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PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural (2021)
Journal Article
Islam, M. J., Granollers Mesa, M., Osatiashtiani, A., Manayil, J. C., Isaacs, M. A., Taylor, M. J., Tsatsos, S., & Kyriakou, G. (2021). PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural. Applied catalysis. B, Environmental, 299, Article 120652. https://doi.org/10.1016/j.apcatb.2021.120652

Single-atom catalysts serve as a skilful control of precious metals on heterogenous catalysts where all active sites are accessible for catalytic reactions. Here we report the adoption of PdCu single-atom alloys supported on alumina for the selective... Read More about PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural.

Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics (2021)
Journal Article
Cheah, K. W., Yusup, S., Loy, A. C. M., How, B. S., Skoulou, V., & Taylor, M. J. (2021). Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics. Molecular Catalysis, Article 111469. https://doi.org/10.1016/j.mcat.2021.111469

With the inevitable human innate aspirations for better urban mobility and sustainable economic development, bio-based transportation fuels are projected to play an essential role in the foreseeable automotive transportation sector. Agricultural-base... Read More about Recent advances in the catalytic deoxygenation of plant oils and prototypical fatty acid models compounds: Catalysis, process, and kinetics.

Pretreating Iignocellulosic biomass wastes for the next generation of solid fuels (2021)
Presentation / Conference Contribution
Hornsby, K., Taylor, M. J., Hurst, P., Walker, S., & Skoulou, V. (2021, February). Pretreating Iignocellulosic biomass wastes for the next generation of solid fuels. Poster presented at LECO Analytical Applications Poster Competition (LA² PC) 2020-2021, Online

From the sponsor's website:
The LECO Analytical Applications Poster Competition (LA2PC) 2020-2021 recently wrapped up, showcasing 15 incredible posters highlighting the applications of LECO instruments in our users’ work and research.

A hearty co... Read More about Pretreating Iignocellulosic biomass wastes for the next generation of solid fuels.

Atom efficient PtCu bimetallic catalysts and ultra dilute alloys for the selective hydrogenation of furfural (2020)
Journal Article
Taylor, M. J., Beaumont, S. K., Islam, M. J., Tsatsos, S., Parlett, C. A., Issacs, M. A., & Kyriakou, G. (2021). Atom efficient PtCu bimetallic catalysts and ultra dilute alloys for the selective hydrogenation of furfural. Applied catalysis. B, Environmental, 284, Article 119737. https://doi.org/10.1016/j.apcatb.2020.119737

A range of Pt:Cu bimetallic nanoparticles were investigated for the liquid-phase selective hydrogenation of furfural, an important platform biomass feedstock. Alloying of the two metals had a profound effect on the overall catalytic activity, providi... Read More about Atom efficient PtCu bimetallic catalysts and ultra dilute alloys for the selective hydrogenation of furfural.

Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step (2020)
Journal Article
Cheah, K. W., Yusup, S., Taylor, M. J., How, B. S., Osatiashtiani, A., Nowakowski, D. J., Bridgwater, A. V., Skoulou, V., Kyriakou, G., & Uemura, Y. (2020). Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step. Reaction Chemistry and Engineering, 5(9), 1682-1693. https://doi.org/10.1039/d0re00214c

Herein, for the first time, we demonstrate a novel continuous flow process involving the application of tetralin as a hydrogen
donor solvent for the catalytic conversion of oleic acid to diesel-like hydrocarbons, using an efficient and stable carbon... Read More about Kinetic modelling of hydrogen transfer deoxygenation of a prototypical fatty acid over a bimetallic Pd60Cu40 catalyst: an investigation of the surface reaction mechanism and rate limiting step.

Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation (2020)
Journal Article
Aladbrabalameer, H., Taylor, M. J., Kauppinen, J., Soini, T., Pikkarainen, T., & Skoulou, V. (2020). Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation. Sustainable Energy & Fuels, 4(7), 3764-3772. https://doi.org/10.1039/d0se00155d

Defluidisation as a result of reactor bed agglomeration is a global challenge associated with the gasification of lignocellulosic biomass waste, specifically its high inorganic content. The use of conventional water leaching has been scrutanised for... Read More about Big problem, little answer: overcoming bed agglomeration and reactor slagging during the gasification of barley straw under continuous operation.

Probing synergies between lignin-rich and cellulose compounds for gasification (2020)
Journal Article
Taylor, M. J., Michopoulos, A. K., Zabaniotou, A. A., & Skoulou, V. (2020). Probing synergies between lignin-rich and cellulose compounds for gasification. Energies, 13(10), Article 2590. https://doi.org/10.3390/en13102590

The fixed bed gasification of lignin rich and deficient mixtures was carried out to probe the synergistic effects between two model compounds, Lignin Pink (LP) rich in Na and Cellulose Microcrystalline (CM). Reaction conditions utilized the most comm... Read More about Probing synergies between lignin-rich and cellulose compounds for gasification.

The effect of metal precursor on copper phase dispersion and nanoparticle formation for the catalytic transformations of furfural (2020)
Journal Article
Islam, M. J., Granollers Mesa, M., Osatiashtiani, A., Taylor, M. J., Manayil, J. C., Parlett, C. M., Isaacs, M. A., & Kyriakou, G. (2020). The effect of metal precursor on copper phase dispersion and nanoparticle formation for the catalytic transformations of furfural. Applied catalysis. B, Environmental, 273, Article 119062. https://doi.org/10.1016/j.apcatb.2020.119062

The formation of copper-based catalysts ranging from nanoparticles to isolated and dimeric Cu species supported on nanophased alumina is reported and utilised for the catalytic liquid-phase hydrogenation of furfural. The materials were synthesised vi... Read More about The effect of metal precursor on copper phase dispersion and nanoparticle formation for the catalytic transformations of furfural.

Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network (2020)
Journal Article
Taylor, M. J., Alabdrabalameer, H. A., Michopoulos, A. K., Volpe, R., & Skoulou, V. (2020). Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network. ACS Sustainable Chemistry and Engineering, 8(14), 5674-5682. https://doi.org/10.1021/acssuschemeng.0c00351

© 2020 American Chemical Society. By augmenting conventional leaching technologies for the removal of ash constituents from lignocellulosic waste residues, a cleaner and energy efficient solution can be provided for critical industrial problems such... Read More about Augmented Leaching Pretreatments for Forest Wood Waste and Their Effect on Ash Composition and the Lignocellulosic Network.

Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels (2019)
Journal Article
Taylor, M. J., Alabdrabalameer, H. A., & Skoulou, V. (2019). Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels. Sustainability, 11(13), Article 3604. https://doi.org/10.3390/su11133604

Various methods of physical, chemical and combined physicochemical pre-treatments for biomass waste valorization to value added feedstock for downstream processes in Chemical Industries have been reviewed. Where relevant literature was scrutinized fo... Read More about Choosing physical, physicochemical and chemical methods of pre-treating lignocellulosic wastes to repurpose into solid fuels.