All Outputs (6)

Pentamethylcyclopentadienyl molybdenum(V) complexes derived from iodoanilines: Synthesis, structure, and rop of ε-caprolactone (2021)
Journal Article
Xing, T., Elsegood, M. R. J., Dale, S. H., & Redshaw, C. (2021). Pentamethylcyclopentadienyl molybdenum(V) complexes derived from iodoanilines: Synthesis, structure, and rop of ε-caprolactone. Catalysts, 11(12), Article 1554. https://doi.org/10.3390/catal11121554

The reaction of [Mo(η-C5Me5 )Cl4 ] with the ortho-, meta-, or para-iodo-functionalized anilines 2-IC6H4NH2, 3-IC6H4NH2, 4-IC6H4NH2 yields imido or amine products of the type [Mo(ηC5Me5 )Cl2 (IC6H4N)] (2-I, 1, 3-I, 3, 4-I, 5) or [Mo(η-C5Me5 )Cl4 (IC6H... Read More about Pentamethylcyclopentadienyl molybdenum(V) complexes derived from iodoanilines: Synthesis, structure, and rop of ε-caprolactone.

Lithiated Calix[ n]arenes (n = 6 or 8): Synthesis, Structures, and Use in the Ring-Opening Polymerization of Cyclic Esters (2021)
Journal Article
Xing, T., Jiang, C., Elsegood, M. R. J., & Redshaw, C. (2021). Lithiated Calix[ n]arenes (n = 6 or 8): Synthesis, Structures, and Use in the Ring-Opening Polymerization of Cyclic Esters. Inorganic chemistry, https://doi.org/10.1021/acs.inorgchem.1c02192

A variety of lithiated calix[n]arenes, for which n = 6 or 8, have been isolated, structurally characterized, and evaluated as catalysts for the ring-opening polymerization (ROP) of the cyclic esters ϵ-caprolactone (ϵ-CL), δ-valerolactone (δ-VL), and... Read More about Lithiated Calix[ n]arenes (n = 6 or 8): Synthesis, Structures, and Use in the Ring-Opening Polymerization of Cyclic Esters.

Lead calix[n]arenes (n = 4, 6, 8): Structures and ring opening homo-/co-polymerization capability for cyclic esters (2021)
Journal Article
Xing, T., Prior, T. J., & Redshaw, C. (2021). Lead calix[n]arenes (n = 4, 6, 8): Structures and ring opening homo-/co-polymerization capability for cyclic esters. Dalton Transactions : an international journal of inorganic chemistry, 50(42), 15140-15152. https://doi.org/10.1039/d1dt02790e

Reaction of [LiPb(OiPr)3]2 (generated in situ) with either p-tert-butylcalix[4]areneH4 (L4H4) or p-tert-butylcalix[6]areneH6 (L6H6) resulted in the heterometallic lithium/lead complexes [Pb4Li2(L4)4H6(MeCN)3]·4.5MeCN (1·4.5MeCN) and [Pb8Li10Cl2(L6H2)... Read More about Lead calix[n]arenes (n = 4, 6, 8): Structures and ring opening homo-/co-polymerization capability for cyclic esters.

New pre-catalysts derived from calixarenes : synthesis, structural and polymerization studies (2021)
Thesis
Xing, T. (2021). New pre-catalysts derived from calixarenes : synthesis, structural and polymerization studies. (Thesis). University of Hull. Retrieved from https://hull-repository.worktribe.com/output/4223659

In this thesis, a series of V, Ti, Li and Pb compounds have been synthesized and fully characterized. The catalytic performance of these pre-catalysts towards different polymerization reactions, including ring opening polymerization (ROP) of cyclic e... Read More about New pre-catalysts derived from calixarenes : synthesis, structural and polymerization studies.

Titanium complexes bearing oxa- and azacalix[4, 6]arenes: structural studies and use in the ring opening homo-/co-polymerization of cyclic esters. (2021)
Journal Article
Xing, T., Prior, T. J., Chen, K., & Redshaw, C. (2021). Titanium complexes bearing oxa- and azacalix[4, 6]arenes: structural studies and use in the ring opening homo-/co-polymerization of cyclic esters. Dalton Transactions : an international journal of inorganic chemistry, 50(12), 4396-4407. https://doi.org/10.1039/d1dt00189b

Reaction of excess [Ti(OiPr)4] with p-tert-butyltetrahomodioxacalix[6]areneH6 (L1H6) afforded, after work-up (MeCN), the complex [Ti2(OiPr)2(MeCN)L1]∙3.5MeCN (1∙3.5MeCN), whilst the oxo complex [Ti4(3-O)2(H2O)(L1)2]∙MeCN (2∙MeCN) was isolated via a... Read More about Titanium complexes bearing oxa- and azacalix[4, 6]arenes: structural studies and use in the ring opening homo-/co-polymerization of cyclic esters..

Co-polymerization of propylene oxide and CO2 using early transition metal (groups IV and V) metallocalix[n]arenes (n = 4, 6, 8) (2021)
Journal Article
Sun, Y. C., He, Z. H., Wang, Z. Y., Xing, T., Wang, Z., Sun, Y., …Redshaw, C. (in press). Co-polymerization of propylene oxide and CO2 using early transition metal (groups IV and V) metallocalix[n]arenes (n = 4, 6, 8). Journal of Applied Polymer Science, Article 50513. https://doi.org/10.1002/app.50513

A number of metallocalix[n]arenes, where n = 4, 6, or 8, of titanium and vanadium have been screened for their ability to act as catalysts for the co‐polymerization of propylene oxide and CO2 to form cyclic/polycarbonates. The vanadium‐containing cat... Read More about Co-polymerization of propylene oxide and CO2 using early transition metal (groups IV and V) metallocalix[n]arenes (n = 4, 6, 8).