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Multinuclear alkylaluminium macrocyclic Schiff base complexes: Influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone

Arbaoui, Abdessamad; Redshaw, Carl; Hughes, David L.

Authors

Abdessamad Arbaoui

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Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry

David L. Hughes



Abstract

Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited beneficial cooperative effects, whilst aluminoxane-type bonding proved to be detrimental to activity for the ring opening polymerisation of ε-caprolactone.

Journal Article Type Article
Publication Date Oct 9, 2008
Journal CHEMICAL COMMUNICATIONS
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Issue 39
Pages 4717-4719
APA6 Citation Arbaoui, A., Redshaw, C., & Hughes, D. L. (2008). Multinuclear alkylaluminium macrocyclic Schiff base complexes: Influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone. Chemical communications : Chem comm / the Royal Society of Chemistry, 4717-4719. doi:10.1039/b810417d
DOI https://doi.org/10.1039/b810417d
Keywords Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
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