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pH-dependent modulation of reactivity in Ruthenium(II) organometallics (2018)
Journal Article
Prior, T. J., Savoie, H., Boyle, R. W., & Murray, B. S. (2018). pH-dependent modulation of reactivity in Ruthenium(II) organometallics. Organometallics, 37(3), 294-297. https://doi.org/10.1021/acs.organomet.7b00868

The pH-dependent intramolecular chelation of a tethered sulfonamide ligand in ruthenium(II) arene complexes is demonstrated, a process shown to modulate metal-centered reactivity toward the model ligand guanosine 5′-monophosphate within the physiolog... Read More about pH-dependent modulation of reactivity in Ruthenium(II) organometallics.

Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex (2018)
Journal Article
Xia, Y., Wang, C., Tian, M., Tao, Z., Ni, X., Prior, T. J., & Redshaw, C. (2018). Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex. Molecules, 23(1), 175. https://doi.org/10.3390/molecules23010175

2018 by the authors. The host-guest interaction of a series of cyclohexyl-appended guests with cucurbit[8]uril (Q[8] ) was studied by 1 H NMR spectroscopy, isothermal titration calorimetry (ITC), and X-ray crystallography. The X-ray structure reveale... Read More about Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex.

Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH (2017)
Journal Article
Kubicek, V., Bohmova, Z., Price, T. W., Gallo, J., Kubíček, V., Böhmová, Z., …Stasiuk, G. J. (2017). Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH. Dalton transactions : an international journal of inorganic chemistry / RSoC, 46(48), 16973-16982. https://doi.org/10.1039/c7dt03398b

Gallium-68 ( 68 Ga) has been the subject of increasing interest for its potential in the production of radiotracers for diagnosis of diseases. In this work we report the complexation of 68 Ga by the amino acid based tripodal chelate H 3 Dpaa, and two... Read More about Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH.

Synthesis and structure of the inclusion complex {NdQ[5]K@Q[10](H₂O)4}·4NO₃·20H₂O (2017)
Journal Article
Chen, L. X., Kan, J. L., Cong, H., Prior, T. J., Tao, Z., Xiao, X., & Redshaw, C. (2017). Synthesis and structure of the inclusion complex {NdQ[5]K@Q[10](H₂O)4}·4NO₃·20H₂O. Molecules, 22(7), 1147 . https://doi.org/10.3390/molecules22071147

Heating a mixture of Nd(NO₃)₃·6H₂O, KCl, Q[10] and Q[5] in HCl for 10 min affords the inclusion complex {NdQ[5]K@Q[10](H₂O)₄}·4NO₃·20H₂O. The structure of the inclusion complex has been investigated by single crystal X-ray diffraction and by X-ray Ph... Read More about Synthesis and structure of the inclusion complex {NdQ[5]K@Q[10](H₂O)4}·4NO₃·20H₂O.

Interconvertible geometric isomers of Plasmodium falciparum dihydroorotate dehydrogenase inhibitors exhibit multiple binding modes (2017)
Journal Article
Boa, A. N., McConkey, G. A., Bedingfield, P. T., Burrell, D. R., Chambers, N. C., Cunningham, F., …Boa, A. N. (2017). Interconvertible geometric isomers of Plasmodium falciparum dihydroorotate dehydrogenase inhibitors exhibit multiple binding modes. Bioorganic and Medicinal Chemistry Letters, 27(16), 3878-3882. https://doi.org/10.1016/j.bmcl.2017.06.052

Two new tricyclic β-aminoacrylate derivatives (2e and 3e) have been found to be inhibitors of Plasmodium falciparum dihydroorotate dehydrogenase (PfDHODH) with Ki 0.037 and 0.15 μM respectively. 1H and 13C NMR spectroscopic data show that these compo... Read More about Interconvertible geometric isomers of Plasmodium falciparum dihydroorotate dehydrogenase inhibitors exhibit multiple binding modes.

