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Crossover between liquid-like and gas-like behaviour in CH₄ at 400 K (2017)
Journal Article
Smith, D., Hakeem, M. A., Parisiades, P., Maynard-Casely, H. E., Foster, D., Eden, D., …Proctor, J. E. (2017). Crossover between liquid-like and gas-like behaviour in CH₄ at 400 K. Physical Review E, 96(5), doi:10.1103/PhysRevE.96.052113

We report experimental evidence for a crossover between a liquid-like state and a gas-like state in fluid methane (CH₄). This crossover is observed in all of our experiments, up to 397 K temperature; 2.1 times the critical temperature of methane. The... Read More

Determining molecular orientation via single molecule SERS in a plasmonic nano-gap (2017)
Journal Article
Marshall, A. R. L., Viscomi, F. N., Proctor, J. E., Bouillard, J. G., Adawi, A. M., Marshall, A. R., …Gierschner, J. (2017). Determining molecular orientation via single molecule SERS in a plasmonic nano-gap. Nanoscale, 9(44), 17415-17421. doi:10.1039/C7NR05107G

In this work, plasmonic nano-gaps consisting of a silver nanoparticle coupled to an extended silver film have been fully optimized for single molecule Surface-Enhanced Raman Scattering (SERS) spectroscopy. The SERS signal was found to be strongly dep... Read More