Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability
(2014)
Journal Article
Ma, J., Zhao, K.-Q., Walton, M., Wright, J. A., Hughes, D. L., Elsegood, M. R. J., Michiue, K., Sun, X., & Redshaw, C. (2014). Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability. Dalton Transactions : an international journal of inorganic chemistry, 43(44), 16698-16706. https://doi.org/10.1039/c4dt01448k
Reaction of the ligand 2,4-tert-butyl-6-[(2-methylquinolin-8-ylimino)methyl]phenol (L¹H) with [VOCl₃] in the presence of triethylamine afforded the complex [VOCl₂L¹] (1), whereas use of [VO(OnPr)₃] led to the isolation of [VO₂L¹] (2) or [VO₂L¹]·2/3Me... Read More about Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability.