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Pillared two-dimensional metal-organic frameworks based on a lower-rim acid appended calix[4]arene

Horsburg, Lynne; Redshaw, Carl; Rowe, Oliver; Elsegood, Mark R. J.; Horsburgh, Lynne; Teat, Simon J.

Authors

Lynne Horsburg

Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry

Oliver Rowe

Mark R. J. Elsegood

Lynne Horsburgh

Simon J. Teat

Abstract

Solvothermal reactions of the lower-rim functionalized diacid calix[4]arene 25,27-bis(methoxycarboxylic acid)-26,28-dihydroxy-4-tert-butylcalix[4]arene (LH₂) with Zn(NO₃)₂•6H₂O and the dipyridyl ligands 4,4/-bipyridyl (4,4/-bipy), 1,2-di(4-pyridyl)ethylene (DPE) or 4,4/-azopyridyl (4,4/-azopy) afforded a series of 2-D structures of the formulae {[Zn(4,4/-bipy)(L)]•2¼DEF}n (1), {[Zn₂(L)(DPE)]•DEF}n (2) and {[Zn(OH₂)₂(L)(4,4/-azopy)]•DEF}n (3) (DEF = diethylformamide).

Journal Article Type Article
Publication Date 2014
Journal Crystal growth & design
Print ISSN 1528-7483
Electronic ISSN 1528-7505
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 14
Issue 1
Pages 270-277
Institution Citation Redshaw, C., Rowe, O., Elsegood, M. R. J., Horsburgh, L., & Teat, S. J. (2014). Pillared two-dimensional metal-organic frameworks based on a lower-rim acid appended calix[4]arene. Crystal growth & design, 14(1), (270-277). doi:10.1021/cg4014703. ISSN 1528-7483
DOI https://doi.org/10.1021/cg4014703
Keywords Calixarene family; Metal-organic frameworks
Publisher URL http://pubs.acs.org/doi/abs/10.1021/cg4014703
Copyright Statement © 2013 American Chemical Society. For terms of use see http://pubs.acs.org/pag...rchoice_termsofuse.html
Additional Information Copy of article published in Crystal growth & design, 2014, v.14 at: http://pubs.acs.org/doi/abs/10.1021/cg4014703

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Copyright Statement
© 2013 American Chemical Society. For terms of use see http://pubs.acs.org/page/policy/authorchoice_termsofuse.html



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