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Click-modified hexahomotrioxacalix[3]arenes as fluorometric and colorimetric dual-modal chemosensors for 2,4,6-trinitrophenol (2016)
Journal Article
Wu, C., Zhao, J. L., Jiang, X. K., Ni, X. L., Zeng, X., Redshaw, C., & Yamato, T. (2016). Click-modified hexahomotrioxacalix[3]arenes as fluorometric and colorimetric dual-modal chemosensors for 2,4,6-trinitrophenol. Analytica Chimica Acta, 936, 216-221. https://doi.org/10.1016/j.aca.2016.06.045

A new type of chemosensor-based approach to the detection of 2,4,6-trinitrophenol (TNP) is described in this paper. Two hexahomotrioxacalix[3]arene-based chemosensors 1 and 2 were synthesized through click chemistry, which exhibited high binding affi... Read More about Click-modified hexahomotrioxacalix[3]arenes as fluorometric and colorimetric dual-modal chemosensors for 2,4,6-trinitrophenol.

Ocean acidification affects marine chemical communication by changing structure and function of peptide signalling molecules (2016)
Journal Article
Roggatz, C. C., Lorch, M., Hardege, J. D., & Benoit, D. M. (2016). Ocean acidification affects marine chemical communication by changing structure and function of peptide signalling molecules. Global change biology, 22(12), 3914-3926. https://doi.org/10.1111/gcb.13354

Ocean acidification is a global challenge that faces marine organisms in the near future with a predicted rapid drop in pH of up to 0.4 units by the end of this century. Effects of the change in ocean carbon chemistry and pH on the development, growt... Read More about Ocean acidification affects marine chemical communication by changing structure and function of peptide signalling molecules.

Mesophase structure and behaviour in bulk and restricted geometry of a dimeric compound exhibiting a nematic-nematic transition (2016)
Journal Article
Sebastián, N., Tamba, M. G., Stannarius, R., de la Fuente, M. R., Salamonczyk, M., Cukrov, G., …Eremin, A. (2016). Mesophase structure and behaviour in bulk and restricted geometry of a dimeric compound exhibiting a nematic-nematic transition. Physical chemistry chemical physics : PCCP, 18(28), 19299-19308. https://doi.org/10.1039/c6cp03899a

We present structural studies of a dimeric compound composed of a central heptyl spacer linking two mesogens consisiting of terphenyl units at which two adjacent fluoro groups are attached to each central ring. The terminal rings are linked to pentyl... Read More about Mesophase structure and behaviour in bulk and restricted geometry of a dimeric compound exhibiting a nematic-nematic transition.

Synthesis and evaluation of a novel fluorescent sensor based on hexahomotrioxacalix[3]arene for Zn²+ and Cd²+ (2016)
Journal Article
Jiang, X., Ikejiri, Y., Jin, C., Wu, C., Zhao, J., Ni, X., …Yamato, T. (2016). Synthesis and evaluation of a novel fluorescent sensor based on hexahomotrioxacalix[3]arene for Zn²+ and Cd²+. Tetrahedron, 72(32), 4854-4858. https://doi.org/10.1016/j.tet.2016.06.055

A novel type of selective and sensitive fluorescent sensor having triazole rings as the binding sites on the lower rim of a hexahomotrioxacalix[3]arene scaffold in a cone conformation is reported. This sensor has desirable properties for practical ap... Read More about Synthesis and evaluation of a novel fluorescent sensor based on hexahomotrioxacalix[3]arene for Zn²+ and Cd²+.

Fluctuation modes of a twist-bend nematic liquid crystal (2016)
Journal Article
Parsouzi, Z., Shamid, S. M., Borshch, V., Challa, P. K., Baldwin, A. R., Tamba, M. G., …Sprunt, S. (2016). Fluctuation modes of a twist-bend nematic liquid crystal. Physical Review X, 6(2), 021041-1-021041-16. https://doi.org/10.1103/PhysRevX.6.021041

We report a dynamic light-scattering study of the fluctuation modes in a thermotropic liquid crystalline mixture of monomer and dimer compounds that exhibits the twist-bend nematic (NTB) phase. The results reveal a spectrum of overdamped fluctuations... Read More about Fluctuation modes of a twist-bend nematic liquid crystal.

