Chong Wu
Synthesis of mono-O-alkylated homooxacalix[3]arene and a protection–deprotection strategy for homooxacalix[3]arene
Wu, Chong; Ikejiri, Yusuke; Zeng, Xi; Elsegood, Mark R.J.; Redshaw, Carl; Yamato, Takehiko
Authors
Yusuke Ikejiri
Xi Zeng
Mark R.J. Elsegood
Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry
Takehiko Yamato
Abstract
The regioselective synthesis of mono-O-alkylated homooxacalix[3]arene is accomplished for the first time. The synthetic route relies on two key steps: (i) a facile protection of two OH groups at the lower rim of the homooxacalix[3]arene and (ii) the deprotection of 9- anthrylmethyl groups via the Pd/C-catalyzed hydrogenation under atmospheric hydrogen. An efficient protection- deprotection strategy for the functionalization of homooxacalix[ 3]arene is presented.
Citation
Wu, C., Ikejiri, Y., Zeng, X., Elsegood, M. R., Redshaw, C., & Yamato, T. (2017). Synthesis of mono-O-alkylated homooxacalix[3]arene and a protection–deprotection strategy for homooxacalix[3]arene. Organic Letters, 19(1), 66-69. https://doi.org/10.1021/acs.orglett.6b03338
Acceptance Date | Dec 10, 2016 |
---|---|
Online Publication Date | Dec 12, 2016 |
Publication Date | 2017-02 |
Deposit Date | Dec 13, 2016 |
Publicly Available Date | Dec 14, 2017 |
Journal | Organic letters |
Print ISSN | 1523-7060 |
Electronic ISSN | 1523-7052 |
Publisher | American Chemical Society |
Peer Reviewed | Peer Reviewed |
Volume | 19 |
Issue | 1 |
Pages | 66-69 |
DOI | https://doi.org/10.1021/acs.orglett.6b03338 |
Keywords | Mono-O-alkylated homooxacalix[3]arene; Homooxacalix[3]arene |
Public URL | https://hull-repository.worktribe.com/output/472183 |
Publisher URL | http://pubs.acs.org/doi/abs/10.1021/acs.orglett.6b03338 |
Additional Information | This is a description of an article which has been published in: Organic letters, 2017, v.19, issue 1. |
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©2017 University of Hull
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