Through-plane gas permeability of gas diffusion layers and microporous layer: Effects of carbon loading and sintering

Orogbemi, O. M.; Ingham, D. B.; Ismail, M. S.; Hughes, K. J.; Ma, L.; Pourkashanian, M.

doi:10.1016/j.joei.2016.11.008

Wheat straw bio-refining. Part II: Optimization of the microwave radiation with sulphuric acid pre-treatment and its enzymatic hydrolysis for fermentable sugars (2017)
Journal Article
Festus, O., Skoulou, V. K., & Zein, S. H. (2017). Wheat straw bio-refining. Part II: Optimization of the microwave radiation with sulphuric acid pre-treatment and its enzymatic hydrolysis for fermentable sugars. Current Microwave Chemistry, 4(4), 306-316. https://doi.org/10.2174/2213335604666171103123459

Background: The potential of microwave-assisted heating for enhancing the alkaline pretreatment of lignocellulosic waste is highlighted in this work. Objective: To maximize separation of fermentable sugars from wheat straw. Methods: Wheat straw... Read More about Wheat straw bio-refining. Part II: Optimization of the microwave radiation with sulphuric acid pre-treatment and its enzymatic hydrolysis for fermentable sugars.

Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions (2017)
Journal Article
Yentekakis, I., Goula, G., Kampouri, S., Betsi-argyropoulou, I., Panagiotopoulou, P., Taylor, M., …Lambert, R. (2018). Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions. Catalysis Letters, 148(1), 341-347. https://doi.org/10.1007/s10562-017-2233-z

The effect of the morphology of Ir particles supported on γ-Al2O3, 8 mol%Y2O3-stabilized ZrO2 (YSZ), 10 mol%Gd2O3-doped CeO2 (GDC) and 80 wt%Al2O3–10 wt%CeO2–10 wt%ZrO2 (ACZ) on their stability on oxidative conditions, the associated metal–support in... Read More about Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions.

Behavior and pressure drop of an upwardly two-phase flow through multi-hole orifices (2017)
Journal Article
Zeghloul, A., Azzi, A., Hasan, A., & Azzopardi, B. J. (2018). Behavior and pressure drop of an upwardly two-phase flow through multi-hole orifices. Proceedings of the Institution of Mechanical Engineers. Part C, Mechanical engineering science, 232(18), 3281-3299. https://doi.org/10.1177/0954406217736081

Experimental results on hydrodynamic behavior and pressure drop of two-phase mixture flowing upwardly in a pipe containing single- and/or multi-hole orifice plate are presented. It was found from the measurement of the void fraction upstream and down... Read More about Behavior and pressure drop of an upwardly two-phase flow through multi-hole orifices.

On the gas permeability of the microporous layer used in polymer electrolyte fuel cells (2017)
Journal Article
Orogbemi, O. M., Ingham, D. B., Ismail, M. S., Hughes, K. J., Ma, L., & Pourkashanian, M. (2018). On the gas permeability of the microporous layer used in polymer electrolyte fuel cells. Journal of the Energy Institute, 91(6), 894-901. https://doi.org/10.1016/j.joei.2017.09.006

In an attempt to obtain accurate values of the gas permeability of the microporous layer (MPL), substrates with negligible MPL penetration and of known gas permeability, i.e. membrane filters, have been employed. The values of the MPL permeability ob... Read More about On the gas permeability of the microporous layer used in polymer electrolyte fuel cells.

Dependency of the combustion behavior of energy grass and three other types of biomass upon lignocellulosic composition (2017)
Journal Article
Ma, Y., Guan, Y., Zhang, K., Xu, G., Yang, Y., & Stevenson, P. (2018). Dependency of the combustion behavior of energy grass and three other types of biomass upon lignocellulosic composition. Environmental Progress and Sustainable Energy, 37(2), 815-823. https://doi.org/10.1002/ep.12705

The combustion characteristics of four kinds of biomass fuels (energy grass, sawdust, corn cob, and walnut shell) are investigated in this article. All the samples are heated from room temperature to 800°C at multiple heating rates of 10, 20, and 30°... Read More about Dependency of the combustion behavior of energy grass and three other types of biomass upon lignocellulosic composition.

