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Highly selective recognition of the Al(ClO4)3 molecule by a mono-pyrene substituted thiacalix[4]arene chemosensor

Zhao, Jiang Lin; Xuan, Shuguang; Chen, Kai; Redshaw, Carl; Chen, Yan; Jin, Zongwen

Authors

Jiang Lin Zhao

Shuguang Xuan

Kai Chen

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Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry

Yan Chen

Zongwen Jin



Abstract

A mono-pyrene substituted thiacalix[4]arene chemosensor (TCA-Py) was successfully synthesized in satisfactory yield. Fluorescence analysis revealed that TCA-Py exhibited a high recognition selectivity toward the Al(ClO4)3 molecule due to the synergy between the Al3+ cation and ClO4- anion. This unique ability to recognise an entire inorganic molecule broadens the field of molecular recognition.

Citation

Zhao, J. L., Xuan, S., Chen, K., Redshaw, C., Chen, Y., & Jin, Z. (2022). Highly selective recognition of the Al(ClO4)3 molecule by a mono-pyrene substituted thiacalix[4]arene chemosensor. Chemical Communications, 58(41), 6112-6115. https://doi.org/10.1039/d2cc01609e

Journal Article Type Article
Acceptance Date Apr 27, 2022
Online Publication Date Apr 27, 2022
Publication Date May 20, 2022
Deposit Date May 4, 2022
Publicly Available Date Mar 29, 2024
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 58
Issue 41
Pages 6112-6115
DOI https://doi.org/10.1039/d2cc01609e
Keywords Materials Chemistry; Metals and Alloys; Surfaces, Coatings and Films; General Chemistry; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Catalysis
Public URL https://hull-repository.worktribe.com/output/3987533

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©2022 The authors. All rights reserved. No part of this publication may be reproduced without the written permission of the copyright holder




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