Chong Wu
A pyrene-functionalized triazole-linked hexahomotrioxacalix[3]arene as a fluorescent chemosensor for Zn²⁺ ions
Wu, Chong; Ikejiri, Yusuke; Zhao, Jiang-Lin; Jiang, Xue-Kai; Ni, Xin-Long; Zeng, Xi; Redshaw, Carl; Yamato, Takehiko
Authors
Yusuke Ikejiri
Jiang-Lin Zhao
Xue-Kai Jiang
Xin-Long Ni
Xi Zeng
Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry
Takehiko Yamato
Abstract
A new pyrenyl appended hexahomotrioxacalix[3]arene L featuring 1,2,3-triazole linkers was synthesized as a fluorescent chemosensor for Zn²⁺ in mixed aqueous media. It exhibited high affinity toward Zn²⁺, and the monomer and excimer emission of the pyrene moieties could be adjusted. The binding stoichiometry of the L·Zn²⁺ complex was determined to be 1:1, and the association constant (Ka) was found to be 7.05 × 10⁴ M⁻¹. The binding behavior with Zn²⁺ has been confirmed by ¹H NMR spectroscopic analysis.
Citation
Wu, C., Ikejiri, Y., Zhao, J.-L., Jiang, X.-K., Ni, X.-L., Zeng, X., Redshaw, C., & Yamato, T. (2016). A pyrene-functionalized triazole-linked hexahomotrioxacalix[3]arene as a fluorescent chemosensor for Zn²⁺ ions. Sensors and actuators. B, Chemical, 228(2 June), 480-485. https://doi.org/10.1016/j.snb.2016.01.051
Journal Article Type | Article |
---|---|
Acceptance Date | Jan 13, 2016 |
Online Publication Date | Jan 19, 2016 |
Publication Date | Jun 2, 2016 |
Deposit Date | Jun 22, 2016 |
Publicly Available Date | Jun 22, 2016 |
Journal | Sensors and actuators B : chemical |
Print ISSN | 0925-4005 |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 228 |
Issue | 2 June |
Pages | 480-485 |
DOI | https://doi.org/10.1016/j.snb.2016.01.051 |
Keywords | Hexahomotrioxacalix[3]arene, Fluorescent chemosensor, Pyrene, Zn²⁺ |
Public URL | https://hull-repository.worktribe.com/output/440061 |
Publisher URL | http://www.sciencedirect.com/science/article/pii/S0925400516300533 |
Additional Information | This article is maintained by: Elsevier; Article Title: A pyrene-functionalized triazole-linked hexahomotrioxacalix[3]arene as a fluorescent chemosensor for Zn2+ ions; Journal Title: Sensors and Actuators B: Chemical; CrossRef DOI link to publisher maintained version: http://dx.doi.org/10.1016/j.snb.2016.01.051; Content Type: article; Copyright: Copyright © 2016 Elsevier B.V. All rights reserved. |
Contract Date | Jun 22, 2016 |
Files
Article.pdf
(1.8 Mb)
PDF
Copyright Statement
©2017 University of Hull
You might also like
Detection of the pesticide dodine using a cucurbit[10]uril-based fluorescent probe
(2021)
Journal Article
Downloadable Citations
About Repository@Hull
Administrator e-mail: repository@hull.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2024
Advanced Search