One-step reforming of CO₂ and CH₄ to high-value liquid chemicals and fuels at room temperature via plasma-driven catalysis (2017)
Journal Article
Wang, L., Yi, Y., Wu, C., Guo, H., & Tu, X. (2017). One-step reforming of CO₂ and CH₄ to high-value liquid chemicals and fuels at room temperature via plasma-driven catalysis. Angewandte Chemie, 129(44), 13867-13871. https://doi.org/10.1002/ange.201707131

Conversion of CO₂ with CH₄ into liquid fuels and chemicals in a single-step catalytic process bypassing the production of syngas remains a challenge. In this study, one-step synthesis of liquid fuels and chemicals (e.g. acetic acid, methanol, ethanol... Read More about One-step reforming of CO₂ and CH₄ to high-value liquid chemicals and fuels at room temperature via plasma-driven catalysis.

Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment (2017)
Journal Article
Demirhan, H., Fauzi, A., Skoulou, V. . K., Haywood, S. . . H., & Zein, S. . . H. (2017). Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment. Current Microwave Chemistry, 4(3), https://doi.org/10.2174/2213335604666170719113659

Background: This study investigates the microwave-assisted acid extraction of lignin from wheat straw. Methods: Two experimental design methods, the Central Composite Design (CCD) and the Response Surface Method (RSM) methods were used to select c... Read More about Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment.

Nanoparticulate Pd-Sn Compounds Supported on Metal Oxides: Synthesis, Material and Catalytic Properties (2017)
Journal Article
Ibhadon, A. O., Francesconi, M. G., & Johnston, S. K. (2017). Nanoparticulate Pd-Sn Compounds Supported on Metal Oxides: Synthesis, Material and Catalytic Properties. Chemical Engineering & Process Techniques, 3(3), Article 1044

The manufacture of chemicals requires innovation at the catalyst frontier so that processes can be developed with higher energy efficiency and increased facility of separation and recovery of products. Catalysts with high selectivity and activity con... Read More about Nanoparticulate Pd-Sn Compounds Supported on Metal Oxides: Synthesis, Material and Catalytic Properties.

Simultaneous direct visualisation of liquid water in the cathode and anode serpentine flow channels of proton exchange membrane (PEM) fuel cells (2017)
Journal Article
Aslam, R. M., Ingham, D. B., Ismail, M. S., Hughes, K. J., Ma, L., & Pourkashanian, M. (2018). Simultaneous direct visualisation of liquid water in the cathode and anode serpentine flow channels of proton exchange membrane (PEM) fuel cells. Journal of the Energy Institute, 91(6), 1057-1070. https://doi.org/10.1016/j.joei.2017.07.003

Water flooding is detrimental to the performance of the proton exchange membrane fuel cell (PEMFC) and therefore it has to be addressed. To better understand how liquid water affects the fuel cell performance, direct visualisation of liquid water in... Read More about Simultaneous direct visualisation of liquid water in the cathode and anode serpentine flow channels of proton exchange membrane (PEM) fuel cells.

Application of a porous media model for the acoustic damping of perforated plate absorbers (2017)
Journal Article
Wang, J., Rubini, P., & Qin, Q. (2017). Application of a porous media model for the acoustic damping of perforated plate absorbers. Applied acoustics. Acoustique appliqué. Angewandte Akustik, 127, 324-335. https://doi.org/10.1016/j.apacoust.2017.07.003

Perforated panel, or plate, absorbers are commonly employed to reduce sound pressure levels across a broad range of applications including the built environment, industrial installations and propulsion devices. The acoustic performance of a perforate... Read More about Application of a porous media model for the acoustic damping of perforated plate absorbers.

