Pillared two-dimensional metal-organic frameworks based on a lower-rim acid appended calix[4]arene

Redshaw, Carl; Rowe, Oliver; Elsegood, Mark R. J.; Horsburgh, Lynne; Teat, Simon J.

Abstract

Solvothermal reactions of the lower-rim functionalized diacid calix[4]arene 25,27-bis(methoxycarboxylic acid)-26,28-dihydroxy-4-tert-butylcalix[4]arene (LH₂) with Zn(NO₃)₂•6H₂O and the dipyridyl ligands 4,4/-bipyridyl (4,4/-bipy), 1,2-di(4-pyridyl)ethylene (DPE) or 4,4/-azopyridyl (4,4/-azopy) afforded a series of 2-D structures of the formulae {[Zn(4,4/-bipy)(L)]•2¼DEF}n (1), {[Zn₂(L)(DPE)]•DEF}n (2) and {[Zn(OH₂)₂(L)(4,4/-azopy)]•DEF}n (3) (DEF = diethylformamide).

Citation

Redshaw, C., Rowe, O., Elsegood, M. R. J., Horsburgh, L., & Teat, S. J. (2014). Pillared two-dimensional metal-organic frameworks based on a lower-rim acid appended calix[4]arene. Crystal growth & design, 14(1), 270-277. https://doi.org/10.1021/cg4014703

• Journal Article Type: Article
• Acceptance Date: Oct 3, 2013
• Online Publication Date: Dec 18, 2013
• Publication Date: 2014
• Deposit Date: Jul 1, 2015
• Publicly Available Date: Jul 1, 2015
• Journal: Crystal growth & design
• Print ISSN: 1528-7483
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 14
• Issue: 1
• Pages: 270-277
• DOI: https://doi.org/10.1021/cg4014703
• Keywords: Calixarene family; Metal-organic frameworks
• Public URL: https://hull-repository.worktribe.com/output/375916
• Publisher URL: http://pubs.acs.org/doi/abs/10.1021/cg4014703
• Additional Information: Copy of article published in Crystal growth & design, 2014, v.14 at: http://pubs.acs.org/doi/abs/10.1021/cg4014703
• Contract Date: Jul 1, 2015