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Synthesis and structure of tetrakis(isopropylimino)bis-[tris(dimethylamino) silylamino]alane (2005)
Journal Article
Cheng, F., Clark, S., Archibald, S. J., Kelly, S. M., & Bradley, J. S. (2005). Synthesis and structure of tetrakis(isopropylimino)bis-[tris(dimethylamino) silylamino]alane. Journal of organometallic chemistry, 690(5), 1205-1208. https://doi.org/10.1016/j.jorganchem.2004.11.025

A novel cage-type compound tetrakis(isopropylimino)bis[tris(dimethylamino) silylamino]alane, H 6 Al 6 (N i Pr) 4 [NSi(NMe 2 ) 3 ] 2 , (1), was prepared by reaction of tris(dimethylamino)silylamine H 2 NSi(NMe 2 ) 3 with poly(isopropyliminoalane) (HAl... Read More about Synthesis and structure of tetrakis(isopropylimino)bis-[tris(dimethylamino) silylamino]alane.

Novel amide-based chain transfer agent for reversible addition fragmentation chain transfer polymerization (2005)
Journal Article
Takolpuckdee, P., Mars, C. A., Perrier, S., & Archibald, S. J. (2005). Novel amide-based chain transfer agent for reversible addition fragmentation chain transfer polymerization. Macromolecules, 38(4), 1057-1060. https://doi.org/10.1021/ma0487271

A novel chain transfer agent (CTA), S-diethylcarbamoylphenylmethyl dithiobenzoate (DCPDB), based on an amide functionality was analyzed, to mediate the polymerization of styrene and acrylamide derivatives. The reversible addition fragmentation chain... Read More about Novel amide-based chain transfer agent for reversible addition fragmentation chain transfer polymerization.

Toward the soil poultice and a new separations methodology: Rebinding of macrocyclic metal complexes to molecularly imprinted polymers specifically templated via noncovalent interactions (2005)
Journal Article
Zuo, X., Mosha, D., Archibald, S. J., Mccasland, A. K., Hassan, A. M., Givens, R. S., & Busch, D. H. (2005). Toward the soil poultice and a new separations methodology: Rebinding of macrocyclic metal complexes to molecularly imprinted polymers specifically templated via noncovalent interactions. Journal of coordination chemistry, 58(1), 21-39. https://doi.org/10.1080/00958970512331327357

The siderophore-based extraction of iron from the soil by bacteria is proposed as a model for a new separation methodology labeled the soil poultice, a molecular device that would selectively retrieve the complex of a targeted metal ion. In this firs... Read More about Toward the soil poultice and a new separations methodology: Rebinding of macrocyclic metal complexes to molecularly imprinted polymers specifically templated via noncovalent interactions.

Rigidity extremes in coordination chemistry: A fine energetic balance in the isolation of a trapped ligand inversion intermediate (2004)
Journal Article
May, C. M., Archibald, S. J., Bridgeman, A. J., Empson, C. J., & Hubin, T. J. (2004). Rigidity extremes in coordination chemistry: A fine energetic balance in the isolation of a trapped ligand inversion intermediate. Chemical communications : Chem comm / the Royal Society of Chemistry, 10(16), 1880-1881. https://doi.org/10.1039/b405358c

An unusual copper(II) complex of a highly rigid and bulky ligand (a macrocycle-glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.

Synthesis and characterization of the cobalt(III) complexes of two pendant-arm cross-bridged cyclams (2004)
Journal Article
Lichty, J., Allen, S. M., Grillo, A. I., Archibald, S. J., & Hubin, T. J. (2004). Synthesis and characterization of the cobalt(III) complexes of two pendant-arm cross-bridged cyclams. Inorganica Chimica Acta, 357(2), 615-618. https://doi.org/10.1016/j.ica.2003.08.014

The cobalt(III) complexes of 4,11-diacetato-1,4,8,11-tetraazabicyclo[6.6.2] hexadecane (1), [Co(1)] PF 6 , and 4,11-diacetamido-1,4,8,11- tetraazabicyclo[6.6.2]hexadecane (2), [Co(2)] [PF 6 ] 3 , have been synthesized and characterized. The crystal s... Read More about Synthesis and characterization of the cobalt(III) complexes of two pendant-arm cross-bridged cyclams.

Preparation of Mesoporous Silicon Boron Imide Gels from Single-Source Precursors via a Nonaqueous Sol-Gel Route (2003)
Journal Article
Cheng, F., Archibald, S. J., Clark, S., Toury, B., Kelly, S. M., Bradley, J. S., & Lefebvre, F. (2003). Preparation of Mesoporous Silicon Boron Imide Gels from Single-Source Precursors via a Nonaqueous Sol-Gel Route. Chemistry of materials : a publication of the American Chemical Society, 15(24), 4651-4657. https://doi.org/10.1021/cm034337m

The preparation and structure of the novel compound 2-(dimethylamino)-4,6-di[tris-(dimethylamino)silylamino]borazine, (Me 2 N)[(Me 2 N) 3 SiNH] 2 B 3 N 3 H 3 , 1a, is reported. Two translucent silicon boron imide gels, Si 2 B 3 (NH) x (NH 2 ) y (N... Read More about Preparation of Mesoporous Silicon Boron Imide Gels from Single-Source Precursors via a Nonaqueous Sol-Gel Route.

