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Synthesis of graphene-encapsulated Fe3C/Fe catalyst supported on Sporopollenin exine capsules, and its use for the reverse water gas shift reaction (2023)
Journal Article
Malik, W., Tafoya, J. . P. V., Doszczeczko, S., Jorge Sobrido, A. B., Skoulou, V., Boa, A. N., …Volpe, R. (in press). Synthesis of graphene-encapsulated Fe3C/Fe catalyst supported on Sporopollenin exine capsules, and its use for the reverse water gas shift reaction. ACS Sustainable Chemistry and Engineering,

Bioderived materials have emerged as sustainable catalyst supports for several heterogeneous reactions owing to their naturally occurring hierarchal pore size distribution, high surface area, and thermal and chemical stability. We utilize sporopollen... Read More about Synthesis of graphene-encapsulated Fe3C/Fe catalyst supported on Sporopollenin exine capsules, and its use for the reverse water gas shift reaction.

A Multidisciplinary Approach for an Effective and Rational Energy Transition in Crete Island, Greece (2022)
Journal Article
Katsaprakakis, D., Michopoulos, A., Skoulou, V., Dakanali, I., Maragkaki, A., Pappa, S., …Contaxakis, C. (2022). A Multidisciplinary Approach for an Effective and Rational Energy Transition in Crete Island, Greece. Energies, 15(9), Article 3010. https://doi.org/10.3390/en15093010

This article proposes a mixture of actions for the development of an effective and rational energy transition plan for all sectors and for all types of onshore final energy use in Crete. Energy transition is initiated with an appropriate capacity bui... Read More about A Multidisciplinary Approach for an Effective and Rational Energy Transition in Crete Island, Greece.

Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics (2021)
Journal Article
Cheah, K. W., Yusup, S., Loy, A. C. M., How, B. S., Skoulou, V., & Taylor, M. J. (2021). Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics. Molecular Catalysis, Article 111469. https://doi.org/10.1016/j.mcat.2021.111469

With the inevitable human innate aspirations for better urban mobility and sustainable economic development, bio-based transportation fuels are projected to play an essential role in the foreseeable automotive transportation sector. Agricultural-base... Read More about Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics.

Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step (2020)
Journal Article
Cheah, K. W., Yusup, S., Taylor, M. J., How, B. S., Osatiashtiani, A., Nowakowski, D. J., …Uemura, Y. (2020). Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step. Reaction Chemistry and Engineering, 5(9), 1682-1693. https://doi.org/10.1039/d0re00214c

Herein, for the first time, we demonstrate a novel continuous flow process involving the application of tetralin as a hydrogen donor solvent for the catalytic conversion of oleic acid to diesel-like hydrocarbons, using an efficient and stable carbon... Read More about Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step.

Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation (2020)
Journal Article
Aladbrabalameer, H., Taylor, M. J., Kauppinen, J., Soini, T., Pikkarainen, T., & Skoulou, V. (2020). Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation. Sustainable Energy & Fuels, 4(7), 3764-3772. https://doi.org/10.1039/d0se00155d

Defluidisation as a result of reactor bed agglomeration is a global challenge associated with the gasification of lignocellulosic biomass waste, specifically its high inorganic content. The use of conventional water leaching has been scrutanised for... Read More about Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation.

Probing synergies between lignin-rich and cellulose compounds for gasification (2020)
Journal Article
Taylor, M. J., Michopoulos, A. K., Zabaniotou, A. A., & Skoulou, V. (2020). Probing synergies between lignin-rich and cellulose compounds for gasification. Energies, 13(10), Article 2590. https://doi.org/10.3390/en13102590

The fixed bed gasification of lignin rich and deficient mixtures was carried out to probe the synergistic effects between two model compounds, Lignin Pink (LP) rich in Na and Cellulose Microcrystalline (CM). Reaction conditions utilized the most comm... Read More about Probing synergies between lignin-rich and cellulose compounds for gasification.

Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network (2020)
Journal Article
Taylor, M. J., Alabdrabalameer, H. A., Michopoulos, A. K., Volpe, R., & Skoulou, V. (2020). Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network. ACS Sustainable Chemistry and Engineering, 8(14), 5674-5682. https://doi.org/10.1021/acssuschemeng.0c00351

© 2020 American Chemical Society. By augmenting conventional leaching technologies for the removal of ash constituents from lignocellulosic waste residues, a cleaner and energy efficient solution can be provided for critical industrial problems such... Read More about Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network.

