2-(1-Arylimino)quinolylnickel halides: Synthesis, characterization and catalytic behavior towards ethylene

Song, Shengju; Xiao, Tianpengfei; Wang, Lin; Redshaw, Carl; Wang, Fosong; Sun, Wen Hua

Abstract

A series of 2-(1-arylimino)quinolylnickel halides were synthesized and characterized by IR and elemental analyses. Distorted trigonal bipyramidal geometries are adopted for the nickel complexes C1, C4, C7 and C11 as crystallized from either DMF or methanol solution. When activated by Et 2AlCl, the nickel pre-catalysts exhibited good to high catalytic activities in ethylene oligomerization.

Citation

Song, S., Xiao, T., Wang, L., Redshaw, C., Wang, F., & Sun, W. H. (2012). 2-(1-Arylimino)quinolylnickel halides: Synthesis, characterization and catalytic behavior towards ethylene. Journal of organometallic chemistry, 699, 18-25. https://doi.org/10.1016/j.jorganchem.2011.11.001

• Journal Article Type: Article
• Acceptance Date: Nov 1, 2011
• Online Publication Date: Nov 16, 2011
• Publication Date: Feb 15, 2012
• Deposit Date: Jun 8, 2022
• Journal: Journal of Organometallic Chemistry
• Print ISSN: 0022-328X
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 699
• Pages: 18-25
• DOI: https://doi.org/10.1016/j.jorganchem.2011.11.001
• Keywords: Ethylene oligomerization; Nickel pre-catalyst; X-ray diffraction; 2-(1-Arylimino)quinoline
• Public URL: https://hull-repository.worktribe.com/output/3622275