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Regio-selective substitution at the 1,3- and 6,8-positions of pyrene for the construction of small dipolar molecules

Feng, Xing; Tomiyasu, Hirotsugu; Hu, Jian-Yong; Wei, Xianfu; Redshaw, Carl; Elsegood, Mark R. J.; Horsburgh, Lynne; Teat, Simon J.; Yamato, Takehiko

Authors

Xing Feng

Hirotsugu Tomiyasu

Jian-Yong Hu

Xianfu Wei

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Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry

Mark R. J. Elsegood

Lynne Horsburgh

Simon J. Teat

Takehiko Yamato



Abstract

© 2015 American Chemical Society. This article presents a novel asymmetrical functionalization strategy for the construction of dipolar molecules via efficient regioselective functionalization along the Z-axis of pyrene at both the 1,3- and 6,8-positions. Three asymmetrical ly substituted 1,3-diphenyl-6,8-R-disubsituted pyrenes were fully characterized by X-ray crystallography, photophysical properties, electrochemistry, and density functional theory calculations.

Journal Article Type Article
Publication Date Nov 6, 2015
Journal Journal of organic chemistry
Print ISSN 0022-3263
Electronic ISSN 1520-6904
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 80
Issue 21
Pages 10973-10978
APA6 Citation Feng, X., Tomiyasu, H., Hu, J., Wei, X., Redshaw, C., Elsegood, M. R. J., …Yamato, T. (2015). Regio-selective substitution at the 1,3- and 6,8-positions of pyrene for the construction of small dipolar molecules. Journal of Organic Chemistry, 80(21), (10973-10978). doi:10.1021/acs.joc.5b02128. ISSN 0022-3263
DOI https://doi.org/10.1021/acs.joc.5b02128
Keywords Dipolar molecules; Regioselective functionalization
Publisher URL http://pubs.acs.org/doi/10.1021/acs.joc.5b02128
Copyright Statement ©2015 University of Hull
Additional Information This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of organic chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see 10.1021/acs.joc.5b02128

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