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Pillared two-dimensional metal-organic frameworks based on a lower-rim acid appended calix[4]arene

Horsburg, Lynne; Redshaw, Carl; Rowe, Oliver; Elsegood, Mark R. J.; Horsburgh, Lynne; Teat, Simon J.

Authors

Lynne Horsburg

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Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry

Oliver Rowe

Mark R. J. Elsegood

Lynne Horsburgh

Simon J. Teat



Abstract

Solvothermal reactions of the lower-rim functionalized diacid calix[4]arene 25,27-bis(methoxycarboxylic acid)-26,28-dihydroxy-4-tert-butylcalix[4]arene (LH₂) with Zn(NO₃)₂•6H₂O and the dipyridyl ligands 4,4/-bipyridyl (4,4/-bipy), 1,2-di(4-pyridyl)ethylene (DPE) or 4,4/-azopyridyl (4,4/-azopy) afforded a series of 2-D structures of the formulae {[Zn(4,4/-bipy)(L)]•2¼DEF}n (1), {[Zn₂(L)(DPE)]•DEF}n (2) and {[Zn(OH₂)₂(L)(4,4/-azopy)]•DEF}n (3) (DEF = diethylformamide).

Citation

Redshaw, C., Rowe, O., Elsegood, M. R. J., Horsburgh, L., & Teat, S. J. (2014). Pillared two-dimensional metal-organic frameworks based on a lower-rim acid appended calix[4]arene. Crystal growth & design, 14(1), 270-277. https://doi.org/10.1021/cg4014703

Journal Article Type Article
Acceptance Date Oct 3, 2013
Online Publication Date Dec 18, 2013
Publication Date 2014
Deposit Date Jul 1, 2015
Publicly Available Date Jul 1, 2015
Journal Crystal growth & design
Print ISSN 1528-7483
Electronic ISSN 1528-7505
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 14
Issue 1
Pages 270-277
DOI https://doi.org/10.1021/cg4014703
Keywords Calixarene family; Metal-organic frameworks
Public URL https://hull-repository.worktribe.com/output/375916
Publisher URL http://pubs.acs.org/doi/abs/10.1021/cg4014703
Copyright Statement © 2013 American Chemical Society. For terms of use see http://pubs.acs.org/page/policy/authorchoice_termsofuse.html
Additional Information Copy of article published in Crystal growth & design, 2014, v.14 at: http://pubs.acs.org/doi/abs/10.1021/cg4014703

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Copyright Statement
© 2013 American Chemical Society. For terms of use see http://pubs.acs.org/page/policy/authorchoice_termsofuse.html





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