Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with 'pendant' arms

Lorber, Christian; Despagnet-Ayoub, Emmanuelle; Vendier, Laure; Arbaoui, Abdessamad; Redshaw, Carl

Abstract

Two families of vanadium complexes bearing diphenolate ligands with different 'pendant' arms have been screened under various conditions for the polymerisation behaviour of ethylene. The presence of a bound amine arm was found to favour enhanced thermal stability. © 2011 The Royal Society of Chemistry.

Citation

Lorber, C., Despagnet-Ayoub, E., Vendier, L., Arbaoui, A., & Redshaw, C. (2011). Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with 'pendant' arms. Catalysis science & technology, 1(3), 489-494. https://doi.org/10.1039/c1cy00089f

• Journal Article Type: Article
• Acceptance Date: Mar 29, 2011
• Online Publication Date: Apr 15, 2011
• Publication Date: Jun 1, 2011
• Deposit Date: Jun 8, 2022
• Journal: Catalysis Science and Technology
• Print ISSN: 2044-4753
• Electronic ISSN: 2044-4761
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 1
• Issue: 3
• Pages: 489-494
• DOI: https://doi.org/10.1039/c1cy00089f
• Public URL: https://hull-repository.worktribe.com/output/3622430