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Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate (2018)
Journal Article
Hobson, A. J., Stewart, D. I., Bray, A. W., Mortimer, R. J., Mayes, W. M., Riley, A. L., …Burke, I. T. (2018). Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate. The Science of the total environment, 643, 1191-1199. https://doi.org/10.1016/j.scitotenv.2018.06.272

© 2018 Vanadium is a toxic metal present in alkaline leachates produced during the weathering of steel slags. Slag leaching can therefore have deleterious effects on local watercourses due to metal toxicity, the effects of the high pH (9–12.5) and ra... Read More about Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate.

Atmospheric CO2 sequestration in iron and steel slag: Consett, Co. Durham, UK (2018)
Journal Article
Mayes, W. M., Riley, A. L., Gomes, H., Brabham, P., Hamlyn, J., Pullin, H., & Renforth, P. (2018). Atmospheric CO2 sequestration in iron and steel slag: Consett, Co. Durham, UK. Environmental Science and Technology, 52(14), 7892-7900. https://doi.org/10.1021/acs.est.8b01883

Carbonate formation in waste from the steel industry could constitute a non-trivial proportion of global requirements to remove carbon dioxide from the atmosphere at potentially low cost. To constrain this potential, we examined atmospheric carbon di... Read More about Atmospheric CO2 sequestration in iron and steel slag: Consett, Co. Durham, UK.

Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments (2018)
Journal Article
Gomes, H. I., Funari, V., Mayes, W. M., Rogerson, M., & Prior, T. J. (2018). Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments. Journal of environmental management, 222, 30-36. https://doi.org/10.1016/j.jenvman.2018.05.056

Steel slag is a major by-product of the steel industry and a potential resource of technology critical elements. For this study, a basic oxygen furnace (BOF) steel slag was tested for bacterial leaching and recovery of aluminium (Al), chromium (Cr),... Read More about Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments.

Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag (2018)
Journal Article
Stewart, D. I., Bray, A. W., Udoma, G., Hobson, A. J., Mayes, W. M., Rogerson, M., & Burke, I. T. (2018). Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag. Environmental science and pollution research, 25(10), 9861-9872. https://doi.org/10.1007/s11356-018-1260-7

© 2018 The Author(s) Alkalinity generation and toxic trace metal (such as vanadium) leaching from basic oxygen furnace (BOF) steel slag particles must be properly understood and managed by pre-conditioning if beneficial reuse of slag is to be maximis... Read More about Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag.

Hydraulic and biotic impacts on neutralisation of high-pH waters (2017)
Journal Article
Gomes, H. I., Mayes, W. M., Rogerson, M., Burke, I. T., & Stewart, D. I. (2017). Hydraulic and biotic impacts on neutralisation of high-pH waters. The Science of the total environment, 601-602, 1271-1279. https://doi.org/10.1016/j.scitotenv.2017.05.248

The management of alkaline (pH 11–12.5) leachate is an important issue associated with the conditioning, afteruse or disposal of steel slags. Passive in-gassing of atmospheric CO2 is a low cost option for reducing Ca(OH)2 alkalinity, as Ca(OH)2 is ne... Read More about Hydraulic and biotic impacts on neutralisation of high-pH waters.

Sustained bauxite residue rehabilitation with gypsum and organic matter 16 years after initial treatment (2017)
Journal Article
Bray, A. W., Stewart, D. I., Courtney, R., Rout, S. P., Humphreys, P. N., Mayes, W. M., & Burke, I. T. (2018). Sustained bauxite residue rehabilitation with gypsum and organic matter 16 years after initial treatment. Environmental Science and Technology, 52(1), 152-161. https://doi.org/10.1021/acs.est.7b03568

Bauxite residue is a high volume by-product of alumina manufacture which is commonly disposed of in purpose-built bauxite residue disposal areas (BRDAs). Natural waters interacting with bauxite residue are characteristically highly alkaline, and have... Read More about Sustained bauxite residue rehabilitation with gypsum and organic matter 16 years after initial treatment.

Mechanism of Vanadium Leaching during Surface Weathering of Basic Oxygen Furnace Steel Slag Blocks: A Microfocus X-ray Absorption Spectroscopy and Electron Microscopy Study (2017)
Journal Article
Hobson, A. J., Stewart, D. I., Bray, A. W., Mortimer, R. J. G., Mayes, W. M., Rogerson, M., & Burke, I. T. (2017). Mechanism of Vanadium Leaching during Surface Weathering of Basic Oxygen Furnace Steel Slag Blocks: A Microfocus X-ray Absorption Spectroscopy and Electron Microscopy Study. Environmental Science and Technology, 51(14), 7823-7830. https://doi.org/10.1021/acs.est.7b00874

© 2017 American Chemical Society. Basic oxygen furnace (BOF) steelmaking slag is enriched in potentially toxic V which may become mobilized in high pH leachate during weathering. BOF slag was weathered under aerated and air-excluded conditions for 6... Read More about Mechanism of Vanadium Leaching during Surface Weathering of Basic Oxygen Furnace Steel Slag Blocks: A Microfocus X-ray Absorption Spectroscopy and Electron Microscopy Study.

