All Outputs (5)

Water‐soluble rhenium clusters with triazoles: the effect of chemical structure on cellular internalization and the DNA binding of the complexes (2020)
Journal Article
Konovalov, D. I., Ivanov, A. A., Frolova, T. S., Eltsov, I. V., Gayfulin, Y. M., Plunkett, L., …Shestopalov, M. A. (2020). Water‐soluble rhenium clusters with triazoles: the effect of chemical structure on cellular internalization and the DNA binding of the complexes. Chemistry: a European journal, 26(61), 13904-13914. https://doi.org/10.1002/chem.202001680

Here we explore the effect of the nature of organic ligands in rhenium cluster complexes [Re6Q8L6]4− (where Q=S or Se, and L=benzotriazole, 1,2,3-triazole or 1,2,4-triazole) on the biological properties of the complexes, in particular on the cellular... Read More about Water‐soluble rhenium clusters with triazoles: the effect of chemical structure on cellular internalization and the DNA binding of the complexes.

From photoinduced to dark cytotoxicity via an octahedral cluster hydrolysis (2018)
Journal Article
Svezhentseva, E. V., Vorotnikov, Y. A., Solovieva, A. O., Pozmogova, T. N., Eltsov, I. V., Ivanov, A. A., …Shestopalov, M. A. (2018). From photoinduced to dark cytotoxicity via an octahedral cluster hydrolysis. Chemistry: a European journal, 24(68), 17915-17920. https://doi.org/10.1002/chem.201804663

Octahedral molybdenum and tungsten clusters have potential biological applications in photodynamic therapy and bioimaging. However, poor solubility and hydrolysis stability of these compounds hinder their application. The first water-soluble photolum... Read More about From photoinduced to dark cytotoxicity via an octahedral cluster hydrolysis.

Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity (2018)
Journal Article
Chen, L., Vivier, E., Eling, C. J., Babra, T. S., Bouillard, J. S. G., Adawi, A. M., …Greenland, B. W. (2018). Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity. Synthetic Metals, 241, 31-38. https://doi.org/10.1016/j.synthmet.2018.03.019

© 2018 An iterative synthesis has been used to produce conjugated, monodisperse, viologen-based aromatic oligomers containing up to 12 aromatic/heterocyclic rings. The methoxy-substituted oligomers were soluble in common organic solvents and could be... Read More about Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity.

23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] – (2017)
Journal Article
Syrokvashin, M. M., Vorotnikova, N. A., Vorotnikov, Y. A., Novozhilov, I. N., Syrokvashin, M. М., Nadolinny, V. A., …Efremova, O. A. (2018). 23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –. Inorganic chemistry, 57(2), https://doi.org/10.1021/acs.inorgchem.7b02760

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare clust... Read More about 23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –.

Octahedral molybdenum cluster complexes with aromatic sulfonate ligands (2016)
Journal Article
Efremova, O. A., Vorotnikov, Y. A., Brylev, K. A., Vorotnikova, N. A., Novozhilov, I. N., Kuratieva, N. V., …Sutherland, A. J. (2016). Octahedral molybdenum cluster complexes with aromatic sulfonate ligands. Dalton Transactions : an international journal of inorganic chemistry, 45(39), 15427-15435. https://doi.org/10.1039/c6dt02863b

This article describes the synthesis, structures and systematic study of the spectroscopic and redox properties of a series of octahedral molybdenum metal cluster complexes with aromatic sulfonate ligands (ⁿBu₄N)₂[{Mo₆X₈}(OTs)₆] and (ⁿBu₄N)₂[{Mo₆X₈}(... Read More about Octahedral molybdenum cluster complexes with aromatic sulfonate ligands.