Towards circular economy solutions for the management of rice processing residues to bioenergy via gasification (2019)
Journal Article
Vaskalis, I., Skoulou, V., Stavropoulos, G., & Zabaniotou, A. (2019). Towards circular economy solutions for the management of rice processing residues to bioenergy via gasification. Sustainability, 11(22), Article 6433. https://doi.org/10.3390/su1122643

An economic assessment of two circular economy scenarios of fluidized bed gasification-based systems for combined heat and power (CHP) generation, fueled with rice processing wastes, was conducted. In the first scenario, the gasification plant with a... Read More about Towards circular economy solutions for the management of rice processing residues to bioenergy via gasification.

Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels (2019)
Journal Article
Taylor, M. J., Alabdrabalameer, H. A., & Skoulou, V. (2019). Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels. Sustainability, 11(13), Article 3604. https://doi.org/10.3390/su11133604

Various methods of physical, chemical and combined physicochemical pre-treatments for biomass waste valorization to value added feedstock for downstream processes in Chemical Industries have been reviewed. Where relevant literature was scrutinized fo... Read More about Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels.

Synergistic effects of lignin and cellulose during pyrolysis of agricultural waste. (2018)
Journal Article
Volpe, R., Zabaniotou, A. A., & Skoulou, V. (2018). Synergistic effects of lignin and cellulose during pyrolysis of agricultural waste. Energy and Fuels, 32(8), 8420-8430. https://doi.org/10.1021/acs.energyfuels.8b00767

© 2018 American Chemical Society. Varying lignin and cellulose contents in agro-waste cause feed-stock to respond differently during their thermochemical conversion. The effect of pyrolysis temperature (400, 500, 600oC) and feedstock composition on p... Read More about Synergistic effects of lignin and cellulose during pyrolysis of agricultural waste..

Investigation and simulation of the transport of gas containing mercury in microporous silica membranes (2018)
Journal Article
Ji, G., George, A., Skoulou, V., Reed, G., Millan, M., Hooman, K., …Diniz da Costa, J. C. (2018). Investigation and simulation of the transport of gas containing mercury in microporous silica membranes. Chemical engineering science, 190, 286-296. https://doi.org/10.1016/j.ces.2018.06.006

This work investigates the effect of condensable Hg vapour on the transport of N2 gas across cobalt oxide silica (CoOxSi) membranes. Experimental results suggest that Hg significantly affects N2 permeation at 100 and 200°C, though this effect is negl... Read More about Investigation and simulation of the transport of gas containing mercury in microporous silica membranes.

Wheat straw bio-refining. Part II: Optimization of the microwave radiation with sulphuric acid pre-treatment and its enzymatic hydrolysis for fermentable sugars (2017)
Journal Article
Festus, O., Skoulou, V. K., & Zein, S. H. (2017). Wheat straw bio-refining. Part II: Optimization of the microwave radiation with sulphuric acid pre-treatment and its enzymatic hydrolysis for fermentable sugars. Current Microwave Chemistry, 4(4), 306-316. https://doi.org/10.2174/2213335604666171103123459

Background: The potential of microwave-assisted heating for enhancing the alkaline pretreatment of lignocellulosic waste is highlighted in this work. Objective: To maximize separation of fermentable sugars from wheat straw. Methods: Wheat straw... Read More about Wheat straw bio-refining. Part II: Optimization of the microwave radiation with sulphuric acid pre-treatment and its enzymatic hydrolysis for fermentable sugars.

Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment (2017)
Journal Article
Demirhan, H., Fauzi, A., Skoulou, V. . K., Haywood, S. . . H., & Zein, S. . . H. (2017). Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment. Current Microwave Chemistry, 4(3), https://doi.org/10.2174/2213335604666170719113659

Background: This study investigates the microwave-assisted acid extraction of lignin from wheat straw. Methods: Two experimental design methods, the Central Composite Design (CCD) and the Response Surface Method (RSM) methods were used to select c... Read More about Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment.

Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment (2017)
Journal Article
Demirhan, H., Fauzi, A., Skoulou, V., Haywood, S., & Zein, S. H. (2017). Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment. Current Microwave Chemistry, 4(3), 205-218. https://doi.org/10.2174/2213335604666170719113659

Background: This study investigates the microwave-assisted acid extraction of lignin from wheat straw. Methods: Two experimental design methods, the Central Composite Design (CCD) and the Response Surface Method (RSM) methods were used to select c... Read More about Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment.