A silver-iodine chain complex: Catenapoly[anilinium [silver(I)-di-μ- iodo]], {[PhNH3][Agl2]}n (2003)
Journal Article
Alcock, N. W., Archibald, S. J., & Busch, D. H. (2003). A silver-iodine chain complex: Catenapoly[anilinium [silver(I)-di-μ- iodo]], {[PhNH3][Agl2]}n. Acta Crystallographica Section E: Crystallographic Communications, 59(12), https://doi.org/10.1107/S1600536803024966

The synthesis of the compound, {(C 6 H 8 N)[AgI 2 ]} n was discussed. The compound was prepared by the synthesis of a silver complex in the presence of N,N'-diphenyl-amidine contaminated with potassium iodide. The complex was prepared from aniliniu... Read More about A silver-iodine chain complex: Catenapoly[anilinium [silver(I)-di-μ- iodo]], {[PhNH3][Agl2]}n.

Replacement of [RuH2(PMe3)4] by [RuH 2(PEt3)4] switches reaction products: Synthesis of fluoride-bridged diruthenium complexes (2003)
Journal Article
Jasim, N. A., Perutz, R. N., & Archibald, S. J. (2003). Replacement of [RuH2(PMe3)4] by [RuH 2(PEt3)4] switches reaction products: Synthesis of fluoride-bridged diruthenium complexes. Dalton Transactions : an international journal of inorganic chemistry, 2184-2187. https://doi.org/10.1039/b301582c

The fluoride-bridged ruthenium dimers [Ru 2 (μ-F) 3 (PR 3 ) 6 ][F(HF) n ] (R = Et, Pr, Bu; n ≈ 3) were synthesised by the reactions of the cis-[RuH 2 (PR 3 ) 4 ] complexes with NEt 3 ·3HF in THF; the crystal structure of [Ru 2 (μ-F) 3 (PEt 3 ) 6 ]... Read More about Replacement of [RuH2(PMe3)4] by [RuH 2(PEt3)4] switches reaction products: Synthesis of fluoride-bridged diruthenium complexes.

Syntheses and structures of [(Me3N)3SiNHLi] 4, (C4H8O)Al[NHSi(NMe2) 3]3, ((Me2N)3SiNH)3Al and Li(THF)2+[((Me2N)3SiNH) 4Al]- (2003)
Journal Article
Bradley, J. S., Cheng, F., Archibald, S. J., Supplit, R., Rovai, R., Lehmann, C. W., Krüger, C., & Lefebvre, F. (2003). Syntheses and structures of [(Me3N)3SiNHLi] 4, (C4H8O)Al[NHSi(NMe2) 3]3, ((Me2N)3SiNH)3Al and Li(THF)2+[((Me2N)3SiNH) 4Al]-. Dalton Transactions : an international journal of inorganic chemistry, 1846-1851. https://doi.org/10.1039/b209605f

The preparation of lithium tris(dimethylamino)silylamide, [(Me 3 N) 3 SiNHLi] 4 , 2, and its reaction with aluminium trichloride to give tris(dimethylamino)silylamino)(tetrahydrofuran) alane, (C 4 H 8 O)Al[NHSi(NMe 2 ) 3 ] 3 , 3, and bis(tetrahydro... Read More about Syntheses and structures of [(Me3N)3SiNHLi] 4, (C4H8O)Al[NHSi(NMe2) 3]3, ((Me2N)3SiNH)3Al and Li(THF)2+[((Me2N)3SiNH) 4Al]-.

Synthesis and structure of 2,4,6-tris[tris(dimethylamino)silylamino]borazine: (2002)
Journal Article
Cheng, F., Toury, B., Archibald, S. J., & Bradley, J. S. (2002). Synthesis and structure of 2,4,6-tris[tris(dimethylamino)silylamino]borazine:. Journal of organometallic chemistry, 657(1-2), 71-74. https://doi.org/10.1016/S0022-328X%2802%2901566-8

A novel compound 2,4,6-tris[tris(dimethylamino)silylamino]borazine {[(CH 3 ) 2 N] 3 SiNH} 3 B 3 N 3 H 3 (1) was prepared by reaction between lithium tris(dimethylamino)silylamide [(CH 3 ) 2 N] 3 SiNHLi and 2,4,6-trichloroborazine Cl 3 B 3 N 3 H 3 . T... Read More about Synthesis and structure of 2,4,6-tris[tris(dimethylamino)silylamino]borazine:.

Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes (2001)
Journal Article
Lewis, E. A., Smith, J. R., Walton, P. H., Archibald, S. J., Foxon, S. P., & Giblin, G. M. (2001). Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes. Dalton Transactions : an international journal of inorganic chemistry, 1159-1161

A selection of 5-substituted salicylaldehydes have been reacted with cis,cis-triaminocyclohexane to prepare a series of tri-imine and tri-amine ligands; cyclic voltammetry has been used to show that the electronic effect of the substituent has a mark... Read More about Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes.

Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs (2000)
Journal Article
Archibald, S. J., Alcock, N. W., Busch, D. H., & Whitcomb, D. R. (2000). Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs. Journal of cluster science, 11(1), 261-283

N,N′-Diphenylamidines and the silver(I) complexes of their deprotonated anions have been synthesized. Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition o... Read More about Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs.

Chemistry of nickel tetrafluoropyridyl derivatives: Their versatile behaviour with Brønsted acids and the Lewis acid BF3 (2000)
Journal Article
Archibald, S. J., Braun, T., Gaunt, J. A., Hobson, J. E., & Perutz, R. N. (2000). Chemistry of nickel tetrafluoropyridyl derivatives: Their versatile behaviour with Brønsted acids and the Lewis acid BF3. Dalton Transactions : an international journal of inorganic chemistry, 2013-2018. https://doi.org/10.1039/b002333g

Treatment of trans-[NiF(2-C 5 NF 4 )(PEt 3 ) 2 ] (C 5 NF 4 = tetrafluoropyridyl) (1) with HCl effects the formation of the air stable chloride complex trans-[NiCl(2-C 5 NF 4 )(PEt 3 ) 2 ] (2). The reaction of 2 with excess HCl slowly yields 2,3,4,5-... Read More about Chemistry of nickel tetrafluoropyridyl derivatives: Their versatile behaviour with Brønsted acids and the Lewis acid BF3.

Hydrogen bonding interactions in amorphous salicyl salicylate (2000)
Journal Article
Greener, B., Archibald, S. J., & Hodkinson, M. (2000). Hydrogen bonding interactions in amorphous salicyl salicylate. Angewandte Chemie, 39(20), 3601-3604. https://doi.org/10.1002/1521-3773%2820001016%2939%3A20%3C3601%3A%3AAID-ANIE3601%3E3.0.CO%3B2-R

Rapid intermolecular acid-alcohol hydrogen-bonded proton exchange and geometrical disorder, well below the melting temperature, form the basis of the observed amorphous behavior of salicyl salicylate 1. Compound 1 was observed in a stable, undercoole... Read More about Hydrogen bonding interactions in amorphous salicyl salicylate.

A Novel Route to Preussomerins via 2-Arylacetal Anions (2000)
Journal Article
Ragot, J. P., Prime, M. E., Archibald, S. J., & Taylor, R. J. (2000). A Novel Route to Preussomerins via 2-Arylacetal Anions. Organic Letters, 2(11), 1613-1616. https://doi.org/10.1021/ol005881t

(Matrix Presented) Dimerization of salicylaldehydes provided 6H,12H-6,12-epoxydibenzo[b,f][1,5] dioxocins in multigram quantities. Deprotonation-allylation of the benzylic acetals followed by further functionalization of the diallyl derivative and do... Read More about A Novel Route to Preussomerins via 2-Arylacetal Anions.

New ligands for complexation of lanthanoids: The synthesis and structures of a nonadentate Schiff-base ligand (L1) and of the complexes [ML1(OH2)](ClO4)3·3MeNO 2 (M = La, Pr) and [YL1](ClO4) 3·3MeCN (1994)
Journal Article
Archibald, S. J., Blake, A. J., Schröder, M., & Winpenny, R. E. (1994). New ligands for complexation of lanthanoids: The synthesis and structures of a nonadentate Schiff-base ligand (L1) and of the complexes [ML1(OH2)](ClO4)3·3MeNO 2 (M = La, Pr) and [YL1](ClO4) 3·3MeCN. Journal of the Chemical Society. Chemical communications, 1669-1670. https://doi.org/10.1039/C39940001669

The synthesis and structures of a nonadentate Schiff-base ligand L 1 , prepared from tris(2-aminoethyl)amine and 2,6-diformyl-4- methylphenol, and of its complexes with M III ions (M = La, Pr and Y) are reported; [ML 1 (OH 2 )](ClO 4 ) 3 ·3MeNO 2... Read More about New ligands for complexation of lanthanoids: The synthesis and structures of a nonadentate Schiff-base ligand (L1) and of the complexes [ML1(OH2)](ClO4)3·3MeNO 2 (M = La, Pr) and [YL1](ClO4) 3·3MeCN.