Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters

Redshaw, Carl; Jana, Surajit; Shang, Congxiao; Elsegood, Mark R. J.; Elsegood, Mark R.J.; Lu, Xuesong; Guo, Zheng Xiao

Abstract

The introduction of fluorinated aryls at zinc in Zn (and to a lesser extent Zn4N8-type4N6O) cages led to enhanced H2 uptake. Lithium alkoxides have been shown to link such cages (non-fluorinated), but showed no substantial improvement in uptake.

Citation

Redshaw, C., Jana, S., Shang, C., Elsegood, M. R., Lu, X., & Guo, Z. X. (2010). Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters. Chemical communications : Chem comm / the Royal Society of Chemistry, 46(47), 9055-9057. https://doi.org/10.1039/c0cc03380d

• Journal Article Type: Article
• Acceptance Date: Oct 12, 2010
• Online Publication Date: Nov 3, 2010
• Publication Date: Dec 21, 2010
• Journal: CHEMICAL COMMUNICATIONS
• Print ISSN: 1359-7345
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 46
• Issue: 47
• Pages: 9055-9057
• DOI: https://doi.org/10.1039/c0cc03380d
• Keywords: Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
• Public URL: https://hull-repository.worktribe.com/output/418035