Possibilities of upgrading solid underutilized lingo-cellulosic feedstock (carob pods) to liquid bio-fuel: Bio-ethanol production and electricity generation in fuel cells - A critical appraisal of the required processes (2017)
Journal Article
Skoulou, V. K., & Vourdoubas, J. (2017). Possibilities of upgrading solid underutilized lingo-cellulosic feedstock (carob pods) to liquid bio-fuel: Bio-ethanol production and electricity generation in fuel cells - A critical appraisal of the required processes. Studies in Engineering and Technology, 4(1), 25-34. https://doi.org/10.11114/set.v4i1.2170

The exploitation of rich in sugars lingo-cellulosic residue of carob pods for bio-ethanol and bio-electricity generation has been investigated. The process could take place in two (2) or three (3) stages including: a) bio-ethanol production originate... Read More about Possibilities of upgrading solid underutilized lingo-cellulosic feedstock (carob pods) to liquid bio-fuel: Bio-ethanol production and electricity generation in fuel cells - A critical appraisal of the required processes.

Case study of viability of bioenergy production from landfill gas (LFG) (2016)
Journal Article
Vourdoubas, J., & Skoulou, V. K. (2016). Case study of viability of bioenergy production from landfill gas (LFG). Journal of Agricultural Science, 8(10), 165-176. https://doi.org/10.5539/jas.v8n10p165

The landfill gas (LFG) produced from the existing landfill site in Heraklion city, Crete island, Greece, is not currently exploited to its full potential. It could however be exploited for power generation and/or combined heat and power (CHP) product... Read More about Case study of viability of bioenergy production from landfill gas (LFG).

Co-gasification of crude glycerol with lignocellulosic biomass for enhanced syngas production (2012)
Journal Article
Skoulou, V. K., & Zabaniotou, A. A. (2013). Co-gasification of crude glycerol with lignocellulosic biomass for enhanced syngas production. Journal of Analytical and Applied Pyrolysis, 99, 110-116. https://doi.org/10.1016/j.jaap.2012.10.015

The present work concerns the co-gasification of crude glycerol (CG), a by-product of biodiesel industry, with locally available lignocellulosic biomass aiming at the production of syngas and further promotion of power production in dedicated bioener... Read More about Co-gasification of crude glycerol with lignocellulosic biomass for enhanced syngas production.

H2 enriched fuels from co-pyrolysis of crude glycerol with biomass (2012)
Journal Article
Skoulou, V., Manara, P., & Zabaniotou, A. (2012). H2 enriched fuels from co-pyrolysis of crude glycerol with biomass. Journal of Analytical and Applied Pyrolysis, 97, 198-204. https://doi.org/10.1016/j.jaap.2012.05.011

Pyrolysis of glycerol has been identified as a possible route for producing high added value fuels like renewable hydrogen (H 2 ). Crude glycerol (CG) is the main byproduct of biodiesel industry and without purification it is a low added value materi... Read More about H2 enriched fuels from co-pyrolysis of crude glycerol with biomass.

Fe catalysis for lignocellulosic biomass conversion to fuels and materials via thermochemical processes (2012)
Journal Article
Skoulou, V., & Zabaniotou, A. (2012). Fe catalysis for lignocellulosic biomass conversion to fuels and materials via thermochemical processes. Catalysis Today, 196(1), 56-66. https://doi.org/10.1016/j.cattod.2012.03.035

Recently, international research is aiming at developing gasification and pyrolysis processes for the cost-effective thermochemical conversion of non-food biomass to biofuels. Gasification produces a mixture of carbon monoxide and hydrogen, known as... Read More about Fe catalysis for lignocellulosic biomass conversion to fuels and materials via thermochemical processes.

Integrated environmental assessment of energy crops for biofuel and energy production in Greece (2012)
Journal Article
Fontaras, G., Skoulou, V., Zanakis, G., Zabaniotou, A., & Samaras, Z. (2012). Integrated environmental assessment of energy crops for biofuel and energy production in Greece. Renewable energy, 43, 201-209. https://doi.org/10.1016/j.renene.2011.12.010

This paper attempts an integrated environmental assessment of certain crops, their products and by-products, which are promoted in Greece, as potential raw materials for liquid biofuel and low carbon energy production. The analysis is based on the ex... Read More about Integrated environmental assessment of energy crops for biofuel and energy production in Greece.