Crystal structures of N ′-Aminopyridine-2-carboximidamide and N ′-{[1-(pyridin-2-yl)ethylidene]amino}pyridine-2-carboximidamide (2017)
Journal Article
Meva, F. E., Prior, T. J., Evans, D. J., & Mang, E. R. (2017). Crystal structures of N ′-Aminopyridine-2-carboximidamide and N ′-{[1-(pyridin-2-yl)ethylidene]amino}pyridine-2-carboximidamide. Acta Crystallographica Section E: Crystallographic Communications, 73(7), 1021-1025. https://doi.org/10.1107/s2056989017008416

© Eya'ane Meva et al. 2017. The crystal structures of N,-Aminopyridine-2-carboximidamide (C 6 H 8 N 4 ), 1, and N,-{[1-(pyridin-2-yl)ethylidene]amino}pyridine-2-carboximidamide (C 13 H 13 N 5 ), 2, are described. The non-H atoms in compound 1 are nea... Read More about Crystal structures of N ′-Aminopyridine-2-carboximidamide and N ′-{[1-(pyridin-2-yl)ethylidene]amino}pyridine-2-carboximidamide.

Crystal structures and gas adsorption behavior of new lanthanide-benzene-1,4-dicarboxylate frameworks (2017)
Journal Article
Panyarat, K., Surinwong, S., Prior, T. J., Konno, T., & Rujiwatra, A. (2017). Crystal structures and gas adsorption behavior of new lanthanide-benzene-1,4-dicarboxylate frameworks. Microporous and Mesoporous Materials, 251, 155-164. https://doi.org/10.1016/j.micromeso.2017.06.003

Six new lanthanide metal organic complexes, i.e. [La2(NO2-BDC)3(H2O)4] (1) [Ln(L)0.5(NO2-BDC) (H2O)]·3H2O (Ln = Eu (2), Tb (3), Dy (4) and Ho (5); L = BDC2− or BDC2−/NO2-BDC2-) and [Tm(NO2-BDC)1.5(H2O)]·H2O (6), have been synthesized using mixed liga... Read More about Crystal structures and gas adsorption behavior of new lanthanide-benzene-1,4-dicarboxylate frameworks.

Are spherulitic lacustrine carbonates an expression of large-scale mineral carbonation? A case study from the East Kirkton Limestone, Scotland (2017)
Journal Article
Rogerson, M., Mercedes Martín, R., Brasier, A. T., McGill, R. A. R., Prior, T. J., Vonhof, H., …Pedley, H. M. (2017). Are spherulitic lacustrine carbonates an expression of large-scale mineral carbonation? A case study from the East Kirkton Limestone, Scotland. Gondwana Research, 48, 101-109. https://doi.org/10.1016/j.gr.2017.04.007

Lacustrine carbonate deposits with spherulitic facies are poorly understood, but are key to understanding the economically important “Pre-Salt” Mesozoic strata of the South Atlantic. A major barrier to research into these unique and spectacular facie... Read More about Are spherulitic lacustrine carbonates an expression of large-scale mineral carbonation? A case study from the East Kirkton Limestone, Scotland.

Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites (2017)
Journal Article
Kelly, S., Kornherr, A., Alahmadi, N. S., Betts, J. W., Francesconi, M. G., Prior, T. J., …Kornherr, A. (2017). Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites. RSC advances, 7(32), 20020-20026. https://doi.org/10.1039/c7ra00920h

© The Royal Society of Chemistry. Green synthesis is employed to prepare cobalt/cellulose nanocomposites with cubic (α-cobalt) cobalt as a main component with antibacterial and magnetic properties. An in situ reduction of aqueous solutions of cobalt... Read More about Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites.

Organoaluminium complexes derived from Anilines or Schiff bases for ring opening polymerization of epsilon-caprolactone, delta-valerolactone and rac-lactide (2017)
Journal Article
Mo, S., Prior, T. J., Al-Khafaj, Y., Zhao, K., Wang, X., Elsegood, M. R., …Redshaw, C. (2017). Organoaluminium complexes derived from Anilines or Schiff bases for ring opening polymerization of epsilon-caprolactone, delta-valerolactone and rac-lactide. European Journal of Inorganic Chemistry, 2017(13), 1951-1965. https://doi.org/10.1002/ejic.201601415

Reaction of R¹R²CHN=CH(3,5-tBu₂C₆H₂-OH-2) (R¹ = R² = Me L¹H; R¹ = Me, R² = Ph L²H; R¹ = R2 = Ph L³H) with one equivalent of R³3Al (R³ = Me, Et) afforded [(L¹-³)AlR³₂] (L¹, R³ = Me 1, R³ = Et 2; L², R³ = Me 3, R³ = Et 4; L³ R³ = Me 5, R³ = Et 6); comp... Read More about Organoaluminium complexes derived from Anilines or Schiff bases for ring opening polymerization of epsilon-caprolactone, delta-valerolactone and rac-lactide.

