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Resource recovery and remediation of alkaline wastes

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Dr Amanda Gregory

Professor Jonathan Atkins

Professor Mike Rogerson

Vanadium: A re-emerging environmental hazard (2018)
Journal Article
Watt, J. A., Burke, I. T., Edwards, R. A., Malcolm, H. M., Mayes, W. M., Olszewska, J. P., Pan, G., Graham, M. C., Heal, K. V., Rose, N. L., Turner, S. D., & Spears, B. M. (2018). Vanadium: A re-emerging environmental hazard. Environmental Science and Technology, 52(21), 11973-11974. https://doi.org/10.1021/acs.est.8b05560

Vanadium (V) is a contaminant which has been long confined to the annals of regulatory history. This follows the reduction of its historical primary source (fossil fuel emissions) since the 1970s (e.g., by 80% in the UK). However, V is quickly becomi... Read More about Vanadium: A re-emerging environmental hazard.

Options for managing alkaline steel slag leachate: A life cycle assessment (2018)
Journal Article
Gomes, H. I., Mayes, W. M., Baxter, H. A., Jarvis, A. P., Burke, I. T., Stewart, D. I., & Rogerson, M. (2018). Options for managing alkaline steel slag leachate: A life cycle assessment. Journal of cleaner production, 202, 401-412. https://doi.org/10.1016/j.jclepro.2018.08.163

Management of steel slag (a major by-product of the steel industry) includes the treatment of highly alkaline leachate (pH > 11.5) from rainwater infiltration of slag deposits to prevent adverse impact upon surface or ground waters. This study aims t... Read More about Options for managing alkaline steel slag leachate: A life cycle assessment.

Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate (2018)
Journal Article
Hobson, A. J., Stewart, D. I., Bray, A. W., Mortimer, R. J., Mayes, W. M., Riley, A. L., Rogerson, M., & Burke, I. T. (2018). Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate. Science of the Total Environment, 643, 1191-1199. https://doi.org/10.1016/j.scitotenv.2018.06.272

© 2018 Vanadium is a toxic metal present in alkaline leachates produced during the weathering of steel slags. Slag leaching can therefore have deleterious effects on local watercourses due to metal toxicity, the effects of the high pH (9–12.5) and ra... Read More about Behaviour and fate of vanadium during the aerobic neutralisation of hyperalkaline slag leachate.

Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag (2018)
Journal Article
Stewart, D. I., Bray, A. W., Udoma, G., Hobson, A. J., Mayes, W. M., Rogerson, M., & Burke, I. T. (2018). Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag. Environmental science and pollution research, 25(10), 9861-9872. https://doi.org/10.1007/s11356-018-1260-7

© 2018 The Author(s) Alkalinity generation and toxic trace metal (such as vanadium) leaching from basic oxygen furnace (BOF) steel slag particles must be properly understood and managed by pre-conditioning if beneficial reuse of slag is to be maximis... Read More about Hydration of dicalcium silicate and diffusion through neo-formed calcium-silicate-hydrates at weathered surfaces control the long-term leaching behaviour of basic oxygen furnace (BOF) steelmaking slag.