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Machine learning–assisted CO2 utilization in the catalytic dry reforming of hydrocarbons: Reaction pathways and multicriteria optimization analyses (2021)
Journal Article
Lim, J. Y., Loy, A. C. M., Alhazmi, H., Fui, B. C. L., Cheah, K. W., Taylor, M. J., …Yoo, C. K. (in press). Machine learning–assisted CO2 utilization in the catalytic dry reforming of hydrocarbons: Reaction pathways and multicriteria optimization analyses. International journal of energy research, https://doi.org/10.1002/er.7565

The catalytic dry reforming (DR) process is a clean approach to transform CO2 into H2 and CO-rich synthetic gas that can be used for various energy applications such as Fischer–Tropsch fuels production. A novel framework is proposed to determine the... Read More about Machine learning–assisted CO2 utilization in the catalytic dry reforming of hydrocarbons: Reaction pathways and multicriteria optimization analyses.

Asymmetric and Anharmonic Electrode Kinetics: Evaluation of a Model for Electron Transfer with Concerted Rupture of Weak, Inner Shell Interactions (2021)
Journal Article
Lawrence, N. S., Schöllhorn, B., & Wadhawan, J. D. (2021). Asymmetric and Anharmonic Electrode Kinetics: Evaluation of a Model for Electron Transfer with Concerted Rupture of Weak, Inner Shell Interactions. ChemistrySelect, 6(46), 13331-13335. https://doi.org/10.1002/slct.202103526

A surface-integrated form of the widely used (anharmonic) Lennard-Jones 12–6 interaction potential, the Lennard-Jones 9–3 potential, is used to develop a quadratic activation/driving force relationship that gives rise to asymmetric Tafel plots for el... Read More about Asymmetric and Anharmonic Electrode Kinetics: Evaluation of a Model for Electron Transfer with Concerted Rupture of Weak, Inner Shell Interactions.

Modelling mass transport within the membrane of direct contact membrane distillation modules used for desalination and wastewater treatment: Scrutinising assumptions (2021)
Journal Article
Ismail, M. S., Mohamed, A. M., Poggio, D., Walker, M., & Pourkashanian, M. (2022). Modelling mass transport within the membrane of direct contact membrane distillation modules used for desalination and wastewater treatment: Scrutinising assumptions. Journal of Water Process Engineering, 45, Article 102460. https://doi.org/10.1016/j.jwpe.2021.102460

A two-dimensional numerical model for a direct contact membrane distillation (DCMD) module, mostly used for desalination and wastewater treatment, has been created. This model has been used to explore the sensitivity of the simulated transmembrane fl... Read More about Modelling mass transport within the membrane of direct contact membrane distillation modules used for desalination and wastewater treatment: Scrutinising assumptions.

Fully-developed laminar flow in trapezoidal ducts with rounded corners: a numerical solution and case study (2021)
Journal Article
Ismail, M. S., Berber, M. R., Alrowaili, Z. A., & Pourkashanian, M. (2022). Fully-developed laminar flow in trapezoidal ducts with rounded corners: a numerical solution and case study. International Journal of Numerical Methods for Heat and Fluid Flow, 32(8), 2682-2699. https://doi.org/10.1108/HFF-09-2021-0620

Purpose: This paper aims to numerically solve fully developed laminar flow in trapezoidal ducts with rounded corners which result following forming processes. Design/methodology/approach: A two-dimensional model for a trapezoidal duct with rounded co... Read More about Fully-developed laminar flow in trapezoidal ducts with rounded corners: a numerical solution and case study.

Support induced effects on the ir nanoparticles activity, selectivity and stability performance under CO<inf>2</inf> reforming of methane (2021)
Journal Article
Nikolaraki, E., Goula, G., Panagiotopoulo, P., Taylor, M. J., Kousi, K., Kyriakou, G., …Yentekakis, I. V. (2021). Support induced effects on the ir nanoparticles activity, selectivity and stability performance under CO2 reforming of methane. Nanomaterials, 11(11), Article 2880. https://doi.org/10.3390/nano11112880

The production of syngas (H2 and CO)—a key building block for the manufacture of liquid energy carriers, ammonia and hydrogen—through the dry (CO2 −) reforming of methane (DRM) continues to gain attention in heterogeneous catalysis, renewable energy... Read More about Support induced effects on the ir nanoparticles activity, selectivity and stability performance under CO<inf>2</inf> reforming of methane.

