Jack O. Conway
Interstitial nitrides revisited - a simple synthesis of MxMo3N (M = Fe, Co, Ni)
Conway, Jack O.; Prior, Timothy J.
Dr Timothy Prior T.Prior@hull.ac.uk
Lecturer in Inorganic Chemistry
The efficient synthesis of polycrystalline filled beta-Mn structured Ni2Mo3N, and the eta-carbides Fe3Mo3N and Co3Mo3N, by a single heating of metal powders at 975 ºC under a hydrogen-nitrogen mixture is reported. Rietveld analysis of high-resolution X-ray powder diffraction data shows that the reduction-nitridation of NiMoO4 produces Ni2Mo3N and nickel; Ni3Mo3N is not obtained in this way and its existence is disproved.
|Journal Article Type||Article|
|Publication Date||Feb 5, 2019|
|Journal||Journal of Alloys and Compounds|
|Peer Reviewed||Peer Reviewed|
|APA6 Citation||Conway, J. O., & Prior, T. J. (2019). Interstitial nitrides revisited - a simple synthesis of MxMo3N (M = Fe, Co, Ni). Journal of Alloys and Compounds, 774, 69-74. https://doi.org/10.1016/j.jallcom.2018.09.307|
|Keywords||Beta manganese; Eta carbide; Ni3Mo3N; Interstitial; Catalysis; Nitride|
© 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/