Structural studies of Schiff-base [2 + 2] macrocycles derived from 2,2′-oxydianiline and the ROP capability of their organoaluminium complexes (2016)
Journal Article
Yang, W., Zhao, K., Prior, T. J., Hughes, D. L., Arbaoui, A., Elsegood, M. R. J., & Redshaw, C. (2016). Structural studies of Schiff-base [2 + 2] macrocycles derived from 2,2′-oxydianiline and the ROP capability of their organoaluminium complexes. Dalton Transactions : an international journal of inorganic chemistry, 45(30), 11990-12005. https://doi.org/10.1039/c6dt01997h

The molecular structures of a number of solvates of the [2+2] Schiff-base macrocycles {[2-(OH)-5-(R)-C₆H₂-1,3-(CH)₂][O(2-C₆H₄N)₂]}₂ (R = Me L¹H₂, tBu L²H₂, Cl L³H₂), formed by reacting 2,6-dicarboxy-4-R-phenol with 2,2/-oxydianiline (2-aminophenyleth... Read More about Structural studies of Schiff-base [2 + 2] macrocycles derived from 2,2′-oxydianiline and the ROP capability of their organoaluminium complexes.

Synthesis and characterization of biodegradable lignin nanoparticles with tunable surface properties (2016)
Journal Article
Richter, A. P., Bharti, B., Armstrong, H. B., Brown, J. S., Plemmons, D., Paunov, V. N., …Velev, O. D. (2016). Synthesis and characterization of biodegradable lignin nanoparticles with tunable surface properties. Langmuir : the ACS journal of surfaces and colloids, 32(25), 6468-6477. https://doi.org/10.1021/acs.langmuir.6b01088

Lignin nanoparticles can serve as biodegradable carriers of biocidal actives with minimal environmental footprint. Here we describe the colloidal synthesis and interfacial design of nanoparticles with tunable surface properties using two different li... Read More about Synthesis and characterization of biodegradable lignin nanoparticles with tunable surface properties.

Extended π-conjugated pyrene derivatives: structural, photophysical and electrochemical properties (2016)
Journal Article
Feng, X., Seto, N., Wang, C., Matsumoto, T., Tanaka, J., Wei, X., …Yamato, T. (2016). Extended π-conjugated pyrene derivatives: structural, photophysical and electrochemical properties. ChemistrySelect, 1(9), 1926-1932. https://doi.org/10.1002/slct.201600598

This article presents a set of extended π-conjugated pyrene derivatives, namely 1,3-di(arylethynyl)-7-tert-butylpyrenes, which were synthesized by a Pd-catalyzed Sonogashira coupling reaction of 1,3-dibromo-7-tert-butylpyrenes with the corresponding... Read More about Extended π-conjugated pyrene derivatives: structural, photophysical and electrochemical properties.

Cellular internalisation, bioimaging and dark and photodynamic cytotoxicity of silica nanoparticles doped by {Mo₆I₈}⁴⁺ metal clusters (2016)
Journal Article
Solovieva, A. O., Vorotnikov, Y. A., Trifonova, K. E., Efremova, O. A., Krasilnikova, A. A., Brylev, K. A., …Shestopalov, M. A. (in press). Cellular internalisation, bioimaging and dark and photodynamic cytotoxicity of silica nanoparticles doped by {Mo₆I₈}⁴⁺ metal clusters. Journal of Materials Chemistry B, 4(28), 4839-4846. https://doi.org/10.1039/c6tb00723f

Silica nanoparticles (SNPs) doped by hexanuclear molybdenum cluster complexes [{Mo₆X₈}L₆]n (X = Cl, Br, or I; L = various inorganic or organic ligands) have been recently suggested as materials with a high potential for biomedical applications due to... Read More about Cellular internalisation, bioimaging and dark and photodynamic cytotoxicity of silica nanoparticles doped by {Mo₆I₈}⁴⁺ metal clusters.

A ratiometric Al³⁺ ion probe based on the coumarin-quinoline FRET system (2016)
Journal Article
Zhu, Q., Li, L., Mu, L., Zeng, X., Redshaw, C., & Wei, G. (2016). A ratiometric Al³⁺ ion probe based on the coumarin-quinoline FRET system. Journal of Photochemistry and Photobiology A: Chemistry, 328, 217-224. https://doi.org/10.1016/j.jphotochem.2016.06.006

A coumarin-quinoline based fluorescence resonance energy transfer (FRET) system (TCQ) has been synthesized and employed as a ratiometric fluorescence probe. The selective fluorescent response of the probe TCQ toward Al³⁺ was devised by employing a qu... Read More about A ratiometric Al³⁺ ion probe based on the coumarin-quinoline FRET system.