Vanadyl calix[6]arene complexes: Synthesis, structural studies and ethylene homo-(co-)polymerization capability
(2015)
Journal Article
Redshaw, C., Walton, M., Michiue, K., Chao, Y., Walton, A., Elo, P., Sumerin, V., Jiang, C., & Elsegood, M. R. J. (2015). Vanadyl calix[6]arene complexes: Synthesis, structural studies and ethylene homo-(co-)polymerization capability. Dalton Transactions : an international journal of inorganic chemistry, 44(27), 12292-12303. https://doi.org/10.1039/c5dt00376h
Treatment of p-tert-butylcalix[6]areneH₆ (L⁶H₆) with in situ [LiVO(Ot-Bu)₄] afforded, after work-up, the dark green complex [Li(MeCN)₄][V₂(O)₂Li(MeCN)(L⁶H₂)₂]·8MeCN (1·8MeCN). On one occasion, the reaction led to the formation of a mixture of product... Read More about Vanadyl calix[6]arene complexes: Synthesis, structural studies and ethylene homo-(co-)polymerization capability.