Supramolecular assembly of cucurbit[6]uril and N-butyl-4-pyrrolidinopyridine (2017)
Journal Article
Hou, H., Gao, Z., Bai, D., Tao, Z., Prior, T. J., Redshaw, C., & Xiao, X. (2017). Supramolecular assembly of cucurbit[6]uril and N-butyl-4-pyrrolidinopyridine. Supramolecular chemistry, 29(9), 680-685. https://doi.org/10.1080/10610278.2017.1304549

The nature of the supramolecular host-guest complex involving 4-pyrrolidinopyridine (BuPC4) and cucurbit[6]uril (Q[6]) has been investigated by NMR and UV spectroscopy, MALDI-TOF mass spectrometry, X-ray crystallography and isothermal titration calor... Read More about Supramolecular assembly of cucurbit[6]uril and N-butyl-4-pyrrolidinopyridine.

On the high-pressure phase stability and elastic properties of β-titanium alloys (2017)
Journal Article
Smith, D., Joris, O. P. J., Sankaran, A., Weekes, H. E., Bull, D. J., Dye, D., …Proctor, J. E. (2017). On the high-pressure phase stability and elastic properties of β-titanium alloys. Journal of physics. an Institute of Physics journal. Condensed matter, 29(15), 155401. https://doi.org/10.1088/1361-648x/aa60b6

We have studied the compressibility and stability of different β-titanium alloys at high pressure, including binary Ti-Mo, Ti-24Nb-4Zr-8Sn (Ti2448) and Ti-36Nb-2Ta-0.3O (gum metal). We observed stability of the β phase in these alloys to 40 GPa, well... Read More about On the high-pressure phase stability and elastic properties of β-titanium alloys.

Multimetallic lithium complexes derived from the acids Ph₂C(X)CO₂H (X = OH, NH₂) : synthesis, structure and ring opening polymerization of lactides and lactones (2017)
Journal Article
Al-Khafaji, Y. F., Prior, T. J., Horsburgh, L., Elsegood, M. R. J., & Redshaw, C. (2017). Multimetallic lithium complexes derived from the acids Ph₂C(X)CO₂H (X = OH, NH₂) : synthesis, structure and ring opening polymerization of lactides and lactones. ChemistrySelect, 2(2), 759-768. https://doi.org/10.1002/slct.201602029

Reaction of LiOR (R=t-Bu, Ph) with the acids 2,2/-Ph₂C(X)(CO₂H), X=OH (benzH), NH₂ (dpgH) was investigated. For benzH, one equivalent LiOt-Bu in THF afforded [Li(benz)]2⋅2THF (1⋅2THF), which adopts a 1D chain structure. If acetonitrile is used (mild... Read More about Multimetallic lithium complexes derived from the acids Ph₂C(X)CO₂H (X = OH, NH₂) : synthesis, structure and ring opening polymerization of lactides and lactones.

A study of the interaction between inverted cucurbit[7]uril and symmetric viologens (2017)
Journal Article
Gao, Z., Chen, L., Gao, Z., Bai, D., Chen, L., Tao, Z., …Redshaw, C. (2017). A study of the interaction between inverted cucurbit[7]uril and symmetric viologens. RSC advances, 7(1), 461-467. https://doi.org/10.1039/c6ra24780f

The interaction between inverted cucuribit[7]uril (iQ[7]) and a series of symmetric viologen derivatives bearing aliphatic substituents of variable length, namely dicationic dialkyl-4,4′-bipyridinium guests where the alkyl is CH₃(CH₂)n with n = 0 to... Read More about A study of the interaction between inverted cucurbit[7]uril and symmetric viologens.

Polymorphism and solid−gas/solid−solid reactions of isonicotinic acid, isonicotinamide, and nicotinamide copper chloride compounds (2016)
Journal Article
Fellows, S. M., & Prior, T. J. (2017). Polymorphism and solid−gas/solid−solid reactions of isonicotinic acid, isonicotinamide, and nicotinamide copper chloride compounds. Crystal growth & design, 17(1), 106-116. https://doi.org/10.1021/acs.cgd.6b01295

The crystal structures of eight new copper chloride coordination complexes with substituted pyridines have been determined through a combination of single crystal X-ray diffraction and ab initio structure solution from X-ray powder diffraction data.... Read More about Polymorphism and solid−gas/solid−solid reactions of isonicotinic acid, isonicotinamide, and nicotinamide copper chloride compounds.