In situ recalibration of ion selective electrodes (2021)
Journal Article
Wadhawan, J. D., Sisodia, N., Lawrence, N. S., & McGuinness, K. L. (2022). In situ recalibration of ion selective electrodes. Sensors and Diagnostics, 1(1), 134-138. https://doi.org/10.1039/d1sd00003a

Reference electrode drift resulting from the exchange of ions at the solution/reference electrode chamber interface is the number one reason why ion selective electrodes and pH sensors in particular require recalibration, costing companies up to 70%... Read More about In situ recalibration of ion selective electrodes.

Unravelling the Occurrence of Mediator-Blood Protein Interactions via the Redox Catalysis of the Physiological Gasotransmitter Hydrogen Sulfide (2021)
Journal Article
Ward, H. J., Ward, R. A., Lawrence, N. S., & Wadhawan, J. D. (2021). Unravelling the Occurrence of Mediator-Blood Protein Interactions via the Redox Catalysis of the Physiological Gasotransmitter Hydrogen Sulfide. ChemistrySelect, 6(37), 10059-10062. https://doi.org/10.1002/slct.202102974

Ferrocenemethanol is employed as an aqueous, homogeneous redox mediator for hydrogen sulfide. The reaction is seen to follow an EC’ mechanism over the range 6≤pH≤9, with bisulfide reacting four times more rapidly than hydrogen sulfide. In the presenc... Read More about Unravelling the Occurrence of Mediator-Blood Protein Interactions via the Redox Catalysis of the Physiological Gasotransmitter Hydrogen Sulfide.

Promoted N[triple bond]N activation by oxygen and boosted ammonia production over Bi4O5Br2 (2021)
Journal Article
Yuan, C., Lu, Z., Jiang, W., Ibhadon, A. O., & Teng, F. (2021). Promoted N[triple bond]N activation by oxygen and boosted ammonia production over Bi4O5Br2. Molecular Catalysis, 515, Article 111913. https://doi.org/10.1016/j.mcat.2021.111913

Nitrogen photoreduction method is recognized as a safe, environmentally friendly and sustainable technology for ammonia production. For this method, nevertheless, it is a big challenge to efficaciously activate the N[tbnd]N triple bond. In this work,... Read More about Promoted N[triple bond]N activation by oxygen and boosted ammonia production over Bi4O5Br2.

Enhanced clearing of Candida biofilms on a 3D urothelial cell in vitro model using lysozyme-functionalized fluconazole-loaded shellac nanoparticles (2021)
Journal Article
Wang, A., Weldrick, P. J., Madden, L. A., & Paunov, V. N. (2021). Enhanced clearing of Candida biofilms on a 3D urothelial cell in vitro model using lysozyme-functionalized fluconazole-loaded shellac nanoparticles. Biomaterials science / Royal Society of Chemistry, 9(20), 6927-6939. https://doi.org/10.1039/d1bm01035b

Candida urinary tract biofilms are increasingly witnessed in nosocomial infections due to reduced immunity of patients and the hospital ecosystem. The indwelling devices utilized to support patients with urethral diseases that connect the unsterilize... Read More about Enhanced clearing of Candida biofilms on a 3D urothelial cell in vitro model using lysozyme-functionalized fluconazole-loaded shellac nanoparticles.

Identification of soluble tissue‑derived biomarkers from human thyroid tissue explants maintained on a microfluidic device (2021)
Journal Article
Riley, A., Jones, H., England, J., Kuvshinov, D., Green, V., & Greenman, J. (2021). Identification of soluble tissue‑derived biomarkers from human thyroid tissue explants maintained on a microfluidic device. Oncology Letters, 22(5), Article 780. https://doi.org/10.3892/ol.2021.13041

Although a large cohort of potential biomarkers for thyroid cancer aggressiveness have been tested in various formats in recent years, to the best of our knowledge, thyro‑ globulin and calcitonin remain the only two established biomarkers associated... Read More about Identification of soluble tissue‑derived biomarkers from human thyroid tissue explants maintained on a microfluidic device.

