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23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] – (2017)
Journal Article
Syrokvashin, M. M., Vorotnikova, N. A., Vorotnikov, Y. A., Novozhilov, I. N., Syrokvashin, M. М., Nadolinny, V. A., …Efremova, O. A. (2018). 23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –. Inorganic chemistry, 57(2), https://doi.org/10.1021/acs.inorgchem.7b02760

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare clust... Read More

One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction (2017)
Journal Article
Vorotnikova, N. A., Edeleva, M. V., Kurskaya, O. G., Brylev, K. A., Shestopalov, A. M., Mironov, Y. V., …Shestopalov, M. A. (2017). One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction. Polymer international, 66(12), 1906-1912. https://doi.org/10.1002/pi.5473

© 2017 Society of Chemical Industry Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology... Read More

A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes (2017)
Journal Article
Evtushok, D. V., Melnikov, A. R., Vorotnikova, N. A., Vorotnikov, Y. A., Ryadun, A. A., Kuratieva, N. V., …Shestopalov, M. A. (2017). A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes. Dalton transactions : an international journal of inorganic chemistry / RSoC, 46(35), 11738-11747. https://doi.org/10.1039/c7dt01919j

© 2017 The Royal Society of Chemistry. Octahedral metal cluster complexes have high potential for biomedical applications. In order to evaluate the benefits of these moieties for combined CT/X-ray luminescence computed tomography, this paper compares... Read More

A comparative study of hydrophilic phosphine hexanuclear rhenium cluster complexes’ toxicity (2017)
Journal Article
Krasilnikova, A. A., Solovieva, A. O., Ivanov, A. A., Brylev, K. A., Pozmogova, T. N., Gulyaeva, M. A., …Shestopalov, M. A. (2017). A comparative study of hydrophilic phosphine hexanuclear rhenium cluster complexes’ toxicity. Toxicology Research, 6(4), 554-560. https://doi.org/10.1039/c7tx00083a

Octahedral rhenium cluster compound Na2H8[{Re6Se8}(P(C2H4CONH2)(C2H4COO)2)6] has recently emerged as a very promising X-ray contrast agent for biomedical applications. However, the synthesis of this compound is rather challenging due to difficulty to... Read More

Water-soluble hybrid materials based on {Mo₆X₈}⁴⁺ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate (2017)
Journal Article
Solovieva, A. O., Vorotnikov, Y. A., Svezhentseva, E. V., Kurskaya, O. G., Brylev, K. A., Tsygankova, A. R., …Vorotnikov, Y. (2017). Water-soluble hybrid materials based on {Mo₆X₈}⁴⁺ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate. New journal of chemistry = Nouveau journal de chimie, 41(4), 1670-1676. https://doi.org/10.1039/c6nj03469a

Development of water-soluble forms of octahedral molybdenum clusters {Mo₆X₈}⁴⁺ (X = Cl, Br, I) is strongly motivated by the tremendous potential that these complexes have for biological applications, namely as agents for bioimaging and photodynamic t... Read More

Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ₈}Clᵃ₆}²⁻ (M = Mo, W) : synthesis and thermal stability studies (2017)
Journal Article
Evtushok, D. V., Vorotnikova, N. A., Logvinenko, V. A., Smolentsev, A. I., Brylev, K. A., Plyusnin, P. E., …Shestopalov, M. A. (2017). Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ₈}Clᵃ₆}²⁻ (M = Mo, W) : synthesis and thermal stability studies. New journal of chemistry = Nouveau journal de chimie, 41(24), 14855-14861. https://doi.org/10.1039/c7nj02858j

Luminescent coordination polymers (CPs) based of inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphor... Read More