pH-responsive gas–water–solid interface for multiphase catalysis (2015)
Journal Article
Binks, B. P., Cheng, F., Huang, J., & Yang, H. (2015). pH-responsive gas–water–solid interface for multiphase catalysis. Journal of the American Chemical Society, 137(47), 15015-15025. https://doi.org/10.1021/jacs.5b09790

© 2015 American Chemical Society. Despite their wide utility in laboratory synthesis and industrial fabrication, gas-water-solid multiphase catalysis reactions often suffer from low reaction efficiency because of the low solubility of gases in water.... Read More about pH-responsive gas–water–solid interface for multiphase catalysis.

Switchable opening and closing of a liquid marble via ultrasonic levitation (2015)
Journal Article
Zang, D., Li, J., Chen, Z., Zhai, Z., Geng, X., & Binks, B. P. (2015). Switchable opening and closing of a liquid marble via ultrasonic levitation. Langmuir : the ACS journal of surfaces and colloids, 31(42), 11502-11507. https://doi.org/10.1021/acs.langmuir.5b02917

Liquid marbles have promising applications in the field of microreactors, where the opening and closing of their surfaces plays a central role. We have levitated liquid water marbles using an acoustic levitator and, thereby, achieved the manipulation... Read More about Switchable opening and closing of a liquid marble via ultrasonic levitation.

Stabilization of Pickering Emulsions with Oppositely Charged Latex Particles: Influence of Various Parameters and Particle Arrangement around Droplets (2015)
Journal Article
Nallamilli, T., Binks, B. P., Mani, E., & Basavaraj, M. G. (2015). Stabilization of Pickering Emulsions with Oppositely Charged Latex Particles: Influence of Various Parameters and Particle Arrangement around Droplets. Langmuir : the ACS journal of surfaces and colloids, 31(41), 11200-11208. https://doi.org/10.1021/acs.langmuir.5b02443

© 2015 American Chemical Society. In this study we explore the fundamental aspects of Pickering emulsions stabilized by oppositely charged particles. Using oppositely charged latex particles as a model system, Pickering emulsions with good long-term... Read More about Stabilization of Pickering Emulsions with Oppositely Charged Latex Particles: Influence of Various Parameters and Particle Arrangement around Droplets.

Mechanical compression to characterize the robustness of liquid marbles (2015)
Journal Article
Liu, Z., Fu, X., Binks, B. P., & Shum, H. C. (2015). Mechanical compression to characterize the robustness of liquid marbles. Langmuir : the ACS journal of surfaces and colloids, 31(41), 11236-11242. https://doi.org/10.1021/acs.langmuir.5b02792

In this work, we have devised a new approach to measure the critical pressure that a liquid marble can withstand. A liquid marble is gradually squeezed under a mechanical compression applied by two parallel plates. It ruptures at a sufficiently large... Read More about Mechanical compression to characterize the robustness of liquid marbles.

Particles at oil–air surfaces : powdered oil, liquid oil marbles, and oil foam (2015)
Journal Article
Binks, B. P., Johnston, S. K., Sekine, T., & Tyowua, A. T. (2015). Particles at oil–air surfaces : powdered oil, liquid oil marbles, and oil foam. ACS Applied Materials & Interfaces, 7(26), 14328-14337. https://doi.org/10.1021/acsami.5b02890

The type of material stabilized by four kinds of fluorinated particles (sericite and bentonite platelet clays and spherical zinc oxide) in air–oil mixtures has been investigated. It depends on the particle wettability and the degree of shear. Upon vi... Read More about Particles at oil–air surfaces : powdered oil, liquid oil marbles, and oil foam.

Self-propulsion of liquid marbles: Leidenfrost-like levitation driven by marangoni flow (2015)
Journal Article
Bormashenko, E., Bormashenko, Y., Grynyov, R., Aharoni, H., Whyman, G., & Binks, B. P. (2015). Self-propulsion of liquid marbles: Leidenfrost-like levitation driven by marangoni flow. Journal of physical chemistry. C, 119(18), 9910-9915. https://doi.org/10.1021/acs.jpcc.5b01307

Self-propulsion of liquid marbles filled with aqueous alcohol solutions and placed on a water surface is reported. The characteristic velocity of the marbles is ca. 0.1 m/s. The phenomenon of self-propulsion is related to the Marangoni solutocapillar... Read More about Self-propulsion of liquid marbles: Leidenfrost-like levitation driven by marangoni flow.

CO2 capture by dry alkanolamines and an efficient microwave regeneration process (2015)
Journal Article
Yang, J., Tan, H. Y., Low, Q. X., Binks, B. P., & Chin, J. M. (2015). CO2 capture by dry alkanolamines and an efficient microwave regeneration process. Journal of Materials Chemistry A, 3(12), 6440-6446. https://doi.org/10.1039/c4ta06273f

Removal of acidic gases such as H2S and CO2 is performed during the purification of raw natural gas, most commonly using amine gas treatment. However, this industrially entrenched method is limited by significant shortcomings including low operationa... Read More about CO2 capture by dry alkanolamines and an efficient microwave regeneration process.

