All Outputs (363)

Synthesis and structure of pentamethylcyclopentadienyl tungsten(V) complexes containing functionalized 6,12-epiiminodibenzo[b,f][1.5]diazorine ligands (2007)
Journal Article
Redshaw, C., Wood, P. T., & Elsegood, M. R. (2007). Synthesis and structure of pentamethylcyclopentadienyl tungsten(V) complexes containing functionalized 6,12-epiiminodibenzo[b,f][1.5]diazorine ligands. Organometallics, 26(25), 6501-6504. https://doi.org/10.1021/om700810p

2-Amino-3,5-dibromobenzaldehyde [3,5-Br2-2-H2NC 6CHO] undergoes a self-condensation reaction in the presence of o- or m-anthranilic acid, affording the novel ligand systems [o- or m-(HO 2C)C6H4(μ3-N)L] (L = [3,5-Br 2-HNC6H2-CH]2). Further interaction... Read More about Synthesis and structure of pentamethylcyclopentadienyl tungsten(V) complexes containing functionalized 6,12-epiiminodibenzo[b,f][1.5]diazorine ligands.

Chromogenic indicator for anion reporting based on an N-substituted oxoporphyrinogen (2006)
Journal Article
Hill, J. P., Schumacher, A. L., D'Souza, F., Labuta, J., Redshaw, C., Elsegood, M. R., …Ariga, K. (2006). Chromogenic indicator for anion reporting based on an N-substituted oxoporphyrinogen. Inorganic chemistry, 45(20), 8288-8296. https://doi.org/10.1021/ic0611591

5,10,15,20-Tetrakis-3,5-di-tert-butyl-4-oxocyclohexadienylidene porphyrinogen and its di-N-benzylated derivative are solvatochromic dyes capable of binding anionic species. The influence of solvent polarity and hydrogen bonding on their electronic ab... Read More about Chromogenic indicator for anion reporting based on an N-substituted oxoporphyrinogen.

Complexes of tungsten(IV,VI) derived from linked aryloxide ligands (2006)
Journal Article
Redshaw, C., & Humphrey, S. M. (2006). Complexes of tungsten(IV,VI) derived from linked aryloxide ligands. Polyhedron, 25(9), 1946-1954. https://doi.org/10.1016/j.poly.2005.12.008

Biphenoxo complexes of tungsten(VI), [WCl4{CHR[C6H2(But)2O]2}] R = H (1), Me (2) are reduced by Na/Hg in the presence of PMe3 to give cis, trans-WCl2(PMe3)2{CHR[C6H2(But)2O]2} R = H (3), Me (4). Reaction of [WOCl4] with the biphenols 2,2′-CHR[C6H2(Bu... Read More about Complexes of tungsten(IV,VI) derived from linked aryloxide ligands.