial Alkaline Wastes: Case Studies of Steel and Alumina Industry Residues (2019)
Book Chapter
Gomes, H. I., Rogerson, M., Courtney, R., & Mayes, W. M. (2020). Integrating Remediation and Resource Recovery of Industrial Alkaline Wastes: Case Studies of Steel and Alumina Industry Residues. In Resource recovery from wastes: towards a circular economy (168-191). Cambridge: Royal Society of Chemistry. https://doi.org/10.1039/9781788016353-00168

With an estimated annual production of two billion tonnes globally, alkaline industrial wastes can be considered both major global waste streams, and materials that offer significant options for potential resource recovery. Alkaline wastes are usuall... Read More about Integrating Remediation and Resource Recovery of Industrial Alkaline Wastes: Case Studies of Steel and Alumina Industry Residues.

What Causes Carbonates to Form “Shrubby” Morphologies? An Anthropocene Limestone Case Study (2019)
Journal Article
Bastianini, L., Rogerson, M., Mercedes-Martín, R., Prior, T. J., Cesar, E. A., & Mayes, W. M. (2019). What Causes Carbonates to Form “Shrubby” Morphologies? An Anthropocene Limestone Case Study. Frontiers in Earth Science, 7, Article 236. https://doi.org/10.3389/feart.2019.00236

The South Atlantic Aptian “Pre-Salt” shrubby carbonate successions offshore Brazil and Angola are of major interest due to their potential hydrocarbon accumulations. Although the general sedimentology of these deposits is widely recognized to be with... Read More about What Causes Carbonates to Form “Shrubby” Morphologies? An Anthropocene Limestone Case Study.

Constructed wetlands for steel slag leachate management: Partitioning of arsenic, chromium, and vanadium in waters, sediments, and plants (2019)
Journal Article
Gomes, H., Mayes, W. M., Whitby, P., & Rogerson, M. (2019). Constructed wetlands for steel slag leachate management: Partitioning of arsenic, chromium, and vanadium in waters, sediments, and plants. Journal of environmental management, 243, 30-38. https://doi.org/10.1016/j.jenvman.2019.04.127

© 2019 The Authors Constructed wetlands can treat highly alkaline leachate resulting from the weathering of steel slag before reuse (e.g. as aggregate)or during disposal in repositories and legacy sites. This study aimed to assess how metal(loid)s s... Read More about Constructed wetlands for steel slag leachate management: Partitioning of arsenic, chromium, and vanadium in waters, sediments, and plants.

Optimization Routes for the Bioleaching of MSWI Fly and Bottom Ashes Using Microorganisms Collected from a Natural System (2019)
Journal Article
Funari, V., Gomes, H. I., Cappelletti, M., Fedi, S., Dinelli, E., Rogerson, M., …Rovere, M. (2019). Optimization Routes for the Bioleaching of MSWI Fly and Bottom Ashes Using Microorganisms Collected from a Natural System. Waste and biomass valorization, 10(12), 3833-3842. https://doi.org/10.1007/s12649-019-00688-9

This paper presents a route for the treatment of MSWI fly (FA) and bottom ashes (BA) using microorganisms to critically assess whether bioleaching is within reach of effective industrial application. The leaching of metals from BA and FA was investig... Read More about Optimization Routes for the Bioleaching of MSWI Fly and Bottom Ashes Using Microorganisms Collected from a Natural System.

Leaching behaviour of co-disposed steel making wastes: Effects of aeration on leachate chemistry and vanadium mobilisation (2018)
Journal Article
Hobson, A. J., Stewart, D. I., Mortimer, R. J., Mayes, W. M., Rogerson, M., & Burke, I. T. (2018). Leaching behaviour of co-disposed steel making wastes: Effects of aeration on leachate chemistry and vanadium mobilisation. Waste Management, 81, 1-10. https://doi.org/10.1016/j.wasman.2018.09.046

Steelmaking wastes stored in landfill, such as slag and spent refractory liners, are often enriched in toxic trace metals (including V). These may become mobile in highly alkaline leachate generated during weathering. Fresh steelmaking waste was char... Read More about Leaching behaviour of co-disposed steel making wastes: Effects of aeration on leachate chemistry and vanadium mobilisation.

Options for managing alkaline steel slag leachate: A life cycle assessment (2018)
Journal Article
Gomes, H. I., Mayes, W. M., Baxter, H. A., Jarvis, A. P., Burke, I. T., Stewart, D. I., & Rogerson, M. (2018). Options for managing alkaline steel slag leachate: A life cycle assessment. Journal of cleaner production, 202, 401-412. https://doi.org/10.1016/j.jclepro.2018.08.163

Management of steel slag (a major by-product of the steel industry) includes the treatment of highly alkaline leachate (pH > 11.5) from rainwater infiltration of slag deposits to prevent adverse impact upon surface or ground waters. This study aims t... Read More about Options for managing alkaline steel slag leachate: A life cycle assessment.

Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate (2018)
Journal Article
Hobson, A. J., Stewart, D. I., Bray, A. W., Mortimer, R. J., Mayes, W. M., Riley, A. L., …Burke, I. T. (2018). Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate. The Science of the total environment, 643, 1191-1199. https://doi.org/10.1016/j.scitotenv.2018.06.272

© 2018 Vanadium is a toxic metal present in alkaline leachates produced during the weathering of steel slags. Slag leaching can therefore have deleterious effects on local watercourses due to metal toxicity, the effects of the high pH (9–12.5) and ra... Read More about Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate.

Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments (2018)
Journal Article
Gomes, H. I., Funari, V., Mayes, W. M., Rogerson, M., & Prior, T. J. (2018). Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments. Journal of environmental management, 222, 30-36. https://doi.org/10.1016/j.jenvman.2018.05.056

Steel slag is a major by-product of the steel industry and a potential resource of technology critical elements. For this study, a basic oxygen furnace (BOF) steel slag was tested for bacterial leaching and recovery of aluminium (Al), chromium (Cr),... Read More about Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments.

Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag (2018)
Journal Article
Stewart, D. I., Bray, A. W., Udoma, G., Hobson, A. J., Mayes, W. M., Rogerson, M., & Burke, I. T. (2018). Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag. Environmental science and pollution research, 25(10), 9861-9872. https://doi.org/10.1007/s11356-018-1260-7

© 2018 The Author(s) Alkalinity generation and toxic trace metal (such as vanadium) leaching from basic oxygen furnace (BOF) steel slag particles must be properly understood and managed by pre-conditioning if beneficial reuse of slag is to be maximis... Read More about Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag.

Hydraulic and biotic impacts on neutralisation of high-pH waters (2017)
Journal Article
Gomes, H. I., Mayes, W. M., Rogerson, M., Burke, I. T., & Stewart, D. I. (2017). Hydraulic and biotic impacts on neutralisation of high-pH waters. The Science of the total environment, 601-602, 1271-1279. https://doi.org/10.1016/j.scitotenv.2017.05.248

The management of alkaline (pH 11–12.5) leachate is an important issue associated with the conditioning, afteruse or disposal of steel slags. Passive in-gassing of atmospheric CO2 is a low cost option for reducing Ca(OH)2 alkalinity, as Ca(OH)2 is ne... Read More about Hydraulic and biotic impacts on neutralisation of high-pH waters.

Removal and recovery of vanadium from alkaline steel slag leachates with anion exchange resins (2016)
Journal Article
Gomes, H. I., Jones, A., Rogerson, M., Greenway, G. M., Lisbona, D. F., Burke, I. T., & Mayes, W. M. (2017). Removal and recovery of vanadium from alkaline steel slag leachates with anion exchange resins. Journal of environmental management, 187, 384-392. https://doi.org/10.1016/j.jenvman.2016.10.063

© 2016 The Author(s) Leachable vanadium (V) from steel production residues poses a potential environmental hazard due to its mobility and toxicity under the highly alkaline pH conditions that characterise these leachates. This work aims to test the e... Read More about Removal and recovery of vanadium from alkaline steel slag leachates with anion exchange resins.

Vanadium removal and recovery from bauxite residue leachates by ion exchange (2016)
Journal Article
Gomes, H. I., Jones, A., Rogerson, M., Burke, I. T., & Mayes, W. M. (2016). Vanadium removal and recovery from bauxite residue leachates by ion exchange. Environmental science and pollution research, 23(22), 23034-23042. https://doi.org/10.1007/s11356-016-7514-3

Bauxite residue is an important by-product of the alumina industry, and current management practices do not allow their full valorisation, especially with regard to the recovery of critical metals. This work aims to test the efficiency of ion exchang... Read More about Vanadium removal and recovery from bauxite residue leachates by ion exchange.

Alkaline residues and the environment: a review of impacts, management practices and opportunities (2015)
Journal Article
Gomes, H. I., Mayes, W. M., Rogerson, M., Stewart, D. I., & Burke, I. T. (2016). Alkaline residues and the environment: a review of impacts, management practices and opportunities. Journal of cleaner production, 112(4), 3571-3582. https://doi.org/10.1016/j.jclepro.2015.09.111

Around two billion tonnes of alkaline residues are produced globally each year by industries such as steel production, alumina refining and coal-fired power generation, with a total production estimate of 90 billion tonnes since industrialisation. Th... Read More about Alkaline residues and the environment: a review of impacts, management practices and opportunities.

Zinc Uptake from Circumneutral Mine Drainage in Freshwater Biofilms: New Insights from In Vitro Experiments (2015)
Journal Article
Jones, A., Rogerson, M., Greenway, G., & Mayes, W. M. (2015). Zinc Uptake from Circumneutral Mine Drainage in Freshwater Biofilms: New Insights from In Vitro Experiments. Mine Water and the Environment, 34(3), 295-307. https://doi.org/10.1007/s10230-015-0325-9

© 2015, Springer-Verlag Berlin Heidelberg. We present results from in vitro flask and flume experiments using freshwater biofilms sourced and cultivated from a mine-impacted stream in North Yorkshire, UK. Flask experiments showed rapid uptake of Zn f... Read More about Zinc Uptake from Circumneutral Mine Drainage in Freshwater Biofilms: New Insights from In Vitro Experiments.

Mine water geochemistry and metal flux in a major historic Pb-Zn-F orefield, the Yorkshire Pennines, UK (2013)
Journal Article
Jones, A., Rogerson, M., Greenway, G., Potter, H. A., & Mayes, W. M. (2013). Mine water geochemistry and metal flux in a major historic Pb-Zn-F orefield, the Yorkshire Pennines, UK. Environmental science and pollution research, 20(11), 7570-7581. https://doi.org/10.1007/s11356-013-1513-4

Recent studies have shown up to 6 % of rivers in England and Wales to be impacted by discharges from abandoned metal mines. Despite the large extent of impacts, there are still many areas where mine water impact assessments are limited by data availa... Read More about Mine water geochemistry and metal flux in a major historic Pb-Zn-F orefield, the Yorkshire Pennines, UK.