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Cyclotrimerization of alkynes catalyzed by a self-supported cyclic tri-nuclear nickel(0) complex with α-diimine ligands (2019)
Journal Article
Shen, L., Zhao, Y., Luo, Q., Li, Q., Liu, B., Redshaw, C., …Yang, X. (2019). Cyclotrimerization of alkynes catalyzed by a self-supported cyclic tri-nuclear nickel(0) complex with α-diimine ligands. Dalton transactions : an international journal of inorganic chemistry / RSoC, 48(14), 4643-4649. https://doi.org/10.1039/c9dt00819e

A cyclic tri-nuclear α-diimine nickel(0) complex [{Ni(μ-LMe-2,4)}3] (2) was synthesized from a “pre-organized”, trimerized trigonal LNiBr2-type precursor [Ni3(μ2-Br)3(μ3-Br)2(LMe-2,4)3]·Br (1; LMe-2,4 = [(2,4-Me2C6H3)NC(Me)]2). In complex 2, the α-di... Read More