Can aggregate quarry silt lagoons provide resources for wading birds? (2017)
Journal Article
Day, G., Mayes, W. M., Wheeler, P. M., & Hull, S. L. (2017). Can aggregate quarry silt lagoons provide resources for wading birds?. Ecological engineering, 105, 189-197. https://doi.org/10.1016/j.ecoleng.2017.04.055

Wading birds have declined across Europe as the intensification of lowland agriculture has resulted in the loss and degradation of wetland areas. Lowland aggregate extraction sites that incorporate areas of fine, waste sediments deposited in silt lag... Read More about Can aggregate quarry silt lagoons provide resources for wading birds?.

Resource recovery and remediation of highly alkaline residues : a political-industrial ecology approach to building a circular economy (2017)
Journal Article
Deutz, P., Baxter, H., Gibbs, D., Mayes, W. M., & Gomes, H. I. (2017). Resource recovery and remediation of highly alkaline residues : a political-industrial ecology approach to building a circular economy. Geoforum, 85, 336-344. https://doi.org/10.1016/j.geoforum.2017.03.021

Highly alkaline industrial residues (e.g., steel slag, bauxite processing residue (red mud) and ash from coal combustion) have been identified as stocks of potentially valuable metals. Technological change has created demand for metals, such as vanad... Read More about Resource recovery and remediation of highly alkaline residues : a political-industrial ecology approach to building a circular economy.

Identifying pathways of exposure to highway pollutants in great crested newt (Triturus cristatus) road mitigation tunnels: Exposure pathways of highway pollutants to Triturus cristatus (2017)
Journal Article
White, K. J., Mayes, W. M., & Petrovan, S. O. (2017). Identifying pathways of exposure to highway pollutants in great crested newt (Triturus cristatus) road mitigation tunnels: Exposure pathways of highway pollutants to Triturus cristatus. Water and environment journal : the journal / the Chartered Institution of Water and Environmental Management, 31(3), 310-316. https://doi.org/10.1111/wej.12244

Road mitigation tunnels are increasingly deployed for amphibians but very little is known about chemical pollution in such schemes. We assessed pollution pressures associated with road runoff at a major great crested newt mitigation scheme in England... Read More about Identifying pathways of exposure to highway pollutants in great crested newt (Triturus cristatus) road mitigation tunnels: Exposure pathways of highway pollutants to Triturus cristatus.

Removal and recovery of vanadium from alkaline steel slag leachates with anion exchange resins (2016)
Journal Article
Gomes, H. I., Jones, A., Rogerson, M., Greenway, G. M., Lisbona, D. F., Burke, I. T., & Mayes, W. M. (2017). Removal and recovery of vanadium from alkaline steel slag leachates with anion exchange resins. Journal of environmental management, 187, 384-392. https://doi.org/10.1016/j.jenvman.2016.10.063

© 2016 The Author(s) Leachable vanadium (V) from steel production residues poses a potential environmental hazard due to its mobility and toxicity under the highly alkaline pH conditions that characterise these leachates. This work aims to test the e... Read More about Removal and recovery of vanadium from alkaline steel slag leachates with anion exchange resins.

Vanadium removal and recovery from bauxite residue leachates by ion exchange (2016)
Journal Article
Gomes, H. I., Jones, A., Rogerson, M., Burke, I. T., & Mayes, W. M. (2016). Vanadium removal and recovery from bauxite residue leachates by ion exchange. Environmental science and pollution research, 23(22), 23034-23042. https://doi.org/10.1007/s11356-016-7514-3

Bauxite residue is an important by-product of the alumina industry, and current management practices do not allow their full valorisation, especially with regard to the recovery of critical metals. This work aims to test the efficiency of ion exchang... Read More about Vanadium removal and recovery from bauxite residue leachates by ion exchange.

Advances in understanding enviromental risks of red mud after the Ajka Spill, Hungary (2016)
Journal Article
Mayes, W. M., Burke, I. T., Gomes, H. I., Anton, Á. D., Molnár, M., Feigl, V., & Ujaczki, É. (2016). Advances in understanding enviromental risks of red mud after the Ajka Spill, Hungary. Journal of Sustainable Metallurgy, 2(4), 332-343. https://doi.org/10.1007/s40831-016-0050-z

In the 5 years since the 2010 Ajka red mud spill (Hungary), there have been 46 scientific studies assessing the key risks and impacts associated with the largest single release of bauxite-processing residue (red mud) to the environment. These studies... Read More about Advances in understanding enviromental risks of red mud after the Ajka Spill, Hungary.

Alkaline residues and the environment: a review of impacts, management practices and opportunities (2015)
Journal Article
Gomes, H. I., Mayes, W. M., Rogerson, M., Stewart, D. I., & Burke, I. T. (2016). Alkaline residues and the environment: a review of impacts, management practices and opportunities. Journal of cleaner production, 112(4), 3571-3582. https://doi.org/10.1016/j.jclepro.2015.09.111

Around two billion tonnes of alkaline residues are produced globally each year by industries such as steel production, alumina refining and coal-fired power generation, with a total production estimate of 90 billion tonnes since industrialisation. Th... Read More about Alkaline residues and the environment: a review of impacts, management practices and opportunities.