Pd₃Sn nanoparticles on TiO₂ and ZnO supports as catalysts for semi-hydrogenation : synthesis and catalytic performance (2017)
Journal Article
Johnston, S. K., Cherkasov, N., Perez-Barrado, E., Aho, A., Murzin, D. Y., Ibhadon, A. O., & Francesconi, M. G. (2017). Pd₃Sn nanoparticles on TiO₂ and ZnO supports as catalysts for semi-hydrogenation : synthesis and catalytic performance. Applied catalysis. A, General, 544, 40-45. https://doi.org/10.1016/j.apcata.2017.07.005

The two catalysts Pd₃Sn/TiO₂and Pd3Sn/ZnO were prepared via a one-pot procedure based on the “polyol method” with the addition of a capping agent (polyvinylpyrrolidone) to control the particle size distribution. The same procedure was used to prepare... Read More about Pd₃Sn nanoparticles on TiO₂ and ZnO supports as catalysts for semi-hydrogenation : synthesis and catalytic performance.

Controllable synthesis of zeolitic imidazolate frameworks with rod-like or delta-shaped morphologies at oil-water interface (2017)
Journal Article
Zhang, Y., Zhao, Y., Ke, X., & Zhang, L. (2017). Controllable synthesis of zeolitic imidazolate frameworks with rod-like or delta-shaped morphologies at oil-water interface. Materials letters, 206, 233-236. https://doi.org/10.1016/j.matlet.2017.07.002

Zeolitic imidazolate framework (ZIF-8) has attracted extensive application in gas adsorption, membrane separation and catalysis. It has been demonstrated that the morphology is crucial for the physical and chemical properties. In this work, ZIF-8 cry... Read More about Controllable synthesis of zeolitic imidazolate frameworks with rod-like or delta-shaped morphologies at oil-water interface.

Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment (2017)
Journal Article
Demirhan, H., Fauzi, A., Skoulou, V., Haywood, S., & Zein, S. H. (2017). Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment. Current Microwave Chemistry, 4(3), 205-218. https://doi.org/10.2174/2213335604666170719113659

Background: This study investigates the microwave-assisted acid extraction of lignin from wheat straw. Methods: Two experimental design methods, the Central Composite Design (CCD) and the Response Surface Method (RSM) methods were used to select c... Read More about Wheat Straw Bio-refining. Part I: Optimization of the Microwave Radiation Process with Sulphuric Acid Pre-treatment.

Characterization of rice husk-based catalyst prepared via conventional and microwave carbonisation (2017)
Journal Article
Touhami, D., Zhu, Z., Balan, W. S., Janaun, J., Haywood, S., & Zein, S. (2017). Characterization of rice husk-based catalyst prepared via conventional and microwave carbonisation. Journal of Environmental Chemical Engineering, 5(3), 2388-2394. https://doi.org/10.1016/j.jece.2017.04.020

© 2017 Elsevier Ltd. Carbon-based sulphonated catalysts (CBSCs) were made from rice husk for biodiesel production. The CBSCs were prepared by microwave (MW) and conventional heating processes from the same feedstock. In both heating systems, the prep... Read More about Characterization of rice husk-based catalyst prepared via conventional and microwave carbonisation.

Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites (2017)
Journal Article
Kelly, S., Kornherr, A., Alahmadi, N. S., Betts, J. W., Francesconi, M. G., Prior, T. J., …Kornherr, A. (2017). Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites. RSC advances, 7(32), 20020-20026. https://doi.org/10.1039/c7ra00920h

© The Royal Society of Chemistry. Green synthesis is employed to prepare cobalt/cellulose nanocomposites with cubic (α-cobalt) cobalt as a main component with antibacterial and magnetic properties. An in situ reduction of aqueous solutions of cobalt... Read More about Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites.