How polymer additives reduce the pour point of hydrocarbon solvents containing wax crystals (2015)
Journal Article
Binks, B. P., Fletcher, P. D. I., Roberts, N. A., Dunkerley, J., Greenfield, H., Mastrangelo, A., & Trickett, K. (2015). How polymer additives reduce the pour point of hydrocarbon solvents containing wax crystals. Physical chemistry chemical physics : PCCP, 17(6), 4107-4117. https://doi.org/10.1039/c4cp04329d

We have investigated how four different pour point depressant (PPD) polymers affect the pour point transition in mixtures of a single pure wax in a solvent. We used either n-eicosane (C20), CH3(CH2)18CH3, n-tetracosane (C24), CH3(CH2)22CH3 or n-hexat... Read More about How polymer additives reduce the pour point of hydrocarbon solvents containing wax crystals.

Compartmentalization of incompatible reagents within Pickering emulsion droplets for one-pot cascade reactions (2014)
Journal Article
Yang, H., Fu, L., Wei, L., Liang, J., & Binks, B. P. (2015). Compartmentalization of incompatible reagents within Pickering emulsion droplets for one-pot cascade reactions. Journal of the American Chemical Society, 137(3), 1362-1371. https://doi.org/10.1021/ja512337z

It is a dream that future synthetic chemistry can mimic living systems to process multistep cascade reactions in a one-pot fashion. One of the key challenges is the mutual destruction of incompatible or opposing reagents, for example, acid and base,... Read More about Compartmentalization of incompatible reagents within Pickering emulsion droplets for one-pot cascade reactions.

Emulsions stabilised by whey protein microgel particles: Towards food-grade Pickering emulsions (2014)
Journal Article
Destribats, M., Rouvet, M., Gehin-Delval, C., Schmitt, C., & Binks, B. P. (2014). Emulsions stabilised by whey protein microgel particles: Towards food-grade Pickering emulsions. Soft matter, 10(36), 6941-6954. https://doi.org/10.1039/c4sm00179f

We have investigated a new class of food-grade particles, whey protein microgels, as stabilisers of triglyceride-water emulsions. The sub-micron particles stabilized oil-in-water emulsions at all pH with and without salt. All emulsions creamed but ex... Read More about Emulsions stabilised by whey protein microgel particles: Towards food-grade Pickering emulsions.

Adsorption of benzyldimethyldodecylammonium chloride onto stainless steel using the quartz crystal microbalance and the depletion methods: An optimisation study (2014)
Journal Article
Salama, I. E., Binks, B. P., Fletcher, P. D. I., & Horsup, D. I. (2014). Adsorption of benzyldimethyldodecylammonium chloride onto stainless steel using the quartz crystal microbalance and the depletion methods: An optimisation study. Colloids and surfaces. A, Physicochemical and engineering aspects, 447, 155-165. https://doi.org/10.1016/j.colsurfa.2014.01.034

The adsorption behaviour of benzyldimethyldodecylammonium chloride (C12BDMAC) corrosion inhibitor from aqueous solutions onto a stainless steel surface has been investigated using the quartz crystal microbalance (QCM) technique and the depletion-HPLC... Read More about Adsorption of benzyldimethyldodecylammonium chloride onto stainless steel using the quartz crystal microbalance and the depletion methods: An optimisation study.

Dry oil powders and oil foams stabilised by fluorinated clay platelet particles (2013)
Journal Article
Binks, B. P., Sekine, T., & Tyowua, A. T. (2014). Dry oil powders and oil foams stabilised by fluorinated clay platelet particles. Soft matter, 10(4), 578-589. https://doi.org/10.1039/c3sm52748d

A series of platelet sericite particles coated to different extents with a fluorinating agent has been characterised and their behaviour in mixtures with air and oil studied. The material which forms by vigorous shaking depends on both the surface te... Read More about Dry oil powders and oil foams stabilised by fluorinated clay platelet particles.

Electrostatically gated membrane permeability in inorganic protocells (2013)
Journal Article
Li, M., Harbron, R. L., Weaver, J. V., Binks, B. P., & Mann, S. (2013). Electrostatically gated membrane permeability in inorganic protocells. Nature Chemistry, 5(6), 529-536. https://doi.org/10.1038/nchem.1644

Although several strategies are now available to produce functional microcompartments analogous to primitive cell-like structures, little progress has been made in generating protocell constructs with self-controlled membrane permeability. Here we de... Read More about Electrostatically gated membrane permeability in inorganic protocells.

