Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates
(2014)
Journal Article
Soshnikov, I. E., Semikolenova, N. V., Ma, J., Zhao, K.-Q., Zakharov, V. A., Bryliakov, K. P., Redshaw, C., & Talsi, E. P. (2014). Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates. Organometallics, 33(6), 1431-1439. https://doi.org/10.1021/om500017r
The catalyst systems (FI)TiCl₃/MAO (FI = phenoxyimine ligand with an additional aryl–O–CH₃ donor) display exceptionally high activity in selective ethylene trimerization. By means of NMR and EPR spectroscopy, the nature of the Ti species formed in th... Read More about Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates.