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Mercury chemostratigraphy across the Cambrian Series 2 – Series 3 boundary: evidence for increased volcanic activity coincident with extinction?

Faggetter, L. E.; Wignall, P. B.; Pruss, S. B.; Jones, D. S.; Grasby, S.; Widdowson, M.; Newton, R. J.

Authors

L. E. Faggetter

P. B. Wignall

S. B. Pruss

D. S. Jones

S. Grasby

R. J. Newton



Abstract

Flood basalt volcanism represented by the Kalkarindji Province (Australia) is temporally associated with a trilobite mass extinction at the Cambrian Series 2 – Series 3 boundary, providing one of the oldest potential links between volcanism and biotic crisis in the Phanerozoic. However, the relative timing of flood basalt volcanism (Kalkarindji Province, Australia) and the trilobite extinctions, first recorded in North America, is not known. Mercury (Hg) enrichment in the sedimentary record provides a potential proxy for volcanism which may facilitate improved chronologies of eruption and extinction. Here we report mercury records for three sections from mid-shelf strata of the Great Basin (western USA) that straddle the Series 2 – Series 3 boundary. One section (Oak Springs Summit, NV) features a Hg enrichment at the start of the extinction interval, but mercury anomalies are also present at lower levels. These older anomalies may record either earlier phases of Kalkarindji volcanism, eruptions in other locations, or may be the result of sedimentary and/or diagenetic processes affecting the Hg record. In the Carrara Formation at Emigrant Pass, CA, the precise extinction horizon is not well defined, but a carbon isotope anomaly (the Redlichiid-Olenellid Extinction Carbon isotope Event; ROECE) provides a stratigraphic tie point to the Oak Springs Summit section. At Emigrant Pass, Hg enrichments precede the ROECE interval and are absent in the inferred extinction zone. The Pioche Formation at Ruin Wash, NV, lacks Hg enrichment at the extinction horizon but contains older enrichments. The inconsistent Hg records between the three sections demonstrate that factors controlling Hg accumulation and preservation in marine sedimentary environments are not yet fully understood. The effects of redox fluctuations may complicate one-to-one association of sedimentary Hg enrichments and massive volcanism at the Cambrian Series 2 – Series 3 boundary and elsewhere in the geologic record.

Citation

Faggetter, L. E., Wignall, P. B., Pruss, S. B., Jones, D. S., Grasby, S., Widdowson, M., & Newton, R. J. (2019). Mercury chemostratigraphy across the Cambrian Series 2 – Series 3 boundary: evidence for increased volcanic activity coincident with extinction?. Chemical Geology, 510, 188-199. https://doi.org/10.1016/j.chemgeo.2019.02.006

Journal Article Type Article
Acceptance Date Feb 5, 2019
Online Publication Date Feb 18, 2019
Publication Date Apr 5, 2019
Deposit Date Mar 14, 2019
Publicly Available Date Mar 29, 2024
Journal Chemical Geology
Print ISSN 0009-2541
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 510
Pages 188-199
DOI https://doi.org/10.1016/j.chemgeo.2019.02.006
Keywords Geology; Geochemistry and Petrology
Public URL https://hull-repository.worktribe.com/output/1378845
Publisher URL https://www.sciencedirect.com/science/article/pii/S0009254119300415?via%3Dihub
Additional Information This article is maintained by: Elsevier; Article Title: Mercury chemostratigraphy across the Cambrian Series 2 – Series 3 boundary: evidence for increased volcanic activity coincident with extinction?; Journal Title: Chemical Geology; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.chemgeo.2019.02.006; Content Type: article; Copyright: © 2019 Elsevier B.V. All rights reserved.

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