Critical role of oxygen in silver-catalyzed Glaser-Hay coupling on Ag(100) under vacuum and in solution on Ag particles (2017)
Journal Article
Orozco, N., Kyriakou, G., Beaumont, S. K., Fernandez Sanz, J., Holgado, J. P., Taylor, M. J., …Lambert, R. M. (2017). Critical role of oxygen in silver-catalyzed Glaser-Hay coupling on Ag(100) under vacuum and in solution on Ag particles. ACS Catalysis, 7(5), 3113-3120. https://doi.org/10.1021/acscatal.7b00431

The essential role of oxygen in enabling heterogeneously catalyzed Glaser-Hay coupling of phenylacetylene on Ag(100) was elucidated by STM, laboratory and synchrotron photoemission, and DFT calculations. In the absence of coadsorbed oxygen, phenylace... Read More about Critical role of oxygen in silver-catalyzed Glaser-Hay coupling on Ag(100) under vacuum and in solution on Ag particles.

Catalytic hydrogenation and hydrodeoxygenation of Furfural over Pt(111): A model system for the rational design and operation of practical biomass conversion catalysts (2017)
Journal Article
Taylor, M. J., Jiang, L., Reichert, J., Papageorgiou, A. C., Beaumont, S. K., Wilson, K., …Kyriakou, G. (2017). Catalytic hydrogenation and hydrodeoxygenation of Furfural over Pt(111): A model system for the rational design and operation of practical biomass conversion catalysts. Journal of physical chemistry. C, 121(15), 8490-8497. https://doi.org/10.1021/acs.jpcc.7b01744

Furfural is a key bioderived platform chemical whose reactivity under hydrogen atmospheres affords diverse chemical intermediates. Here, temperature-programmed reaction spectrometry and complementary scanning tunneling microscopy (STM) are employed t... Read More about Catalytic hydrogenation and hydrodeoxygenation of Furfural over Pt(111): A model system for the rational design and operation of practical biomass conversion catalysts.

Maintenance of head and neck tumor on-chip: gateway to personalized treatment? (2017)
Journal Article
Bower, R., Green, V. L., Kuvshinova, E., Kuvshinov, D., Karsai, L., Crank, S. T., …Greenman, J. (2017). Maintenance of head and neck tumor on-chip: gateway to personalized treatment?. Future Science OA, 3(2), FSO174. https://doi.org/10.4155/fsoa-2016-0089

Aim: Head and neck squamous cell carcinomas (HNSCC) are solid tumors with low overall survival (40–60%). In a move toward personalized medicine, maintenance of tumor biopsies in microfluidic tissue culture devices is being developed. Methodology/ res... Read More about Maintenance of head and neck tumor on-chip: gateway to personalized treatment?.

Continuous fabrication of calcium sulfate whiskers with adjustable aspect ratio in microdroplets (2017)
Journal Article
Qi, Y., Zeng, C., Wang, C., Ke, X., & Zhang, L. (2017). Continuous fabrication of calcium sulfate whiskers with adjustable aspect ratio in microdroplets. Materials letters, 194, 231-233. https://doi.org/10.1016/j.matlet.2017.02.066

Hemi-hydrate and anhydrous CaSO₄ whiskers with adjustable aspect ratio were continuously synthesized by the reactive crystallization of CaCl₂ to K₂ S₂ O₈ in microdroplets. The effects of solvent and reactive temperature were examined, with SEM and XR... Read More about Continuous fabrication of calcium sulfate whiskers with adjustable aspect ratio in microdroplets.

Through-plane gas permeability of gas diffusion layers and microporous layer: Effects of carbon loading and sintering (2017)
Journal Article
Orogbemi, O. M., Ingham, D. B., Ismail, M. S., Hughes, K. J., Ma, L., & Pourkashanian, M. (2018). Through-plane gas permeability of gas diffusion layers and microporous layer: Effects of carbon loading and sintering. Journal of the Energy Institute, 91(2), 270-278. https://doi.org/10.1016/j.joei.2016.11.008

Knowledge of the absolute permeability for the various porous layers is necessary to obtain accurate profiles for water saturation within the membrane electrode assembly (MEA) in a two-phase model of a polymer electrolyte membrane fuel cell (PEMFC).... Read More about Through-plane gas permeability of gas diffusion layers and microporous layer: Effects of carbon loading and sintering.

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