An experimental study on the effect of gas injection configuration on flow characteristics in high viscosity oil columns (2021)
Journal Article
Mohammed, S. K., Hasan, A. H., Ibrahim, A., & Dimitrakis, G. (in press). An experimental study on the effect of gas injection configuration on flow characteristics in high viscosity oil columns. The Canadian journal of chemical engineering, https://doi.org/10.1002/cjce.24312

Gas-viscous liquid bubbly and slug flow are very common in petroleum, chemical, bioengineering, polymer, and food processing. However, there is a major knowledge gap in two-phase flow research in the design of gas injectors/distributers in very high... Read More about An experimental study on the effect of gas injection configuration on flow characteristics in high viscosity oil columns.

Alkoxy-functionalized schiff-base ligation at aluminum and zinc: Synthesis, structures and rop capability (2021)
Journal Article
Zhang, X., Chen, K., Chicoma, M., Goins, K., Prior, T. J., Nile, T. A., & Redshaw, C. (2021). Alkoxy-functionalized schiff-base ligation at aluminum and zinc: Synthesis, structures and rop capability. Catalysts, 11(9), Article 1090. https://doi.org/10.3390/catal11091090

The Schiff-base compounds 2,4-di-tert-butyl-6-(((3,4,5-trimethoxyphenyl)imino)methyl)phenol (L1H), 2,4-di-tert-butyl-6-(((2,4,6-trimethoxyphenyl)imino)methyl)phenol (L2H), 2,4-di-tert-butyl-6-(((2,4-trimethoxyphenyl)imino)methyl)phenol) (L3H) derived... Read More about Alkoxy-functionalized schiff-base ligation at aluminum and zinc: Synthesis, structures and rop capability.

PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural (2021)
Journal Article
Islam, M. J., Granollers Mesa, M., Osatiashtiani, A., Manayil, J. C., Isaacs, M. A., Taylor, M. J., …Kyriakou, G. (2021). PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural. Applied catalysis. B, Environmental, 299, Article 120652. https://doi.org/10.1016/j.apcatb.2021.120652

Single-atom catalysts serve as a skilful control of precious metals on heterogenous catalysts where all active sites are accessible for catalytic reactions. Here we report the adoption of PdCu single-atom alloys supported on alumina for the selective... Read More about PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural.

Pyrolyzing soft template-containing poly(ionic liquid) into hierarchical N-doped porous carbon for electroreduction of carbon dioxide (2021)
Journal Article
Sun, M., Bian, Z., Cui, W., Zhao, X., Dong, S., Ke, X., …Wang, J. (2022). Pyrolyzing soft template-containing poly(ionic liquid) into hierarchical N-doped porous carbon for electroreduction of carbon dioxide. Chinese Journal of Chemical Engineering, 43, 192-201. https://doi.org/10.1016/j.cjche.2021.07.020

Heteroatom-doped carbon materials have demonstrated great potential in the electrochemical reduction reaction of CO2 (CO2RR) due to their versatile structure and function. However, rational structure control remains one challenge. In this work, we re... Read More about Pyrolyzing soft template-containing poly(ionic liquid) into hierarchical N-doped porous carbon for electroreduction of carbon dioxide.

Effect of composition and structure of gas diffusion layer and microporous layer on the through-plane gas permeability of PEFC porous media (2021)
Journal Article
Neehall, N. D., Ismail, M. S., Hughes, K. J., & Pourkashanian, M. (2021). Effect of composition and structure of gas diffusion layer and microporous layer on the through-plane gas permeability of PEFC porous media. International journal of energy research, 45(15), 20988-21005. https://doi.org/10.1002/er.7158

The through-plane permeability of the gas diffusion media (GDM) is investigated experimentally with regard to the microporous layer (MPL) composition and the gas diffusion layer (GDL) composition and structure. The MPL composition is held constant at... Read More about Effect of composition and structure of gas diffusion layer and microporous layer on the through-plane gas permeability of PEFC porous media.

