Synthesis, crystal structure and complexation behaviour of a thiacalix[4]arene bearing 1,2,3-triazole groups

Ni, Xin Long; Zeng, Xi; Hughes, David L.; Redshaw, Carl; Yamato, Takehiko

Abstract

The structure and complexation behaviour of 1,3-alternate-1,2,3-triazole based on thiacalix[4]arene,1,3-alternate-1 and 2 have been determined by means of X-ray analysis, fluorescence and 1H NMR spectroscopy. The X-ray results suggested that the nitrogen atom N3 on triazole ring can act as hydrogen bond acceptors in the self-assembly of a supramolecular structure. The fluorescence spectra changes indicated that the thiacalix[4]arene bearing 1,2,3-triazole groups were highly selective for Ag + in comparison with other tested metal ions by enhancement of the monomer emission of pyrene. The 1H NMR results suggested that Ag + can be strongly bonded by the triazole groups with the cooperation of the ionophoric cavity formed by the two inverted benzene rings and the sulfur atoms of the thiacalix[4]arene. © 2011 Taylor & Francis.

Citation

Ni, X. L., Zeng, X., Hughes, D. L., Redshaw, C., & Yamato, T. (2011). Synthesis, crystal structure and complexation behaviour of a thiacalix[4]arene bearing 1,2,3-triazole groups. Supramolecular chemistry, 23(10), 689-695. https://doi.org/10.1080/10610278.2011.601603

• Journal Article Type: Article
• Acceptance Date: Jun 24, 2011
• Online Publication Date: Oct 7, 2011
• Publication Date: 2011-10
• Deposit Date: Jun 8, 2022
• Journal: Supramolecular Chemistry
• Print ISSN: 1061-0278
• Electronic ISSN: 1029-0478
• Publisher: Taylor and Francis
• Peer Reviewed: Peer Reviewed
• Volume: 23
• Issue: 10
• Pages: 689-695
• DOI: https://doi.org/10.1080/10610278.2011.601603
• Public URL: https://hull-repository.worktribe.com/output/3622381