An efficient approach to the synthesis of novel pyrene-fused azaacenes

Feng, Xing; Iwanaga, Fumitaka; Hu, Jian Yong; Tomiyasu, Hirotsugu; Nakano, Masahiro; Redshaw, Carl; Elsegood, Mark R.J.; Yamato, Takehiko

Abstract

An efficient synthetic approach for functionalization of both the active sites (1,3-) and the K-region (4,5,9,10-) of pyrene was accomplished by bromination and oxidation with considerable yield. These novel pyrene-fused azaacenes were thoroughly investigated by X-ray diffraction studies, electrochemistry, and DFT calculations. © 2013 American Chemical Society.

Citation

Feng, X., Iwanaga, F., Hu, J. Y., Tomiyasu, H., Nakano, M., Redshaw, C., …Yamato, T. (2013). An efficient approach to the synthesis of novel pyrene-fused azaacenes. Organic Letters, 15(14), 3594-3597. https://doi.org/10.1021/ol401438a

• Journal Article Type: Letter
• Online Publication Date: Jul 3, 2013
• Publication Date: Jul 19, 2013
• Deposit Date: Jun 8, 2022
• Journal: Organic Letters
• Print ISSN: 1523-7060
• Electronic ISSN: 1523-7052
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 15
• Issue: 14
• Pages: 3594-3597
• DOI: https://doi.org/10.1021/ol401438a
• Public URL: https://hull-repository.worktribe.com/output/3621962