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Hexaazide octahedral molybdenum cluster complexes: synthesis, properties and the evidence of hydrolysis (2016)
Journal Article
Vorotnikov, Y. A., Efremova, O. A., Novozhilov, I. N., Yanshole, V. V., Kuratieva, N. V., Brylev, K. A., …Shestopalov, M. A. (2017). Hexaazide octahedral molybdenum cluster complexes: synthesis, properties and the evidence of hydrolysis. Journal of molecular structure, 1134, 237-243. https://doi.org/10.1016/j.molstruc.2016.12.052

This article reports the synthesis, crystal structure of new molybdenum hexaazide cluster complex (ⁿBu₄N)₂[{Mo₆I₈}(N₃)₆] (3) and comparison of its photophysical and electrochemical properties to those of earlier reported analogues (ⁿBu₄N)₂[{M₆X₈}(N₃)... Read More about Hexaazide octahedral molybdenum cluster complexes: synthesis, properties and the evidence of hydrolysis.

Structure and electronic properties of the quasi-one-dimensional Ba₂Co₁₋ₓZnₓS₃ series (2016)
Journal Article
Harrison, M. R., Maignan, A., Hardy, V., Lebedev, O. L., Young, N. A., & Francesconi, M. G. (2017). Structure and electronic properties of the quasi-one-dimensional Ba₂Co₁₋ₓZnₓS₃ series. Inorganic chemistry, 56(1), 213-223. https://doi.org/10.1021/acs.inorgchem.6b02014

This work focuses on the structure and physical properties of the solid solution Ba₂Co₁₋ₓZnₓS₃ (0 ≤ x ≤ 1), a family of quasi-one-dimensional sulfides with end members Ba₂CoS₃ and Ba₂ZnS₃. The structure of selected compounds with increasing Zn²⁺ cont... Read More about Structure and electronic properties of the quasi-one-dimensional Ba₂Co₁₋ₓZnₓS₃ series.

Synthesis of mono-O-alkylated homooxacalix[3]arene and a protection–deprotection strategy for homooxacalix[3]arene (2016)
Journal Article
Wu, C., Ikejiri, Y., Zeng, X., Elsegood, M. R., Redshaw, C., & Yamato, T. (2017). Synthesis of mono-O-alkylated homooxacalix[3]arene and a protection–deprotection strategy for homooxacalix[3]arene. Organic Letters, 19(1), 66-69. https://doi.org/10.1021/acs.orglett.6b03338

The regioselective synthesis of mono-O-alkylated homooxacalix[3]arene is accomplished for the first time. The synthetic route relies on two key steps: (i) a facile protection of two OH groups at the lower rim of the homooxacalix[3]arene and (ii) th... Read More about Synthesis of mono-O-alkylated homooxacalix[3]arene and a protection–deprotection strategy for homooxacalix[3]arene.

D-π-D chromophores based on dithieno[3,2-b:2′,3'-d]thiophene (DTT) : potential application in the fabrication of solar cell (2016)
Journal Article
Akther, T., Feng, X., Elsegood, M. R., Elsegood, M. R., Wang, C., Do, J., …Yamato, T. (2017). D-π-D chromophores based on dithieno[3,2-b:2′,3'-d]thiophene (DTT) : potential application in the fabrication of solar cell. Tetrahedron, 73(4), 307-312. https://doi.org/10.1016/j.tet.2016.11.077

In this work, four stable dithieno[3,2-b:2′,3'-d]thiophene-based π-extended molecules were designed and synthesized via a Pd-catalysed Sonogashira coupling reaction. The structures of these symmetrical compounds, including dithieno[3,2-b:2′,3'-d]thio... Read More about D-π-D chromophores based on dithieno[3,2-b:2′,3'-d]thiophene (DTT) : potential application in the fabrication of solar cell.

Structural classification of quasi-one-dimensional ternary nitrides (2016)
Journal Article
Headspith, D., Headspith, D. A., & Francesconi, M. G. (2016). Structural classification of quasi-one-dimensional ternary nitrides. Inorganics, 4(4), Article 37. https://doi.org/10.3390/inorganics4040037

This review focuses on the crystal structural features of ternary (mixed-metal) quasi-one-dimensional nitrides i.e., nitrides containing (cation-³⁻) coordination polyhedra sharing either corners, edges, or faces, arranged in linear chains, and interc... Read More about Structural classification of quasi-one-dimensional ternary nitrides.

