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Crossover between liquid-like and gas-like behaviour in CH₄ at 400 K (2017)
Journal Article
Smith, D., Hakeem, M. A., Parisiades, P., Maynard-Casely, H. E., Foster, D., Eden, D., …Proctor, J. E. (2017). Crossover between liquid-like and gas-like behaviour in CH₄ at 400 K. Physical Review E, 96(5), https://doi.org/10.1103/PhysRevE.96.052113

We report experimental evidence for a crossover between a liquid-like state and a gas-like state in fluid methane (CH₄). This crossover is observed in all of our experiments, up to 397 K temperature; 2.1 times the critical temperature of methane. The... Read More

Determining molecular orientation via single molecule SERS in a plasmonic nano-gap (2017)
Journal Article
Marshall, A. R. L., Stokes, J., Viscomi, F. N., Proctor, J. E., Gierschner, J., Bouillard, J. G., & Adawi, A. M. (2017). Determining molecular orientation via single molecule SERS in a plasmonic nano-gap. Nanoscale, 9(44), 17415-17421. https://doi.org/10.1039/C7NR05107G

In this work, plasmonic nano-gaps consisting of a silver nanoparticle coupled to an extended silver film have been fully optimized for single molecule Surface-Enhanced Raman Scattering (SERS) spectroscopy. The SERS signal was found to be strongly dep... Read More

Magnetic control of MOF crystal orientation and alignment (2017)
Journal Article
Cheng, F., Marshall, E. S., Young, A. J., Robinson, P. J., Bouillard, J. S. G., Adawi, A. M., …Chin, J. M. (2017). Magnetic control of MOF crystal orientation and alignment. Chemistry : a European journal, 23(62), 15578-15582. https://doi.org/10.1002/chem.201703812

Most metal-organic frameworks (MOFs) possess anisotropic properties, the full exploitation of which necessitates a general strategy for the controllable orientation of such MOF crystals. Current methods largely rely upon layer-by-layer MOF epitaxy or... Read More

Dual-modal SERS/fluorescence AuNP probe for mitochondrial imaging (2017)
Journal Article
Eling, C. J., Price, T. W., Marshall, A. R. L., Narda Viscomi, F., Robinson, P., Firth, G., …Stasiuk, G. J. (2017). Dual-modal SERS/fluorescence AuNP probe for mitochondrial imaging. ChemPlusChem, 82(5), 674-680. https://doi.org/10.1002/cplu.201600593

A novel SERS/fluorescent multimodal imaging probe for mitochondria has been synthesised using 12 nm diameter gold nanoparticles (AuNP) surface functionalised with a rhodamine thiol derivative ligand. The normal pH dependant acidic fluorescence of the... Read More