Transmission of butanol isomers in pervaporation based on series resistance model (2021)
Journal Article
Zuo, C., Hindley, J., Ding, X., Gronnow, M., Xing, W., & Ke, X. (2021). Transmission of butanol isomers in pervaporation based on series resistance model. Journal of membrane science, 638, Article 119702. https://doi.org/10.1016/j.memsci.2021.119702

Pervaporation (PV) has shown great potential in the separation of butanol aqueous solutions due to their economic and environmental benefits. This work applies polydimethylsiloxane (PDMS) composite membrane to separate four butanol isomers (n-butanol... Read More about Transmission of butanol isomers in pervaporation based on series resistance model.

Ultra-small FeS2nanoparticles for highly efficient chemoselective transfer hydrogenation of nitroarenes (2021)
Journal Article
Southouse, J. P., Lazzarini, L., Ibhadon, A. O., & Francesconi, M. G. (2021). Ultra-small FeS2nanoparticles for highly efficient chemoselective transfer hydrogenation of nitroarenes. New journal of chemistry = Nouveau journal de chimie, 45(38), 17808-17815. https://doi.org/10.1039/d1nj03297f

Ultra-small FeS2nanoparticles were prepared and used as catalysts in a hydrogen transfer reaction for the synthesis of substituted anilines. The catalytic performance is superior to current systems across all reactions, within the timeframe of two ho... Read More about Ultra-small FeS2nanoparticles for highly efficient chemoselective transfer hydrogenation of nitroarenes.

Design and Techno-economic assessment of a new hybrid system of a solar dish Stirling engine instegrated with a horizontal axis wind turbine for microgrid power generation (2021)
Journal Article
Shboul, B., AL-Arfi, I., Michailos, S., Ingham, D., AL-Zoubi, O. H., Ma, L., …Pourkashanian, M. (2021). Design and Techno-economic assessment of a new hybrid system of a solar dish Stirling engine instegrated with a horizontal axis wind turbine for microgrid power generation. Energy Conversion and Management, 245, Article 114587. https://doi.org/10.1016/j.enconman.2021.114587

The increasing interest in renewable microgrids have motivated the exploration of more sustainable alternatives to traditional energy supply. In this study, a novel hybrid renewable energy-based microgrid power system is proposed, designed and techno... Read More about Design and Techno-economic assessment of a new hybrid system of a solar dish Stirling engine instegrated with a horizontal axis wind turbine for microgrid power generation.

Crystallization Fouling in Domestic Appliances and Systems (2021)
Journal Article
Al-Gailani, A., Charpentier, T. V., Sanni, O., & Neville, A. (in press). Crystallization Fouling in Domestic Appliances and Systems. Heat Transfer Engineering, https://doi.org/10.1080/01457632.2021.1963091

Formation of mineral scale, particularly calcium carbonate, has long been a concern in domestic appliances such as boilers, steamers and washing machines. In this work, the formation of inorganic deposits was studied on solid surfaces and in the bulk... Read More about Crystallization Fouling in Domestic Appliances and Systems.

Interaction of temperature, salinity and extracellular polymeric substances controls trace element incorporation into tufa calcite (2021)
Journal Article
Rogerson, M., Pedley, H. M., Greenway, G. M., & Wadhawan, J. D. (in press). Interaction of temperature, salinity and extracellular polymeric substances controls trace element incorporation into tufa calcite. The Depositional Record, https://doi.org/10.1002/dep2.160

The influence of extracellular polymeric substances on carbonate mineral growth in natural settings remains one of the most poorly understood contributors to the growth of non-marine carbonate sediments. The influences of these materials are complica... Read More about Interaction of temperature, salinity and extracellular polymeric substances controls trace element incorporation into tufa calcite.