Influence of the degree of fluorination on the behaviour of silica particles at air–oil surfaces (2012)
Journal Article
Binks, B. P., & Tyowua, A. T. (2012). Influence of the degree of fluorination on the behaviour of silica particles at air–oil surfaces. Soft matter, 9(3), 834-845. https://doi.org/10.1039/C2SM27395K

We study the behaviour of fumed silica particles coated to different extents with a perfluoro-alkoxysilane in mixtures of air and liquid, for liquids ranging from non-polar hydrocarbons and polar oils to glycerol and water. Comparisons are made with... Read More about Influence of the degree of fluorination on the behaviour of silica particles at air–oil surfaces.

How membrane permeation is affected by donor delivery solvent (2012)
Journal Article
Binks, B. P., Fletcher, P. D., Johnson, A. J., & Elliott, R. P. (2012). How membrane permeation is affected by donor delivery solvent. Physical chemistry chemical physics : PCCP, 14(44), 15525-15538. https://doi.org/10.1039/c2cp42747h

We investigate theoretically and experimentally how the rate and extent of membrane permeation is affected by switching the donor delivery solvent from water to squalane for different permeants and membranes. In a model based on rate-limiting membran... Read More about How membrane permeation is affected by donor delivery solvent.

Sequestration of edible oil from emulsions using new single and double layered microcapsules from plant spores (2012)
Journal Article
Diego-Taboada, A., Cousson, P., Raynaud, E., Huang, Y., Lorch, M., Binks, B., …Mackenzie, G. (2012). Sequestration of edible oil from emulsions using new single and double layered microcapsules from plant spores. Journal of Materials Chemistry, 22(19), 9767-9773. https://doi.org/10.1039/c2jm00103a

Microcapsules were obtained conveniently from Lycopodium clavatum spores possessing either a single layered shell of sporopollenin (exine) or double layered shell of sporopollenin and cellulose with an inner layer (intine). These microcapsules were f... Read More about Sequestration of edible oil from emulsions using new single and double layered microcapsules from plant spores.

Membrane permeation of testosterone from either solutions, particle dispersions, or particle-stabilized emulsions (2012)
Journal Article
Elliott, R. P., Johnson, A. J., Fletcher, P. D. I., & Binks, B. P. (2012). Membrane permeation of testosterone from either solutions, particle dispersions, or particle-stabilized emulsions. Langmuir : the ACS journal of surfaces and colloids, 28(5), 2510-2522. https://doi.org/10.1021/la204755m

We derive a unified model that accounts for the variation in extent and rate of membrane permeation by a permeating species with the type of donor compartment formulation (aqueous and oil solutions, particle dispersions, and oil-in-water and water-in... Read More about Membrane permeation of testosterone from either solutions, particle dispersions, or particle-stabilized emulsions.

Oil Powders and Gels from Particle-Stabilized Emulsions (2012)
Journal Article
Adelmann, H., Binks, B. P., & Mezzenga, R. (2012). Oil Powders and Gels from Particle-Stabilized Emulsions. Langmuir : the ACS journal of surfaces and colloids, 28(3), 1694-1697. https://doi.org/10.1021/la204811c

We report on the use of silica particle-stabilized oil-in-water emulsions as a template for the preparation of oil powders and gels obtained in a single step by either slow or rapid evaporation of water using freeze-drying or spray-drying, respective... Read More about Oil Powders and Gels from Particle-Stabilized Emulsions.

Particle stabilization of oil-in-water-in-air materials: Powdered emulsions (2012)
Journal Article
Murakami, R., Moriyama, H., Yamamoto, M., Binks, B. P., & Rocher, A. (2012). Particle stabilization of oil-in-water-in-air materials: Powdered emulsions. Advanced materials, 24(6), 767-771. https://doi.org/10.1002/adma.201104089

Drops of a particle-stabilised oil-in-water emulsion are encapsulated in air by using hydrophobic silica particles. Such systems, termed oil-in-water-in-air powdered emulsions, show free-flowing behavior. Successful preparation of the material is ach... Read More about Particle stabilization of oil-in-water-in-air materials: Powdered emulsions.

Multiple phase inversion of emulsions stabilized by in situ surface activation of CaCO3 Nanoparticles via Adsorption of Fatty Acids (2011)
Journal Article
Cui, Z. -., Cui, C. -., Zhu, Y., & Binks, B. P. (2012). Multiple phase inversion of emulsions stabilized by in situ surface activation of CaCO3 Nanoparticles via Adsorption of Fatty Acids. Langmuir : the ACS journal of surfaces and colloids, 28(1), 314-320. https://doi.org/10.1021/la204021v

The in situ surface activation of raw CaCO3 nanoparticles by interaction with a series of sodium carboxylates of chain length between 6 and 12 as well as sodium 2-ethylhexylsulfosuccinate (AOT) was studied, and the impact of this on the stabilization... Read More about Multiple phase inversion of emulsions stabilized by in situ surface activation of CaCO3 Nanoparticles via Adsorption of Fatty Acids.