Outputs (3)

Use of titanocalix[4]arenes in the ring opening polymerization of cyclic esters (2020)
Journal Article
Sun, Z., Zhao, Y., Santoro, O., Elsegood, M. R., Bedwell, E. V., Zahra, K., Walton, A., & Redshaw, C. (2020). Use of titanocalix[4]arenes in the ring opening polymerization of cyclic esters. Catalysis science & technology, 10(6), 1619-1639. https://doi.org/10.1039/c9cy02571e

The known dichloride complexes [TiCl2L(O)2(OR)2] (type I: R = Me (1), n-Pr (2) and n-pentyl (3); L(OH)2(OR)2 = 1,3-dialkyloxy-p-tert-butylcalix[4]arene), together with the new complexes {[TiL(O)3(OR)]2(μ-Cl)2}·6MeCN (R = n-decyl (4·6MeCN)), and [Ti(N... Read More about Use of titanocalix[4]arenes in the ring opening polymerization of cyclic esters.

Water-Soluble Rhenium Phosphine Complexes Incorporating the Ph2C(X) Motif (X = O–, NH–): Structural and Cytotoxicity Studies (2020)
Journal Article
Alshamrani, A. F., Prior, T. J., Burke, B. P., Roberts, D. P., Archibald, S. J., Higham, L. J., Stasiuk, G., & Redshaw, C. (2020). Water-Soluble Rhenium Phosphine Complexes Incorporating the Ph2C(X) Motif (X = O–, NH–): Structural and Cytotoxicity Studies. Inorganic chemistry, 59(4), 2367-2378. https://doi.org/10.1021/acs.inorgchem.9b03239

Reaction of [ReOCl3(PPh3)2] or [ReO2I(PPh3)2] with 2,2′-diphenylglycine (dpgH2) in refluxing ethanol afforded the air-stable complex [ReO(dpgH)(dpg)(PPh3)] (1). Treatment of [ReO(OEt)I2(PPh3)2] with 1,2,3-triaza-7-phosphaadamantane (PTA) afforded the... Read More about Water-Soluble Rhenium Phosphine Complexes Incorporating the Ph2C(X) Motif (X = O–, NH–): Structural and Cytotoxicity Studies.

Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle (2019)
Journal Article
Wang, K., Prior, T. J., & Redshaw, C. (2019). Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle. Chemical communications : Chem comm / the Royal Society of Chemistry, 55(75), 11279-11282. https://doi.org/10.1039/c9cc04494a

Homo-dinuclear Co and Zn complexes derived from the macrocycle LH2, {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][CH2CH2(2-C6H4N)2]}2 (R = Me, tBu), revealed near inactivity for the ring opening polymerization (ROP) of the cyclic esters δ-valerolactone (δ-VL) and ϵ... Read More about Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle.