Skip to main content

Research Repository

Advanced Search

All Outputs (1)

Vanadium complexes derived from oxacalix[6]arenes: structural studies and use in the ring opening homo-/co-polymerization of ε-caprolactone/δ-valerolactone and ethylene polymerization (2020)
Journal Article
Xing, T., Prior, T. J., Elsegood, M. R. J., Semikolenova, N. V., Soshnikov, I. E., Bryliakov, K. P., …Redshaw, C. (2021). Vanadium complexes derived from oxacalix[6]arenes: structural studies and use in the ring opening homo-/co-polymerization of ε-caprolactone/δ-valerolactone and ethylene polymerization. Catalysis science & technology, 11(2), 624-636. https://doi.org/10.1039/d0cy01979h

Reaction of Na[VO(tBuO)4] (generated in-situ from VOCl3 and NaOtBu) with p-tert-butyltetrahomodioxacalix[6]areneH6 (L1H6) afforded, after work-up (in MeCN), the mixed-metal complex [(VO)2(μ-O)Na2(L1)(MeCN)4]·5(MeCN) (1·5MeCN), whilst the oxo complex... Read More about Vanadium complexes derived from oxacalix[6]arenes: structural studies and use in the ring opening homo-/co-polymerization of ε-caprolactone/δ-valerolactone and ethylene polymerization.