Twist-bend nematic phase in cyanobiphenyls and difluoroterphenyls bimesogens (2016)
Journal Article
Panov, V. P., Vij, J. K., & Mehl, G. H. (2017). Twist-bend nematic phase in cyanobiphenyls and difluoroterphenyls bimesogens. Liquid crystals, 44(1), 147-159. https://doi.org/10.1080/02678292.2016.1254289

The paper reviews assignment of the low-temperature nematic phase observed in simple bimesogenic or dimeric systems based on cyanobiphenyls and difluoroterphenyls to the twist-bend nematic phase, NTB, using a range of experimental techniques. These i... Read More about Twist-bend nematic phase in cyanobiphenyls and difluoroterphenyls bimesogens.

Polymorphism and solid−gas/solid−solid reactions of isonicotinic acid, isonicotinamide, and nicotinamide copper chloride compounds (2016)
Journal Article
Fellows, S. M., & Prior, T. J. (2017). Polymorphism and solid−gas/solid−solid reactions of isonicotinic acid, isonicotinamide, and nicotinamide copper chloride compounds. Crystal growth & design, 17(1), 106-116. https://doi.org/10.1021/acs.cgd.6b01295

The crystal structures of eight new copper chloride coordination complexes with substituted pyridines have been determined through a combination of single crystal X-ray diffraction and ab initio structure solution from X-ray powder diffraction data.... Read More about Polymorphism and solid−gas/solid−solid reactions of isonicotinic acid, isonicotinamide, and nicotinamide copper chloride compounds.

Light scattering study of the “pseudo-layer” compression elastic constant in a twist-bend nematic liquid crystal (2016)
Journal Article
Parsouzi, Z., Pardaev, S. A., Welch, C., Ahmed, Z., Mehl, G. H., Baldwin, A. R., …Sprunt, S. (2016). Light scattering study of the “pseudo-layer” compression elastic constant in a twist-bend nematic liquid crystal. Physical chemistry chemical physics : PCCP, 18(46), 31645-31652. https://doi.org/10.1039/C6CP06292J

The nematic twist-bend (TB) phase, exhibited by certain achiral thermotropic liquid crystalline (LC) dimers, features a nanometer-scale, heliconical rotation of the average molecular long axis (director) with equally probable left- and right-handed d... Read More about Light scattering study of the “pseudo-layer” compression elastic constant in a twist-bend nematic liquid crystal.

Synthesis, characterization and in vivo evaluation of a magnetic cisplatin delivery nanosystem based on PMAA-graft-PEG copolymers (2016)
Journal Article
Voulgari, E., Bakandritsos, A., Galtsidis, S., Zoumpourlis, V., Burke, B. P., Clemente, G. S., …Avgoustakis, K. (2016). Synthesis, characterization and in vivo evaluation of a magnetic cisplatin delivery nanosystem based on PMAA-graft-PEG copolymers. Journal of controlled release : official journal of the Controlled Release Society, 243, 342-356. https://doi.org/10.1016/j.jconrel.2016.10.021

© 2016 Elsevier B.V. The development of anticancer drug delivery systems which retain or enhance the cytotoxic properties of the drug to tumorous tissues, while reducing toxicity to other organs is of key importance. We investigated different poly(me... Read More about Synthesis, characterization and in vivo evaluation of a magnetic cisplatin delivery nanosystem based on PMAA-graft-PEG copolymers.

How the sun protection factor (SPF) of sunscreen films change during solar irradiation (2016)
Journal Article
Binks, B. P., Fletcher, P. D., Johnson, A. J., Marinopoulos, I., Crowther, J., & Thompson, M. A. (2017). How the sun protection factor (SPF) of sunscreen films change during solar irradiation. Journal of Photochemistry and Photobiology A: Chemistry, 333, 186-199. https://doi.org/10.1016/j.jphotochem.2016.10.027

We have investigated how the sun protection factor (SPF) of different types of sunscreen film varies with “standard” solar irradiation due to photochemical processes. We have used a combination of chemical actinometry, measurement and modelling to es... Read More about How the sun protection factor (SPF) of sunscreen films change during solar irradiation.