Long-term evolution of highly alkaline steel slag drainage waters (2015)
Journal Article
Riley, A. L., & Mayes, W. M. (2015). Long-term evolution of highly alkaline steel slag drainage waters. Environmental monitoring and assessment, 187(7), Article ARTN 463. https://doi.org/10.1007/s10661-015-4693-1

© 2015, Springer International Publishing Switzerland. The disposal of slag generated by the steel industry can have negative consequences upon the surrounding aquatic environment by the generation of high pH waters, leaching of potentially problemat... Read More about Long-term evolution of highly alkaline steel slag drainage waters.

Leaching of copper and nickel in soil-water systems contaminated by bauxite residue (red mud) from Ajka, Hungary: the importance of soil organic matter (2015)
Journal Article
Lockwood, C. L., Stewart, D. I., Mortimer, R. J. G., Mayes, W., Jarvis, A. P., Gruiz, K., & Burke, I. T. (2015). Leaching of copper and nickel in soil-water systems contaminated by bauxite residue (red mud) from Ajka, Hungary: the importance of soil organic matter. Environmental science and pollution research, 22(14), 10800-10810. https://doi.org/10.1007/s11356-015-4282-4

Red mud is a highly alkaline (pH >12) waste product from bauxite ore processing. The red mud spill at Ajka, Hungary, in 2010 released 1 million m3 of caustic red mud into the surrounding area with devastating results. Aerobic and anaerobic batch expe... Read More about Leaching of copper and nickel in soil-water systems contaminated by bauxite residue (red mud) from Ajka, Hungary: the importance of soil organic matter.

Zinc Uptake from Circumneutral Mine Drainage in Freshwater Biofilms: New Insights from In Vitro Experiments (2015)
Journal Article
Jones, A., Rogerson, M., Greenway, G., & Mayes, W. M. (2015). Zinc Uptake from Circumneutral Mine Drainage in Freshwater Biofilms: New Insights from In Vitro Experiments. Mine Water and the Environment, 34(3), 295-307. https://doi.org/10.1007/s10230-015-0325-9

© 2015, Springer-Verlag Berlin Heidelberg. We present results from in vitro flask and flume experiments using freshwater biofilms sourced and cultivated from a mine-impacted stream in North Yorkshire, UK. Flask experiments showed rapid uptake of Zn f... Read More about Zinc Uptake from Circumneutral Mine Drainage in Freshwater Biofilms: New Insights from In Vitro Experiments.

Mobilisation of arsenic from bauxite residue (red mud) affected soils : effect of pH and redox conditions (2014)
Journal Article
Lockwood, C. L., Mortimer, R. J., Stewart, D. I., Mayes, W. M., Peacock, C. L., Polya, D. A., …Burke, I. T. (2014). Mobilisation of arsenic from bauxite residue (red mud) affected soils : effect of pH and redox conditions. Applied geochemistry : journal of the International Association of Geochemistry and Cosmochemistry, 51(December), 268-277. https://doi.org/10.1016/j.apgeochem.2014.10.009

The tailings dam breach at the Ajka alumina plant, western Hungary in 2010 introduced ∼1 million m³ of red mud suspension into the surrounding area. Red mud (fine fraction bauxite residue) has a characteristically alkaline pH and contains several pot... Read More about Mobilisation of arsenic from bauxite residue (red mud) affected soils : effect of pH and redox conditions.

Geochemical recovery of the Torna-Marcal river system after the Ajka red mud spill, Hungary (2014)
Journal Article
Anton, Á. D., Klebercz, O., Magyar, Á., Burke, I. T., Jarvis, A. P., Gruiz, K., & Mayes, W. M. (2014). Geochemical recovery of the Torna-Marcal river system after the Ajka red mud spill, Hungary. Environmental science--processes & impacts, 16(12), 2677-2685. https://doi.org/10.1039/c4em00452c

The failure of the Ajka red mud depository in October 2010 led to the largest single release of red mud into the surface water environment. This study provides a comparative assessment of stream sediment quality in the Torna–Marcal–Rába catchment bet... Read More about Geochemical recovery of the Torna-Marcal river system after the Ajka red mud spill, Hungary.

The potential use of exhausted open pit mine voids as sinks for atmospheric CO2: Insights from natural reedbeds and mine water treatment wetlands (2014)
Journal Article
Younger, P. L., & Mayes, W. M. (2015). The potential use of exhausted open pit mine voids as sinks for atmospheric CO2: Insights from natural reedbeds and mine water treatment wetlands. Mine Water and the Environment, 34(1), 112-120. https://doi.org/10.1007/s10230-014-0293-5

Abandoned surface mine voids are often left to flood, forming pit lakes. Drawing simple but important lessons from experiences with compost-based passive remediation systems for acidic mine waters, an alternative end-use for open pit mine voids is pr... Read More about The potential use of exhausted open pit mine voids as sinks for atmospheric CO2: Insights from natural reedbeds and mine water treatment wetlands.