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Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters

Redshaw, Carl; Jana, Surajit; Shang, Congxiao; Elsegood, Mark R. J.; Elsegood, Mark R.J.; Lu, Xuesong; Guo, Zheng Xiao

Authors

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Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry

Surajit Jana

Congxiao Shang

Mark R. J. Elsegood

Mark R.J. Elsegood

Xuesong Lu

Zheng Xiao Guo



Abstract

The introduction of fluorinated aryls at zinc in Zn (and to a lesser extent Zn4N8-type4N6O) cages led to enhanced H2 uptake. Lithium alkoxides have been shown to link such cages (non-fluorinated), but showed no substantial improvement in uptake.

Journal Article Type Article
Publication Date Dec 21, 2010
Journal CHEMICAL COMMUNICATIONS
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 46
Issue 47
Pages 9055-9057
APA6 Citation Redshaw, C., Jana, S., Shang, C., Elsegood, M. R., Lu, X., & Guo, Z. X. (2010). Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters. Chemical communications : Chem comm / the Royal Society of Chemistry, 46(47), 9055-9057. doi:10.1039/c0cc03380d
DOI https://doi.org/10.1039/c0cc03380d
Keywords Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
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