Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides

Li, Lin; Sakr, Ahmed K.; Schlöder, Tobias; Klein, Siri; Beckers, Helmut; Kitsaras, Marios?Petros; Snelling, Howard V.; Young, Nigel A.; Andrae, Dirk; Riedel, Sebastian

Abstract

Binary transition metal fluorides are textbook examples combining complex electronic features with most fundamental molecular structures. High‐valent nickel fluorides are among the strongest known fluorinating and oxidizing agents, but there is a lack of experimental structural and spectroscopic investigations on molecular NiF3 or NiF4. Apart from their demanding synthesis, also their quantum‐chemical description is difficult due to their open shell nature and low‐lying excited electronic states. Distorted tetrahedral NiF4 (D2d) and trigonal planar NiF3 (D3h) molecules were produced by thermal evaporation and laser ablation of nickel atoms in a fluorine/noble gas mixture and spectroscopically identified by a joint matrix‐isolation and quantum‐chemical study. Their vibrational band positions provide detailed insights into their molecular structures.

Citation

Li, L., Sakr, A. K., Schlöder, T., Klein, S., Beckers, H., Kitsaras, M., Snelling, H. V., Young, N. A., Andrae, D., & Riedel, S. (2021). Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides. Angewandte Chemie, 60(12), 6391-6394. https://doi.org/10.1002/anie.202015501

• Journal Article Type: Article
• Acceptance Date: Dec 10, 2020
• Online Publication Date: Dec 10, 2020
• Publication Date: Mar 15, 2021
• Deposit Date: Mar 10, 2021
• Publicly Available Date: Mar 12, 2021
• Journal: Angewandte Chemie
• Print ISSN: 1433-7851
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 60
• Issue: 12
• Pages: 6391-6394
• DOI: https://doi.org/10.1002/anie.202015501
• Keywords: Nickel fluorides; Matrix isolation; Computational chemistry
• Public URL: https://hull-repository.worktribe.com/output/3703873