Jiang Lin Zhao
Synthesis, structure and gas adsorption properties of coordination polymers based on mixed imidazole-containing ligands and carboxylate ligands
Zhao, Jiang Lin; Wu, Chong; Redshaw, Carl; Jin, Zongwen
Authors
Chong Wu
Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry
Zongwen Jin
Abstract
Herein, we report the synthesis of two novel coordination polymers using a combination of imidazole-containing ligands, namely 1,3,5-tris((1H-imidazol-1-yl)methyl)benzene (L1) and 3,3′,5,5′-tetra(1H-imidazol-1-yl)-1,1′-biphenyl (L2) and a carboxylate ligand derived from 4,4′-biphenyldicarboxylic acid (H2BPDC). The structures of the two coordination polymers [Ni(L1)(BPDC)]·2H2O (1·2H2O), which exhibits a 2-fold interpenetrated 3D → 3D architecture, and {[Co(CH3OH)2(L2)0.5(BPDC)] (2) possessing a 2D framework, have been determined. Moreover, the gas adsorption properties of 1 and 2 have been investigated.
Citation
Zhao, J. L., Wu, C., Redshaw, C., & Jin, Z. (2020). Synthesis, structure and gas adsorption properties of coordination polymers based on mixed imidazole-containing ligands and carboxylate ligands. Inorganica Chimica Acta, 517, Article 120193. https://doi.org/10.1016/j.ica.2020.120193
Journal Article Type | Article |
---|---|
Acceptance Date | Dec 8, 2020 |
Online Publication Date | Dec 13, 2020 |
Publication Date | Dec 13, 2020 |
Deposit Date | Dec 17, 2020 |
Publicly Available Date | Oct 27, 2022 |
Journal | Inorganica Chimica Acta |
Print ISSN | 0020-1693 |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 517 |
Article Number | 120193 |
DOI | https://doi.org/10.1016/j.ica.2020.120193 |
Keywords | Physical and Theoretical Chemistry; Inorganic Chemistry; Materials Chemistry |
Public URL | https://hull-repository.worktribe.com/output/3679745 |
Publisher URL | https://www.sciencedirect.com/science/article/abs/pii/S0020169320313931?via%3Dihub |
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Copyright Statement
©2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
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