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Bi- and tri-dentate imino-based iron and cobalt pre-catalysts for ethylene oligo-/polymerization

Ma, Jing; Feng, Chun; Wang, Shaoli; Zhao, Ke-Qing; Sun, Wen-Hua; Redshaw, Carl; Solan, Gregory A.

Authors

Jing Ma

Chun Feng

Shaoli Wang

Ke-Qing Zhao

Wen-Hua Sun

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Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry

Gregory A. Solan



Abstract

Recent progress on the use of iron and cobalt complex pre-catalysts for ethylene reactivity is reviewed. The review is organized in terms of the denticity of the chelate ligands employed, with particular reference to the influence of the ligand frameworks and their substituents on the catalytic performance for ethylene oligomerization/polymerization catalysis. The majority of the systems bear tri-dentate ligation at the iron/cobalt centre, though it is clear that bi-dentate iron/cobalt complex pre-catalysts have also attracted significant attention. Such systems produce in most cases highly linear products ranging from oligomeric α-olefins to high molecular weight polyethylene, and as such are promising candidates for both academic and industrial considerations.

Journal Article Type Article
Publication Date Dec 16, 2013
Journal Inorganic chemistry : frontiers
Print ISSN 2052-1553
Electronic ISSN 2052-1553
Peer Reviewed Peer Reviewed
Volume 1
Issue 1
Pages 14-34
Institution Citation Ma, J., Feng, C., Wang, S., Zhao, K., Sun, W., Redshaw, C., & Solan, G. A. (2013). Bi- and tri-dentate imino-based iron and cobalt pre-catalysts for ethylene oligo-/polymerization. Inorganic chemistry frontiers an international journal of inorganic chemistry / Royal Society of Chemistry, 1(1), 14-34. doi:10.1039/c3qi00028a
DOI https://doi.org/10.1039/c3qi00028a
Keywords Chelate ligands, Ethylene oligomerization/polymerization , Iron and cobalt complex pre-catalysts
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2014/QI/C3QI00028A#!divAbstract
Copyright Statement ©2015 University of Hull
Additional Information Author's accepted manuscript of article published in: Inorganic chemistry : frontiers, 2014, v.1.

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