Wei Huang
Synthesis, characterization, and the ethylene (co-)polymerization behaviour of half-titanocene dichloride 2-aryliminoquinolin-8-olates
Huang, Wei; Zhang, Wenjuan; Sun, Wen Hua; Wang, Lin; Redshaw, Carl
Authors
Wenjuan Zhang
Wen Hua Sun
Lin Wang
Emeritus Professor Carl Redshaw C.Redshaw@hull.ac.uk
Emeritus Professor
Abstract
A series of half-titanocene dichloride 2-aryliminoquinolin-8-olates, CpTi LCl2 (C1-C6: Cp as C5H5, L as 2-(1-(o-benzhydrylarylimino)methyl)quinolin-8-olates or 2-(1-(o- benzhydrylarylimino)ethyl)quinolin-8-olates), was synthesized and fully characterized; the molecular structures of representative complexes C2 and C4 are reported. Upon activation with modified methylaluminoxane (MMAO), the title complexes exhibited good activities for ethylene polymerization (up to 1.56 × 106 g mol-1 (Ti) h-1). The C4/MMAO system was further investigated for the co-polymerization of ethylene with 1-hexene, 1-octene, or isoprene. © 2012 The Royal Society of Chemistry.
Citation
Huang, W., Zhang, W., Sun, W. H., Wang, L., & Redshaw, C. (2012). Synthesis, characterization, and the ethylene (co-)polymerization behaviour of half-titanocene dichloride 2-aryliminoquinolin-8-olates. Catalysis science & technology, 12(10), 2090-2098. https://doi.org/10.1039/c2cy20240a
Journal Article Type | Article |
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Publication Date | Oct 1, 2012 |
Deposit Date | Jun 8, 2022 |
Journal | Catalysis Science and Technology |
Print ISSN | 2044-4753 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 12 |
Issue | 10 |
Pages | 2090-2098 |
DOI | https://doi.org/10.1039/c2cy20240a |
Public URL | https://hull-repository.worktribe.com/output/3622173 |