Copper coordination polymers constructed from thiazole-5-carboxylic acid: Synthesis, crystal structures, and structural transformation (2016)
Journal Article
Meundaeng, N., Rujiwatra, A., & Prior, T. J. (2017). Copper coordination polymers constructed from thiazole-5-carboxylic acid: Synthesis, crystal structures, and structural transformation. Journal of Solid State Chemistry, 245, 138-145. https://doi.org/10.1016/j.jssc.2016.10.009

© 2016 Elsevier Inc. We have successfully prepared crystals of thiazole-5-carboxylic acid (5-Htza) (L) and three new thiazole-5-carboxylate-based Cu 2+ coordination polymers with different dimensionality, namely, 1D [Cu 2 (5-tza) 2 (1,10-phenanthroli... Read More about Copper coordination polymers constructed from thiazole-5-carboxylic acid: Synthesis, crystal structures, and structural transformation.

Simultaneous differential scanning calorimetry – synchrotron X-ray powder diffraction : a powerful technique for physical form characterisation in pharmaceutical materials (2016)
Journal Article
Clout, A., Buanz, A. B. M., Prior, T. J., Reinhard, C., Wu, Y., O'Hare, D., …Gaisford, S. (2016). Simultaneous differential scanning calorimetry – synchrotron X-ray powder diffraction : a powerful technique for physical form characterisation in pharmaceutical materials. Analytical chemistry, 88(20), 10111-10117. https://doi.org/10.1021/acs.analchem.6b02549

© 2016 American Chemical Society. We report a powerful new technique: hyphenating synchrotron X-ray powder diffraction (XRD) with differential scanning calorimetry (DSC). This is achieved with a simple modification to a standard laboratory DSC instru... Read More about Simultaneous differential scanning calorimetry – synchrotron X-ray powder diffraction : a powerful technique for physical form characterisation in pharmaceutical materials.

Supramolecular assemblies constructed from inverted cucurbit[7]uril and lanthanide cations: synthesis, structure and sorption properties (2016)
Journal Article
Li, Q., Qiu, S., Zhang, Y., Xue, S., Tao, Z., Prior, T. J., …Xiao, X. (in press). Supramolecular assemblies constructed from inverted cucurbit[7]uril and lanthanide cations: synthesis, structure and sorption properties. RSC advances, 6(81), 77805-77810. https://doi.org/10.1039/c6ra15559f

The interaction of a series of lanthanide cations (Ln³⁺) with inverted cucurbit[7]uril (iQ[7]) in the presence of [ZnCl₄]²⁻ anions as a structure-directing agent have been investigated. Single-crystal X-ray diffraction analysis has revealed that the... Read More about Supramolecular assemblies constructed from inverted cucurbit[7]uril and lanthanide cations: synthesis, structure and sorption properties.

Stabilisation of metastable polymorphs: the case of paracetamol form III (2016)
Journal Article
Telford, R., Seaton, C. C., Clout, A., Buanz, A., Gaisford, S., Williams, G. R., …Scowen, I. J. (2016). Stabilisation of metastable polymorphs: the case of paracetamol form III. Chemical communications : Chem comm / the Royal Society of Chemistry, 52(81), 12028-12031. https://doi.org/10.1039/c6cc05006a

The design of a melt synthesis of the first air-stable formulation of the metastable form III of paracetamol is derived from thermospectroscopic and thermo-diffraction experiments. Melt crystallisation in the presence of b-1,4-saccharides produces fo... Read More about Stabilisation of metastable polymorphs: the case of paracetamol form III.

Polymorphism in metal complexes of thiazole-4-carboxylic acid (2016)
Journal Article
Meundaeng, N., Rujiwatra, A., & Prior, T. J. (2016). Polymorphism in metal complexes of thiazole-4-carboxylic acid. Transition Metal Chemistry, 41(7), 783-793. https://doi.org/10.1007/s11243-016-0079-7

Five new molecular complexes of chemical formula [M(4-tza)₂(H₂O)₂] (M = Co, Ni, and Cu) and a complex of [Cu(4-tza)₂]∙4H₂O using thiazole-4-carboxylic acid (4-tza) as the ligand have been successfully synthesized and structurally characterized by sin... Read More about Polymorphism in metal complexes of thiazole-4-carboxylic acid.


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