Vanadium procatalysts bearing chelating aryloxides: Structure-activity trends in ethylene polymerisation

Redshaw, Carl

Abstract

High-valent vanadium complexes bearing a variety of chelating aryloxides including di- and linear tri-phenolates, C/N-capped tripods, phenoxyimines and calixarenes type ligands, when used in combination with dialkylaluminium halides as co-catalyst and a reactivator, are found to act as highly active catalytic systems for α-olefin polymerisation. Pro-catalyst structure-catalytic activity trends can be identified for the various ligand families employed. © 2010 The Royal Society of Chemistry.

Citation

Redshaw, C. (2010). Vanadium procatalysts bearing chelating aryloxides: Structure-activity trends in ethylene polymerisation. Dalton Transactions : an international journal of inorganic chemistry, 39(24), 5595-5604. https://doi.org/10.1039/b924088h

• Journal Article Type: Review
• Acceptance Date: Mar 2, 2010
• Online Publication Date: Apr 1, 2010
• Publication Date: Jun 15, 2010
• Deposit Date: Jun 8, 2022
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 39
• Issue: 24
• Pages: 5595-5604
• DOI: https://doi.org/10.1039/b924088h
• Public URL: https://hull-repository.worktribe.com/output/3622491